Search results for "EMT"
showing 10 items of 413 documents
Dual Luminescence, Interligand Decay, and Nonradiative Electronic Relaxation of Cyclometalated Iridium Complexes in Solution
2016
Femtosecond broadband photoluminescence studies are presented for Ir(ppy)3 (Ir1), Ir(ppy)2(pic) (Ir2), Ir(ppy)2(bpy)(PF6) (Ir3), Ir(ppz)3 (Ir4), and Ir(ppz)2dipy (Ir5) (where ppy = 2-phenylpyridine, pic = picolinate, bpy = 2,2′-bipyridine, ppz = 1-phenylpyrazole, and dipy = 5-phenyldipyrrinato) in solution. Upon 400-nm excitation of Ir1–Ir3, we observed a prompt population of the lowest MLCT states. The higher states decay on an ultrafast time scale (3MLCT state undergoes further vibrational relaxation on a 1-ps time scale. In Ir3, this relaxation is accompanied by an interligand decay from the ppy to the bpy ligand in ∼1.5 ps. For the ppy-containing complexes (Ir1 and Ir2), we found that, …
Carbon Nanodots: A Review—From the Current Understanding of the Fundamental Photophysics to the Full Control of the Optical Response
2018
Carbon dots (CDs) are an emerging family of nanosystems displaying a range of fascinating properties. Broadly speaking, they can be described as small, surface-functionalized carbonaceous nanoparticles characterized by an intense and tunable fluorescence, a marked sensitivity to the environment and a range of interesting photochemical properties. CDs are currently the subject of very intense research, motivated by their possible applications in many fields, including bioimaging, solar energy harvesting, nanosensing, light-emitting devices and photocatalyis. This review covers the latest advancements in the field of CDs, with a focus on the fundamental understanding of their key photophysica…
Laser wavelength effects on the refractive index change of waveguides written by femtosecond pulses in silica glasses
2018
We investigate the influence of two fs-laser wavelengths (343 and 800 nm) on the induced refractive index change (Δn) of waveguides written in silica materials. Results show that Δn is higher for waveguides photo-inscribed with UV photons.
Relaxation processes of point defects in vitreous silica from femtosecond to nanoseconds
2008
We studied ultrafast relaxation of localized excited states at Ge-related oxygen deficient centers in silica using femtosecond transient-absorption spectroscopy. The relaxation dynamics exhibits a biexponential decay, which we ascribe to the departure from the Frank-Condon region of the first excited singlet state in 240 fs, followed by cooling in ∼10 ps. At later times, a nonexponential relaxation spanning up to 40 ns occurs, which is fitted with an inhomogeneous distribution of nonradiative relaxation rates, following a chi-square distribution with one degree of freedom. This reveals several analogies with phenomena such as neutron reactions, quantum dot blinking, or intramolecular vibrat…
Polarization shaping for unidirectional rotational motion of molecules.
2015
Control of the orientation of the angular momentum of linear molecules is demonstrated by means of laser polarization shaping. For this purpose, we combine two orthogonally polarized and partially time-overlapped femtosecond laser pulses so as to produce a spinning linear polarization which in turn induces unidirectional rotation of N2 molecules. The evolution of the rotational response is probed by a third laser beam that can be either linearly or circularly polarized. The physical observable is the frequency shift imparted to the probe beam as a manifestation of the angular Doppler effect. Our experimental results are confirmed by theoretical computations, which allow one to gain a deep p…
Field-free molecular alignment for probing collisional relaxation dynamics
2013
International audience; We report the experimental study of field-free molecular alignment in CO2 gas mixtures induced by intense femtosecond laser pulses in the presence of collisional processes. We demonstrate that the alignment signals exhibit specific features due to nontrivial collisional propensity rules that tend to preserve the orientation of the rotational angular momentum of the molecules. The analysis is performed with a quantum approach based on the modeling of rotational J- and M-dependent state-to-state transfer rates. The present work paves the way for strong-field spectroscopy of collisional dynamics.
Field Emission of Electrons Generated by the Near Field of Strongly Coupled Plasmons
2012
Field emission of electrons is generated solely by the ultrastrong near-field of strongly coupled plasmons without the help of a noticeable dc field. Strongly coupled plasmons are excited at Au nanoparticles in subnanometer distance to a Au film by femtosecond laser pulses. Field-emitted electrons from individual nanoparticles are detected by means of photoelectron emission microscopy and spectroscopy. The dependence of total electron yield and kinetic energy on the laser power proves that field emission is the underlying emission process. We derive a dynamic version of the Fowler-Nordheim equation that yields perfect agreement with the experiment.
Postpulse molecular alignment measured by a weak field polarization technique
2003
We report a direct nonintrusive observation of alignment and planar delocalization of ${\mathrm{C}\mathrm{O}}_{2}$ after an intense linearly polarized femtosecond laser pulse excitation. The effects are measured by a polarization technique involving a perturbative probe that itself does not induce appreciable alignment. We show that this technique allows one to measure a signal proportional to $⟨{cos}^{2}\ensuremath{\theta}⟩\ensuremath{-}1/3$, with $\ensuremath{\theta}$ the angle between the molecular axis and the laser polarization. Simulations that support this analysis allow one to characterize the experimentally observed alignment and planar delocalization quantitatively.
Achromatic diffraction of femtosecond light pulses
2003
Diffraction of electromagnetic waves in free space is a physical phenomenon that explicitly depends on the wavelength of light radiation. As an ultrashort-pulsed waveform consists of many frequency components that are coherently superposed, diffraction of a femtosecond pulse passing through an aperture radically differs from that under continuous wave (CW) monochromatic illumination. Note that the spectral width of a 5 fs pulsed beam is approximately 400 nm, which roughly corresponds to the entire visible spectrum bandwidth. The spectral distribution of the source results in the chromatic distortion, both lateral and axial, of the optical field diffracted by the aperture. This detrimental e…
Dispersion-compensated beam-splitting of femtosecond light pulses: Wave optics analysis
2007
Recently, using parageometrical optics concepts, a hybrid, diffractive-refractive, lens triplet has been suggested to significantly improve the spatiotemporal resolution of light spots in multifocal processing with femtosecond laser pulses. Here, we carry out a rigorous wave-optics analysis, including the spatiotemporal nature of the wave equation, to elucidate both the spatial extent of the diffractive spots and the temporal duration of the pulse at the output plane. Specifically, we show nearly transform-limited behavior of diffraction maxima. Moreover, the temporal broadening of the pulse is related to the group velocity dispersion, which can be pre-compensated for in practical applicati…