Search results for "EFFICIENT"
showing 10 items of 1603 documents
Evaluation of the Complexity of Myocardial Activation During Ventricular Fibrillation. An Experimental Study
2013
A B S T R A C T Introduction and objectives: An experimental model is used to analyze the characteristics of ventricular fibrillation in situations of variable complexity, establishing relationships among the data produced by different methods for analyzing the arrhythmia. Methods: In 27 isolated rabbit heart preparations studied under the action of drugs (propranolol and KB-R7943) or physical procedures (stretching) that produce different degrees of change in the complexity of myocardial activation during ventricular fibrillation, use was made of spectral, morphological, and mapping techniques to process the recordings obtained with epicardial multielectrodes. Results: The complexity of ve…
Direct arylation of heteroaromatic compounds with congested, functionalised aryl bromides at low palladium/triphosphane catalyst loading.
2011
International audience; A new ferrocenyl triphosphane ligand associated to palladium was found to be an efficient catalyst for the direct coupling of highly congested, functionalised aryl bromides with a variety of heteroarenes. These coupling reactions can generally be performed by using a low-loading (0.1-0.5 mol%) of the catalyst. The present protocol tolerates important and useful functional groups, which allows for further elaboration into more sophisticated heterocyclic molecules. The straightforward arylation of heteroaromatic compounds with congested ortho-substituted aryl bromides may permit further convergent syntheses of diverse ligands, biologically active molecules and molecula…
Palladium-catalyzed heteroaryl thioethers synthesis overcoming palladium dithiolate resting states inertness: Practical road to sulfones and NH-sulfo…
2018
International audience; We provide efficient synthetic access to heteroaryl sulfones in two-steps using a simple palladium-1,1'-bis [(diphenyl)phosphanyl]ferrocene catalyst to form in high yields variously functionalized heteroaromatic thioethers. Pyridinyl-containing substrates can be subsequently selectively oxidized into sulfones and NH-sulfoximines by using very mild oxidation conditions with a high functional group tolerance. In the palladium catalyzed C-S coupling of heteroaromatic thiols, reactivity limitation is attached with electron-deficient thiols. We show that this limitation can be resolved by the successful use of 2-bromoheteroarenes in the C-S coupling. We established herein…
Energy efficiency improvement in hospital buildings, based on the example of a selected type of hospital facility in Poland
2019
Abstract Energy demand in hospitals is of highly diverse nature: heat energy, cool energy and electricity. A guarantee of energy supply is required to ensure continuity of medical procedures. Taking care of the lowest possible costs of hospital operations, special attention should be paid to energy efficiency of the installations used in the hospital buildings. The paper presents an analysis of energy demand for heating, cooling, ventilation and lighting in an example hospital in Poland. The selected object was considered a reference as it was built according to a repetitive construction plan, according to which several dozen other hospitals were built in Poland. On the basis of data from 2…
Thermodynamic studies of octyltrimethylammonium chloride in water
1992
Densities, heat capacities, enthalpies of dilution at 298 K and osmotic coefficients at 310 K of octyltrimethylammonium chloride were measured as functions of concentration. From the experimental data, the partial molar volumes, heat capacities, relative enthalpies, nonideal free energies and entropies at 298 K were derived as functions of concentration. A comparison between the above data and those of dodecyltrimethylammonium chloride reported in the literature shows that the increase of the alkyl chain length shifts the apparent molar volumevs. concentration curves towards greater values and the heat capacity, relative enthalpy and free energyvs. concentration curves towards smaller value…
SSPMO: A Scatter Tabu Search Procedure for Non-Linear Multiobjective Optimization
2007
We describe the development and testing of a metaheuristic procedure, based on the scatter-search methodology, for the problem of approximating the efficient frontier of nonlinear multiobjective optimization problems with continuous variables. Recent applications of scatter search have shown its merit as a global optimization technique for single-objective problems. However, the application of scatter search to multiobjective optimization problems has not been fully explored in the literature. We test the proposed procedure on a suite of problems that have been used extensively in multiobjective optimization. Additional tests are performed on instances that are an extension of those consid…
Optimization of hybrid – ground coupled and air source – heat pump systems in combination with thermal storage
2010
Ground coupled heat pumps are attractive solutions for cooling and heating commercial buildings due to their high efficiency and their reduced environmental impact. Two possible ideas to improve the efficiency of these systems are decoupling energy generation from energy distribution and combining different HVAC systems. Based on these two ideas, we present several HVAC configurations which combine the following equipments: a ground coupled heat pump, an air to water heat pump and a thermal storage device. These HVAC configurations are linked to an office building in a cooling dominated area in order to evaluate in these conditions the total electrical consumption of each configuration to o…
ESR study of the liposome membrane physical parameters in the heating-cooling cycles.
1998
Abstract Changes of dynamic and structural parameters of egg yolk lecithin (EYL) liposome membranes in the heating-cooling cycles have been studied using the E S R spin probe method. The investigations were conducted in the range of temperatures from -18 °C to +60 °C. It has been found that in the range of temperatures -15 °C to +45 °C in both the heating and the cooling run the spectroscopic parameters changed practically along the same curve (reversible changes). However, after exceeding this range of temperatures one of the parameters (partition coefficient of the spin probe 2,2,6,6 -tetramethylpiperidine -1-oxyl; TEMPO) changed along a closed curve, showing the phenomenon of thermal h…
Uniqueness, reconstruction and stability for an inverse problem of a semi-linear wave equation
2022
We consider the recovery of a potential associated with a semi-linear wave equation on Rn+1, n > 1. We show that an unknown potential a(x, t) of the wave equation ???u + aum = 0 can be recovered in a H & ouml;lder stable way from the map u|onnx[0,T] ???-> (11, avu|ac >= x[0,T])L2(oc >= x[0,T]). This data is equivalent to the inner product of the Dirichlet-to-Neumann map with a measurement function ???. We also prove similar stability result for the recovery of a when there is noise added to the boundary data. The method we use is constructive and it is based on the higher order linearization. As a consequence, we also get a uniqueness result. We also give a detailed presentation of the forw…
Evaluation of the MOD16A2 evapotranspiration product in an agricultural area of Argentina, the Pampas region
2021
The Pampas Region is a big plain of approximately 520,000 km2 in Argentina. It is essential to estimate evapotranspiration (ET) in this region since the primary productivity is directly linked to water availability. Information provided by satellite missions allows monitoring the spatial and temporal variability of ET. In the current study, we evaluated the version 006 of MOD16A2 product (MOD16A2.006) of Potential Evapotranspiration (ETp) and Actual Evapotranspiration (ETa) in Argentinian Pampas Region (APR). MOD16A2.006 product was compared with Crop Evapotranspiration (ETc), calculated with local measurements from the Oficina de Riesgo Agropecuario (ORA), and Crop Coefficient (Kc) data (f…