Search results for "EPOXY"
showing 10 items of 384 documents
Experimental design of the bearing performances of flax fiber reinforced epoxy composites by a failure map
2018
Abstract This paper represents the first effort aimed to the investigation of the pin/hole contact stress and failure mechanisms of epoxy composites reinforced with woven flax fabrics, underwent to tensile bearing tests. In particular, the maximum loads and failure modes are evaluated at varying the laminate geometrical configuration. In order to optimize the use of polymer composites reinforced with flax fibers in structural applications, an experimental failure map, identifying main failure modes of mechanically fastened joints, is obtained as function of hole diameter, distance of the hole from the free edge of the laminate and laminate width. Moreover, a theoretical approach based on th…
Influence of different parameters on drug release from hydrogel systems to a biomembrane model. Evaluation by differential scanning calorimetry techn…
2000
A comparative study on the drug release capacity of four water swellable polymeric systems was carried out by differential scanning calorimetry (DSC). The polymeric systems chosen were alpha,beta-polyaspartahydrazide (PAHy) crosslinked by glutaraldehyde (GLU) (PAHy-GLU) or by ethyleneglycoldiglycidylether (EGDGE), (PAHy-EGDGE), polyvinylalcohol (PVA) crosslinked by glutaraldehyde (PVA-GLU) and alpha,beta-poly(N-hydroxyethyl)-DL-aspartamide (PHEA) by gamma irradiation (PHEA-gamma matrices). The degree of crosslinking for PAHy-GLU, PAHy-EGDGE and PVA-GLU samples was about 0.4 and 0.8. These hydrogels were characterized as free of drugs and were loaded with diflunisal (DFN) (approximately 2.5%…
Micromechanisms of load transfer in a unidirectional carbon fibre–reinforced epoxy composite due to fibre failures. Part 1: Micromechanisms and 3D an…
2006
This study gives a detailed analysis of load distributions around fibre breaks in a composite and the mechanisms involved in load transfer. In contrast to other studies reported in the literature the analysis considers different configurations of composite damage from the failure of a few fibres to the failure of many. The model considers the elastic case with and without debonding at the broken fibre/matrix interface. In this way, the usual limitations of the finite element approach are overcome so as to take into account the numbers and interactions of broken fibres whilst maintaining an evaluation of the various fields involved, in particular the stress fields associated with fibre failu…
Effects of powder concentration and type of resin on the performance of marble composite structures
2009
In this work, we will expose the behaviour of a composite structure reinforced with marble powder. The attention was focused on the effects produced on the physical and mechanical properties due to different kinds of matrix (epoxy and polyester resins) and filler amounts (60%, 70%, 80%). Rheological, static flexural and Izod impact tests have been carried out. An experiment designed was defined for the mechanical tests, in order to quantify the effects of both the resin and the marble percentage on the material properties, as well as to identify a possible correlation between these factors. Moreover, water absorption and stain resistance have been evaluated to study the surface properties o…
Fracture toughness of synthesised high-performance epoxies subject to accelerated water aging
2018
Abstract The effects of water uptake on the fracture toughness of epoxy systems with high glass-transition temperatures (Tg above 170 °C) are investigated. Aging conditioning has been conducted in hot water, followed by a desorption conditioning in a room temperature dry-airborne. Water aging determines plasticisation effects and crosslink-density modifications, revealed by reductions of the Tg. It is less known how such modifications influence the material fracture toughness. In this study, Single Edge Notched Bending samples have been tested according to standards, to evaluate the KIC fracture toughness at different stages of water absorption-desorption. The characterisation has been supp…
Moisture Absorption Effects on the Resistance to Interlaminar Fracture of Woven Glass/Epoxy Composite Laminates
2012
The influence of moisture absorption on the interlaminar fracture behaviour of 8/8 harness satin weave glass/epoxy composite was investigated. Two series of specimens with 0°/0° and 90°/90° predominant interfaces immersed in water for different duration were tested under double cantilever beam (DCB mode I), single leg bending (SLB mode I + II) and end notched flexural (ENF mode II) loadings. In general, the apparent flexural modulus: E, and the fracture toughness: G C, decrease with increasing moisture content. This effect is more remarkable if mode II participation is bigger. The value of G C measured on 90°/90° specimens reveals higher than that on 0°/0° ones, but the variation in G C is …
Carbon Fiber Composites Cured by γ-Radiation-Induced Polymerization of an Epoxy Resin Matrix
2008
The use of ionizing radiation in order to initiate polymerization of suitable monomers has found increased interest in the last two decades due to its several advantages. In this work, carbon fiber composites through gamma radiation polymerization of epoxy matrices have been produced for aerospace and advanced automotive applications. Composite samples were produced by irradiation at room temperature using different radiation doses and, as reference, thermal curing of the same epoxy resin formulations was also carried out. Furthermore, some irradiated samples were subjected to postirradiation thermal curing to complete the polymerization reactions. The properties of the cured materials were…
Anomalous water diffusion in epoxy/carbon nanoparticle composites
2019
Abstract Water absorption-desorption-resorption and swelling were studied for a DGEBA-based amine-cured epoxy resin filled with four types of carbon nanoparticles: multiwall carbon nanotubes (MWCNT), graphite nano-platelets (GnP), expanded graphite platelets, and carbon black. Nanocomposites are characterised by lower diffusivity (down to 20% for epoxy/GnP) and increased water sorption capacity compared to the neat epoxy. Anomalous water absorption and swelling of nanocomposites is finely described by the diffusion-relaxation model. The relaxation times, considered as quantitative indicators of changes in segmental mobility of the polymer, increased with addition of nanoparticles and decrea…
A shear test for structural adhesives used in the consolidation of old timber
2001
A test method was developed specifically for structural adhesives used in thick joints. It is based on compressive shear loading of glued joints (GJ) and solid wood (SW) specimens, before and after a suitable accelerated ageing cycle. The evaluation of results is based on the ratios of wet strength to dry strength and on the comparison of GJ specimens to SW specimens which are prepared from the same batch of wood, in order to minimise the influence of the variability in wood characteristics. On a group of 10 epoxy-based adhesives, specifically marketed for the consolidation of old timber structures, the method has proved to be effective to differentiate the performances of each product. Amo…
Permeability measurements in cobalt ferrite and carbonyl iron powders and suspensions
2002
Abstract Magnetic permeability data of cobalt ferrite and carbonyl iron suspensions are discussed. Using an induction method, the relative differential permeability, μr,dif, was measured as a function of the internal magnetic field for different volume fractions of the solid phase. In the case of cobalt ferrite suspensions, the μr,dif−H curve was obtained for a first increasing ramp of magnetic field (data series “1”), a decreasing ramp (data series “2”), and the second increasing one (data series “3”). Series “1” showed a maximum in the μr,dif−H trend that did not appear in series “2” and “3”. Furthermore, the data in series “2” and “3” are always below those in series “1”. The latter beha…