Search results for "Détecteurs"
showing 3 items of 3 documents
Synthèse de ligands macrocycliques comportant des fragments aromatiques et leur application pour la détection des cations métalliques
2011
The PhD thesis deals with the synthesis of polyazaligands using Pd-catalyzed amination of aryl halides. The manuscript consists of two parts. In the first part the scope of the Pd-catalyzed amination reaction for the synthesis of polyazamacrocyclic ligands is studied. The Pd-catalyzed amination of 2,7-dibromonaphthalene, 3,3’-dibromobiphenyl and 6,6’-dibromo-2,2’-bipyridyl with linear polyamines and oxadiamines is thoroughly investigated, and corresponding nitrogen- and oxygen-containing macrocycles is synthesized in yields up to 45%. The dependence of the formation of macrocycles and cyclic oligomers on the nature of the starting compounds is established. Two alternative approaches to cycl…
Génération et détection d'électrons chauds dans des dispositifs plasmoniques
2021
Hot carrier-based devices are quite promissing for ultrafast photodetection and toset off enhanced physicochemical reactions. Controlling their generation at the nanoscale within plasmonic devices is a key for the future development of hybrid hot carriers technologies. Indeed, Surface PlasmonPolaritons (SPPs) can be exploited to confine light and enhance the number of excited hot carriers. We aim at studying the excitation and dynamics of hot carriers, enhanced by plasmonics, with two different approaches.In a first approach, we aim at controlling the delocalized generation of hot carriers by a propagative SPP. A plasmonic waveguide with a grating coupler is employed. Hot electrons are indi…
DEFINITION ET ETUDE DES PERFORMANCES D'UN DETECTEUR DE STRUCTURES CURVILINEAIRES. APPLICATION A LA STEREOSCOPIE ET LA DETECTION D'OBJETS FILAIRES
2008
The work presented in this paper falls under the domain of matching. In this context, we try to show the interest of using the curvilinear regions in order to enhance the global performance of various matching applications. A brand new detector for curvilinear regions is introduced (CRD), along with the specific curvilinear regions descriptor (CRD) required. Performance evaluations were done in two parts: First, we evaluated and compared the segmentations performances of our detector, in particular on a retina vessels segmentation application. And second, we estimated the matching performances using K. Mykolajczyk toolkit. This methodology helps obtaining intrinsic performances and comparin…