Search results for "E Conversion"

Sodium Congener of the Classical Lithium Methylchromate Dimer: Synthetic, X-ray Crystallographic, and Magnetic Studies of Me8Cr2[Na(OEt2)]4

2011

One of the milestone structures in the development of transition-metal complexes with metal metal bonds of multiple bond order was the lithium methylchromate dimer Me8Cr2[Li(donor)](4) (donor = THF or Et2O). Using a simple salt metathesis reaction mixing this compound with sodium tert-butoxide, the sodium congener Me8Cr2-[Na(OEt2)]4 has been synthesized as a green crystalline compound and isolated in 51% yield. Its solid-state structure was determined by single-crystal X-ray diffraction. Exhibiting exact crystallographic C-4h symmetry, this heavier alkali-metal chromate structure is also dimeric, formally comprising a (Me8Cr4)(4-) tetranionic core with four peripheral Na+ cations carrying s…

A stacked interleaved DC-DC buck converter for proton exchange membrane electrolyzer applications: Design and experimental validation

2019

Abstract Since the two last decades, hydrogen production has been attracting the attention of the scientific community thanks to its inherent very low pollution when energy coming from renewable energy sources (RESs) are used. However, it implies the use of DC/DC converters to interface source and load. These conversion systems must meet several requirements from current ripple point of view, energy efficiency, and performance to preserve the sustainability of hydrogen production. This article proposes the design and realization of a stacked interleaved buck converter to supply a proton exchange membrane electrolyzer. The converter is designed to ensure a low output current ripple and a sui…

Concerted Evolution of Multigene Families and Homoeologous Recombination

2012

The dynamism of genomes is one of the most thoroughly documented paradigms in the genomic era, envisaged by the cytogenetic school during middle decades of the twentieth century. Such dynamism refers not just to the evolutionary changes that take place across deep time but also to the myriad changes at different levels (from SNPs to large structural rearrangements) that shape and adjust genomes over a smaller time scale. This chapter reviews two of the many forces that provide genome dynamism in plants. These two forces, concerted evolution of multigene families and homoeologous recombination of hybridized genomes, in principle contribute to shape the plant genomes through opposite effects …

Déclaration et vérification des créances. Portée d'une seconde déclaration superfétatoire après conversion d'un redressement judiciaire en liquidatio…

2012

International audience; (Com., 31 mai 2011, n° 10-11.723, arrêt n° 520 F-D, Mme X. ès qual. c/ Sté Gallet, D. 2011. 1614, obs. A. Lienhard)

POSS-Al-porphyrin-imidazolium cross-linked network as catalytic bifunctional platform for the conversion of CO2 with epoxides

2023

Two heterogeneous catalysts were prepared with the aim of following the promising path of CO2 fixation into epoxides. The synthetic procedure involves a radical copolymerization of an octavinylsilsesquioxane as inorganic core building block and tetrastyrylporphyrin aluminum chloride monomer (TSP-AlCl) in presence (POSS-TSP-AlCl-imiBr) or in absence (POSS-TSP-AlCl) of a bis-vinylimidazolium bromide salt (bis-imiBr), in order to investigate if the bifunctional heterogeneous material can display better catalytic performance than the separate species. All the solids were fully characterized and tested in the synthesis of cyclic carbonates starting from CO2 and several epoxides. The synergic coo…

A cluster of cuticle protein genes of Drosophila melanogaster at 65A: sequence, structure and evolution

1997

0016-6731 (Print) Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.; A 36-kb genomic DNA segment of the Drosophila melanogaster genome containing 12 clustered cuticle genes has been mapped and partially sequenced. The cluster maps at 65A 5-6 on the left arm of the third chromosome, in agreement with the previously determined location of a putative cluster encompassing the genes for the third instar larval cuticle proteins LCP5, LCP6 and LCP8. This cluster is the largest cuticle gene cluster discovered to date and shows a number of surprising features that explain in part the genetic complexity of the LCP5, LCP6 and LCP8 loci. The genes encoding LCP5 a…

Conversion of carbohydrates into 5-HMF in Deep Eutectic Solvents under mild reaction conditions

Genetic basis of human complement C4A deficiency. Detection of a point mutation leading to nonexpression.

1993

Abstract The fourth component of the human complement system (C4) is coded for by two genes, C4A and C4B, located within the MHC. Null alleles of C4 (C4Q0) are defined by the absence of C4 protein in plasma. These null alleles are due either to large gene deletions or to nonexpression of the respective genes. In a previous study, evidence was obtained for nonexpressed defective genes at the C4A locus, and for gene conversion at the C4B locus. To further characterize the molecular basis of these non-expressed C4A genes, we selected nine pairs of PCR primers from flanking genomic intron sequences to amplify all 41 exons from individuals with a defective C4A gene. The amplified products were s…

Imidazolium-Functionalized Carbon Nanohorns for the Conversion of Carbon Dioxide

2016

Six new hybrid materials composed of carbon nanohorns (CNHs) and highly cross-linked imidazolium salts were easily synthesized using a one-step procedure based on the radical oligomerization of bis-vinylimidazolium salts (bVImiX) in the presence of pristine CNHs. The hybrid materials were characterized and employed as the sole catalysts for the conversion of carbon dioxide into cyclic carbonate by reaction with epoxides. The solids displayed excellent turnover number and productivity. Moreover, four catalysts were investigated in recycling experiments. Two catalysts containing an octyl linker between the imidazolium units and a bromide or an iodide anion showed no loss in activity after thr…

Exothermic adsorption of chromate by goethite

2020

Abstract Goethite is a common Fe oxyhydroxide coating soil particle surfaces, which has a high Cr(VI) adsorption capacity under acidic pH conditions. Batch equilibrium adsorption experiments with chromate concentrations of 0.1, 0.2, and 0.3 mM were performed using solutions with ionic strengths of 0.1, 0.05, and 0.01 M and pH values of 3–11 and at four temperatures between 10 and 75 °C. The results of these experiments show that the amount of chromate adsorbed decreases as the pH increases towards the zero-point-of-surface-charge of goethite (pHPZC 9.1), which is typical for anions. The chromate adsorption efficiency also depends on the ionic strength of the solution. The amount of chromate…