Search results for "Dye laser"
showing 10 items of 63 documents
Spectroscopic properties of pure and Coumarin 153-doped thin films of sol-gel silica xerogels
1999
Abstract Thin-films doped with Coumarin 153, an important laser dye, have been prepared by the sol-gel method. Spectroscopic properties of the entrapped dye are studied by electronic absorption, diffuse reflectance, electronic excitation, emission and time-resolved emission techniques. The obtained results indicate that the entrapment of the dye results in formation of molecular aggregates having absorption and emission characteristics different from those of the monomeric dye. The blue matrix emission band (at approx. 450 nm) is relatively short-lived while the red band (at approx. 700 nm) displays a very long lifetime. Electronic excitation spectra of the sol-gel thin-films suggest that t…
Vibrational relaxation of Na2 molecules in a triplet state: collisional transfer from a mixed A 1Σu+ − b3Πu gateway level to long-lived levels of b 3…
1997
Abstract Collision-induced vibrational transitions of Na2 within the b 3Π1u state have been observed in a free jet expansion, using two CW dye lasers for the pump and probe steps. The b-state is entered by the pump laser using a low mixed ( A 1 Σ u + − b 3 Π u ) level as a gateway. The occupations of various v′,J′-levels are studied as functions of the position in the flowing gas. The radiative lifetimes of Na2 in levels which had been populated by vibrational relaxation are found to be very long (> 4 μs). Cross-sections are estimated for vibrationally inelastic collisions with Na and Ar atoms.
An efficient excitation scheme for resonance ionization of tin in a laser ion source
1992
An efficient three-colour, three-step resonant excitation/ionization scheme has been found for tin that leads from the 5p23P2 level of the ground-state multiplet via two excited atomic levels (λ1 = 317.51 nm and λ2 = 811.40 nm) to an autoionizing state 9s3P2(λ3 = 823.49 nm) at 59375.9 cm−1. This excitation path permits the saturation of all transitions with the limited power available from a copper vapour laser pumped dye laser system (Esat ≈ 1.5 mJcm2 for λ3). The high repetition rate of such a laser system is essential for a highly efficient laser ion source.
Ground and excited state dipole moments of coumarin laser dyes: Investigation by electro-optical absorption and emission methods
1997
Abstract Modified electro-optical absorption and emission methods were used to measure the dipole moments of four efficient coumarin laser dyes (CU1, CU4, CU120, CU334) in the equilibrated ground, excited Franck-Condon and equilibrated excited states. The measurements were performed in cyclohexane (CU1, CU120, CU334) and dioxane (all CUs) at room temperature. Our results show that the charge distribution in CU4 differs substantially from that in the other CUs. The equilibrated ground and excited state dipole moments measured by electro-optical methods are compared with those derived from other measurement techniques and from semiempirical calculations. The possible role of twisted intermole…
Towards laser cooling of fast Be+ ions in the storage ring TSR
1989
Publisher Summary This chapter presents a clear understanding of laser-ion interactions under storage ring conditions to prepare the basis of laser cooling of fast-stored ion beams. In addition, the method of laser-induced fluorescence provides precise data for beam properties such as absolute velocity, momentum spread, and lifetime. 9Be+ ions stored in a heavy-ion storage ring are a promising species for laser cooling down to temperatures several orders of magnitude less than those reached for protons by electron cooling at the Novosibirsk ring. Short cooling times and microkelvin temperatures can be envisaged, where the structure of the ion beam is dominated by Coulomb repulsion. The chap…
The ground electronic state of KCs studied by Fourier transform spectroscopy
2008
We present here the first analysis of laser induced fluorescence (LIF) of the KCs molecule obtaining highly accurate data and perform a direct potential construction for the X (1)Sigma(+) ground state in a wide range of internuclear distances. KCs molecules were produced by heating a mixture of K and Cs metals in a heat pipe at a temperature of about 270 degrees C. KCs fluorescence was induced by different laser sources: the 454.5, 457.9, 465.8, and 472.7 nm lines of an Ar(+) laser, a dye laser with Rhodamine 6G dye (excitation at around 16 870 cm(-1)), and 850 and 980 nm diode lasers (11 500-11 900 and 10 200-10 450 cm(-1) tuning ranges, respectively). The LIF to the ground state was recor…
Very narrow-bandwidth tunable infrared difference frequency generation with injection-locked dye lasers
1989
Two flashlamp pumped dye lasers of very high spectral quality are mixed in a LiIO3 crystal to generate a tunable infrared beam through the difference frequency mixing. Thanks to the injection-locking process of the pulsed dye lasers leading to a linewidth of 6 MHz with peak powers of about 10 kW, we obtain an IR beam tunable from 3.5 to 5.9 μm with a peak power of 40 W and a linewidth of 9 MHz. As an application we present a spectrum of N2O obtained by differential absorption near 1880 cm−1. The lines of thisQ-branch are Doppler limited at the working pressure (102 Pa).
Laser resonant ionization of plutonium
1985
Resonance ionization mass spectrometry (RIMS) has been tested for the isotope-selective determination of trace amounts of plutonium. An atomic beam is formed by evaporating plutonium atoms from a rhenium-filament heated to 1800 °C. The radiation of a pulsed dye laser excites the atoms in a two-photon process (λ=595.2 nm) followed by photoionization of the excited atoms. Mass selectivity is obtained by use of a time-of-flight spectrometer. A resonant signal of239Pu was measured with 1013 atoms deposited on the filament.
Thermal and optical properties of red luminescent glass forming symmetric and non symmetric styryl-4H-pyran-4-ylidene fragment containing derivatives
2012
Abstract Dyes with amorphous structure deposited from organic solvents and having good fluorescence properties show potential for photonic device applications. Organic glass-forming symmetric and non symmetric styryl- derivatives of 2(2,6-substituted-4H-pyran-4-ylidene)-malononitrile (it has backbone of known laser dye 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran), 2(2,6-substituted-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione and 2(2,6-substituted-4H-pyran-4-ylidene)-pyrimidine-2,4,6(1H,3H,5H)-trione were synthesized and investigated. Glass transition temperatures higher than 110 °C were achieved. The absorption bands in dichloromethane solution cover the spectral regi…
Random Laser Based on TiO2–Nanomembranes
2012
We demonstrated directional random laser emission from a dye-doped polymer film in the presence of a scattering medium consisting of TiO 2 nanomembranes. Evidence for coexistence of extended and localized modes are presented.