Search results for "ENSEMBLES"
showing 10 items of 22 documents
How do presenters engage with their audience? Speakers multimodal interpersonal behaviour in research dissemination talks
2020
Abstract Speakers in research dissemination talks are challenged with the need to connect with an audience that does not necessarily share their knowledge and expertise. This communicative situation can be particularly challenging for speakers using English both as a foreign language and for academic purposes. This study combines multimodal and ethnographic methods to explore how speakers of dissemination talks engage with their public. It focuses on four presenters’ use and combination of language, paralanguage, kinesics, proxemics and gaze during intensive moments of engagement. The results show that these interpersonal rich points consist of dense multimodal ensembles that serve to short…
Accurate estimation of retinal vessel width using bagged decision trees and an extended multiresolution Hermite model.
2012
We present an algorithm estimating the width of retinal vessels in fundus camera images. The algorithm uses a novel parametric surface model of the cross-sectional intensities of vessels, and ensembles of bagged decision trees to estimate the local width from the parameters of the best-fit surface. We report comparative tests with REVIEW, currently the public database of reference for retinal width estimation, containing 16 images with 193 annotated vessel segments and 5066 profile points annotated manually by three independent experts. Comparative tests are reported also with our own set of 378 vessel widths selected sparsely in 38 images from the Tayside Scotland diabetic retinopathy scre…
Bagging and Boosting with Dynamic Integration of Classifiers
2000
One approach in classification tasks is to use machine learning techniques to derive classifiers using learning instances. The co-operation of several base classifiers as a decision committee has succeeded to reduce classification error. The main current decision committee learning approaches boosting and bagging use resampling with the training set and they can be used with different machine learning techniques which derive base classifiers. Boosting uses a kind of weighted voting and bagging uses equal weight voting as a combining method. Both do not take into account the local aspects that the base classifiers may have inside the problem space. We have proposed a dynamic integration tech…
Contribution to variational analysis : stability of tangent and normal cones and convexity of Chebyshev sets
2014
The aim of this thesis is to study the following three problems: 1) We are concerned with the behavior of normal cones and subdifferentials with respect to two types of convergence of sets and functions: Mosco and Attouch-Wets convergences. Our analysis is devoted to proximal, Fréchet, and Mordukhovich limiting normal cones and subdifferentials. The results obtained can be seen as extensions of Attouch theorem to the context of non-convex functions on locally uniformly convex Banach space. 2) For a given bornology β on a Banach space X we are interested in the validity of the following "lim inf" formula (…).Here Tβ(C; x) and Tc(C; x) denote the β-tangent cone and the Clarke tangent cone to …
Inverse Conformational Selection in Lipid–Protein Binding
2021
International audience; Interest in lipid interactions with proteins and other biomolecules is emerging not only in fundamental biochemistry but also in the field of nanobiotechnology where lipids are commonly used, for example, in carriers of mRNA vaccines. The outward-facing components of cellular membranes and lipid nanoparticles, the lipid headgroups, regulate membrane interactions with approaching substances, such as proteins, drugs, RNA, or viruses. Because lipid headgroup conformational ensembles have not been experimentally determined in physiologically relevant conditions, an essential question about their interactions with other biomolecules remains unanswered: Do headgroups excha…
Topological effects of a rigid chiral spacer on the electronic interactions in donor-acceptor ensembles
2005
Two triads (donor-spacer-acceptor), etTTF-BN-C 6 0 (6) and ZnP-BN-C 6 0 (7), in which electron donors (i.e., exTTF or ZnP) are covalently linked to C 6 0 through a chiral binaphthyl bridge (BN), have been prepared in a multistep synthetic procedure starting from a highly soluble enantiomerically pure binaphthyl building block (1). Unlike other oligomeric bridges, with hinaphthyl bridges, the conjugation between the donor and the acceptor units is broken and geometric conformational changes are facilitated. Consequently, distances and electronic interactions between the donor and C 6 0 are drastically changed. Both donor-spacer-acceptor (D-s-A) systems (i.e., 6 and 7) exhibit redox processes…
Entanglement dynamics and relaxation in a few-qubit system interacting with random collisions
2008
The dynamics of a single qubit interacting by a sequence of pairwise collisions with an environment consisting of just two more qubits is analyzed. Each collision is modeled in terms of a random unitary operator with a uniform probability distribution described by the uniform Haar measure. We show that the purity of the system qubit as well as the bipartite and the tripartite entanglement reach time averaged equilibrium values characterized by large instantaneous fluctuations.These equilibrium values are independent of the order of collision among the qubits. The relaxation to equilibrium is analyzed also in terms of an ensemble average of random collision histories. Such average allows for…
Solid film versus solution-phase charge-recombination dynamics of exTTF-bridge-C60 dyads.
2005
The charge-recombination dynamics of two exTTF-C 6 0 dyads (exTTF=9,10-bis(l,3-dithiol-2-ylidene)-9,10-dihydroanthracene), observed after photoinduced charge separation, are compared in solution and in the solid state. The dyads differ only in the degree of conjugation of the bridge between the donor (exTTF) and the acceptor (C 6 0 ) moieties. In solution, photoexcitation of the nonconjugated dyad C 6 0 -BN-exTTF (1) (BN=1,1'-binaphthyl) shows slower charge-recombination dynamics compared with the conjugated dyad C 6 0 -TVB-exTTF (2) (TVB = bisthienylvinylenebenzene) (lifetimes of 24 and 0.6 μs, respectively), consistent with the expected stronger electronic coupling in the conjugated dyad.…
Recent Exploits of the ISOLTRAP Mass Spectrometer
2013
Abstract The Penning-trap mass spectrometer ISOLTRAP, located at the isotope-separator facility ISOLDE (CERN), is presented in its current form taking into account technical developments since 2007. Three areas of developments are presented. The reference ion sources have been modified to guarantee a sufficient supply of reference ions for mass measurements and systematic studies. Different excitation schemes have been investigated for manipulation of the ion motion in the Penning trap, to enhance either the purification or measurement process. A multi-reflection time-of-flight mass separator has been implemented and can now be routinely used for purification and as a versatile tool for bea…
Probing molecular wire: synthesis of donor-acceptor ensembles exhibiting long range electron transfer
2005
A series of donor–acceptor arrays (C60–oligo-PPV–exTTF; 16–20) incorporating p-conjugated oligo(phenylenevinylene) wires (oligo-PPV) of different length between p-extended tetrathiafulvalene (exTTF) as electron donor and C60 as electron acceptor has been prepared by multistep convergent synthetic approaches. The electronic interactions between the three electroactive species present in 16–20 were investigated by UV-visible spectroscopy and cyclic voltammetry (CV). Our studies clearly show that, although the C60 units are connected to the exTTF donors through a p-conjugated oligo- PPV framework, no significant electronic interactions are observed in the ground state. Interestingly, photoindu…