Search results for "Dynamic"

Role of the reagents consumption in the chaotic dynamics of the Belousov-Zhabotitinsky oscillator in closed unstirred reactors

2010

Chemical oscillations generated by the Belousov–Zhabotinsky reaction in batch unstirred reactors, show a characteristic chaotic transient in their dynamical regime, which is generally found between two periodic regions. Chemical chaos starts and finishes by following a direct and an inverse Ruelle–Takens–Newhouse scenario, respectively. In previous works we showed, both experimentally and theoretically, that the complex oscillations are generated by the coupling among the nonlinear kinetics and the transport phenomena, the latter due to concentration and density gradients. In particular, convection was found to play a fundamental role. In this paper, we develop a reaction–diffusion–convecti…

A bending theory of thermoelastic diffusion plates based on Green-Naghdi theory

2017

Abstract This article is concerned with bending plate theory for thermoelastic diffusion materials under Green-Naghdi theory. First, we present the basic equations which characterize the bending of thin thermoelastic diffusion plates for type II and III models. The theory allows for the effect of transverse shear deformation without any shear correction factor, and permits the propagation of waves at a finite speed without energy dissipation for type II model and with energy dissipation for type III model. By the semigroup theory of linear operators, we prove the well-posedness of the both models and the asymptotic behavior of the solutions of type III model. For unbounded plate of type III…

RISQUE ASSOCIE A L'UTILISATION DE LA LOI DE BENFORD POUR DETECTER DES VENTES FRAUDULEUSES DE BIENS INNOVANTS A LA MODE

2010

Benford's law has been promoted as providing the auditors with a turnkey solution for fraud detection. The purpose of this paper is to show it is not always possible to detect fraudulent sales with that law. We use sales in volume of game consoles in Japan (since 1989), in United-States, in France, in Germany and in United-Kingdom (since 2000). After reviewing briefly the literature and our study design, the chi-square test and the bias analysis were used to measure the goodness-of-fit to Benford's law. Despite the absence of actual fraud, these sale series of fashion goods are not significantly in conformity with Benford's law. Thus, for the detection of fraudulent sales in this sector, th…

Visual category representations in the infant brain

2021

SUMMARYVisual categorization is a human core cognitive capacity1,2that depends on the development of visual category representations in the infant brain3–7. However, the exact nature of infant visual category representations and their relationship to the corresponding adult form remains unknown8. Our results clarify the nature of visual category representations from electroencephalography (EEG) data in 6- to 8-month-old infants and their developmental trajectory towards adult maturity in the key characteristics of temporal dynamics2,9, representational format10–12, and spectral properties13,14. Temporal dynamics change from slowly emerging, developing representations in infants to quickly e…

Management diversity begets biodiversity in production forest landscapes

2022

How to manage forest for biodiversity conservation is an ongoing debate. We argue that maximizing biodiversity in managed forest landscapes requires a diversity of forest management regimes in space and time. This will generate high levels of habitat heterogeneity at a landscape scale, which in turn will support various groups of forest species. Based on concepts from landscape ecology, we formulate five hypotheses on how management diversity, i.e. combining various management approaches can benefit overall biodiversity across a production forest landscape. First, management diversity will increase habitat diversity and, therefore, beta diversity (the habitat diversity hypothesis). Second, …

Ring transformation of furfural into an unusual bicyclic system: Characterisation and dynamic stereochemistry of 6,7-diethoxycarbonyl-6,7-diaza-8-oxa…

1997

Abstract 2-Formylthiophene and 3-formylindole react with diethyl azodicarboxylate to give simple products derived from reactions on the formyl group whereas 2-formylfuran reacts to give the unexpected bicyclic title compound. 1 H and 13 C NMR studies indicate that this compound undergoes a series of three dynamic conformational changes over the temperature range 50 to −90°C which are ascribed to slow rotation about the exocyclic carbamate bonds and hindered bridge inversion.

IWCFTA2012 Keynote Speech I - Hidden attractors in dynamical systems: From hidden oscillation in Hilbert-Kolmogorov, Aizerman and Kalman problems to …

2012

Summary form only given. In this survey an attempt is made to reflect the current trends in the synthesis of analytical and numerical methods to develop efficient analytical-numerical methods, based on harmonic linearization, applied bifurcation theory and numerical methods, for searching hidden oscillations.

Attracteurs et bifurcations en dynamique holomorphe

2019

Uncertainty on w from large-scale structure

2012

We find that if we live at the center of an inhomogeneity with total density contrast of roughly 0.1, dark energy is not a cosmological constant at 95% confidence level. Observational constraints on the equation of state of dark energy, w, depend strongly on the local matter density around the observer. We model the local inhomogeneity with an exact spherically symmetric solution which features a pressureless matter component and a dark-energy fluid with constant equation of state and negligible sound speed, that reaches a homogeneous solution at finite radius. We fit this model to observations of the local expansion rate, distant supernovae and the cosmic microwave background. We conclude …

Tracking Changes in Protonation and Conformation during Photoactivation of a Phytochrome Protein

2016

Phytochromes are photosensor proteins in plants and bacteria. The biological response is mediated by structural changes that follow photon absorption in the protein complex. The initial step is the photoisomerization of the biliverdin chromophore. How this leads to large-scale structural changes of the whole complex is, however, poorly understood. In this work, we use molecular dynamics (MD) simulations to investigate the structural changes after isomerization. In particular, we perform MD simulations at constant pH, using a recently developed method, to explore the effect of chromophore isomerization on the protonation (pKa) of nearby residues. In addition, we use a hybrid quantum mechanic…