Search results for "Dye-sensitized Solar Cell"
showing 8 items of 78 documents
Phenothiazine-based dyes with bilateral extension of π-conjugation for efficient dye-sensitized solar cells
2013
Four novel organic photo-sensitizers based on phenothiazine were designed, synthesized and characterized for efficient dye-sensitized solar cells. Anisole, octyloxybenzene and dodecyloxybenzene were incorporated into the phenothiazine by an Ullmann reaction. An additional octyloxybenzene was incorporated into one dye unit through a Suzuki coupling reaction. The modified phenothiazine moiety acts as an electron donor and cyanoacrylic acid acts as an electron acceptor and anchoring unit. The photophysical, electrochemical and sensitizing characteristics of the new dyes were evaluated. The bis(octyloxybenzene) substituted dye delivered the best performance with its sensitized solar cell displa…
Synthesis and Characterization of Extended Bis(terpyridine)ruthenium Amino Acids
2009
(Oligopyridine)ruthenium(II) complexes have been widely used in dye sensitized solar cells and other sophisticated optical devices due to their outstanding photophysical properties and their chemical stability. Herein, we describe the longitudinal extension of our previously reported bis(terpyridine)ruthenium(II) amino acid [Ru(tpy–NH2)(tpy–COOH)]2+ (tpy = 4′-substituted 2,2′:6′,2″-terpyridine) by insertion of para-phenylene spacers –C6H4– between the terpyridine and the functional groups. The influence of the para-phenylene spacer on the absorption and emission properties is investigated using UV/Vis absorption and emission spectroscopy and is discussed within a qualitative molecular orbit…
Anomalous electrical parameters improvement in Ruthenium DSSC
2018
. In this work, we present a series of measurements carried out on Ruthenium-based Dye Sensitized Solar Cells (DSSCs) after the application of different external electrical field values. Such measurements have been performed both in the dark and by illuminating the sample with sunlight emitted by a solar simulator (AM1.5G spectrum with a power irradiance of 1000 W/m2). Our results demonstrate that the initial electrical bias field modifies in both cases the behavior of the cell in terms of an anomalous improvement of the main electrical parameters.
Anomalous performance enhancement effects in Ruthenium-based Dye Sensitized Solar Cells
2017
Dye Sensitized Solar Cells (DSSCs) are nowadays more and more employed since they present lower production costs than traditional silicon photovoltaic devices. An interesting phenomenon affecting such devices consists in the fact that current density-voltage (J-V) characteristic can depend on the history of the cell prior to the measurement, which often can be assimilated to an anomalous hysteresis effect. In this work, we study such phenomenon on Ruthenium-based DSSCs through a series of measurements performed after applying different values of external electrical field to the cell. The measurements have been carried out both under simulated sunlight (AM1.5G - 1000 W/m2) and in the dark. W…
Experimental Investigation on the Performances of Innovative PV Vertical Structures
2019
The sustainable development of our planet is considerably related to a relevant reduction of CO2 global emissions, with building consumption contributing more than 40%. In this scenario, new technological conceptions, such as building-integrated photovoltaic technology, emerged in order to satisfy the requirements of sustainability imposed by the European Union. Therefore, the aim of this work is to provide a technical and economical comparison of the performances of different vertical-mounted innovative photovoltaic systems, potentially integrated on a building instead of on traditional windows or glass walls. The proposed investigation was carried out by means of experimental tests on thr…
The assessment of the reliability of an innovative 3rd generation solar cell integrated with “thermal belt” glass block
2017
Glass block is a building product widely used for the construction of translucent building façades and roofs. The need to adapt the product to the regulations in the field of energy saving and environmental sustainability has led to the design of innovative configurations, through the integration of different sub-components. These ones are able to improve its energy performance by means of the integration of a“thermal belt”, cold glued to the glass shells, which constitute the traditional glass block, and 3rd generation solar cells. This paper reports the first results of the experimental program designed to assess some durability components: inherent and critical reliability. <div id="g…
Donor-π-acceptors containing the 10-(1,3-dithiol-2-ylidene)anthracene unit for dye-sensitized solar cells
2012
Two donor-acceptor molecular tweezers incorporating the 10-(1,3-dithiol-2-ylidene)anthracene unit as donor group and two cyanoacrylic units as accepting/anchoring groups are reported as metal-free sensitizers for dye-sensitized solar cells. By changing the phenyl spacer with 3,4-ethylenedioxythiophene (EDOT) units, the absorption spectrum of the sensitizer is red-shifted with a corresponding increase in the molar absorptivity. Density functional calculations confirmed the intramolecular charge-transfer nature of the lowest-energy absorption bands. The new dyes are highly distorted from planarity and are bound to the TiO(2) surface through the two anchoring groups in a unidentate binding for…
Influence of Nitrogen Doping on Device Operation for TiO₂-Based Solid-State Dye-Sensitized Solar Cells: Photo-Physics from Materials to Devices.
2015
Solid-state dye-sensitized solar cells (ssDSSC) constitute a major approach to photovoltaic energy conversion with efficiencies over 8% reported thanks to the rational design of efficient porous metal oxide electrodes, organic chromophores, and hole transporters. Among the various strategies used to push the performance ahead, doping of the nanocrystalline titanium dioxide (TiO2) electrode is regularly proposed to extend the photo-activity of the materials into the visible range. However, although various beneficial effects for device performance have been observed in the literature, they remain strongly dependent on the method used for the production of the metal oxide, and the influence o…