Search results for "EPOXY"
showing 10 items of 384 documents
Effective electrical conductivity of carbon nanotube–epoxy nanocomposites
2016
The electrical conductivity of carbon nanotube–epoxy composites is investigated analytically and experimentally. The theoretical predictions of the effective electrical conductivity of carbon nanotube–epoxy composites were performed by the analytical approach based on a micromechanical model of composites. The parametric analysis carried out revealed an influence of geometrical and electrical parameters of the micromechanical model on the effective electrical conductivity of carbon nanotube–epoxy nanocomposite. The nanocomposites made from the DGEBA-based and RTM6 epoxy resins filled with different weight content of Baytubes C150P and N7000 multi-walled carbon nanotubes were prepared. The …
Fatigue crack growth of new FML composites for light ship buildings under predominant mode II loading condition
2019
The use of light but strong materials is largely studied in various area of the shipbuilding, this because the need of reducing the weight, and especially the weight of all the structures above the main deck assume primary importance for the stability. Traditionally in fast boats like fast ferries, hydrofoils, patrol boats, the typical materials are Aluminum alloy or composites, both those materials have advantages and disadvantages, but the new development of technologies made possible to combine them, in order to have a new material, combining the advantages of both, in terms of fatigue resistance, firefighting characteristics. In this paper, predominant mode II fatigue delamination tests…
Investigation on fracture of epoxy-filled composites by acoustic emission
2016
Acoustic emission (AE) technique is widely used to monitor failure processes in composite materials includ-ing development of cracks and plastic deformations within the polymer matrix, fracture and debonding of inclusions, etc. In this study, the AE technique was applied investigating failure character of epoxy polymers with different content of nanofiller – fine polyethersulfone (PES) powder. Variation of material properties of the epoxy with 0, 5%, 7.5%, 10%, and 12.5% concentration (by weight) of the PES was assessed experimentally. Correlation between the PES content and the modulus of elasticity was found negligible. The same was characteristic for the tensile strength. Whereas, such a…
An aging evaluation of the bearing performances of glass fiber composite laminate in salt spray fog environment
2019
The aim of the present paper is to assess the bearing performance evolution of pinned, glass-composite laminates due to environmental aging in salt-spray fog tests. Glass fibers/epoxy pinned laminates were exposed for up to 60 days in salt-spraying, foggy environmental conditions (according to ASTM B117 standard). In order to evaluate the relationship between mechanical failure mode and joint stability over increasing aging time, different single lap joints, measured by the changing hole diameter (D), laminate width (W) and hole free edge distance (E), were characterized at varying aging steps. Based on this approach, the property-structure relationship of glass-fibers/epoxy laminates was a…
The influence of the rubber carboxyl functionality on the processability and properties of solid rubber modified epoxy mixtures
2005
A high molecular weight, carboxyl functionalised solid rubber was added to an epoxy resin-aromatic amino system developed for autoclave curing of honeycomb core composite structures. The achievement of an optimal balance of viscous flow and viscoelasticity of the resin, by controlling the nature and extent of cross-linking of the functionalised rubber, was proposed as a route to void-free honeycomb skins. The aim of the present investigation is to understand how the concentration of carboxylic groups of the rubber, prereacted with one of the epoxy monomers, affects the matrix resin flow properties. The concentration of carboxyl groups was changed by reacting them with a monofunctional epoxy…
Aliphatic polycarbonates based on carbon dioxide, furfuryl glycidyl ether, and glycidyl methyl ether: reversible functionalization and cross-linking.
2014
Well-defined poly((furfuryl glycidyl ether)-co-(glycidyl methyl ether) carbonate) (P((FGE-co-GME)C)) copolymers with varying furfuryl glycidyl ether (FGE) content in the range of 26% to 100% are prepared directly from CO2 and the respective epoxides in a solvent-free synthesis. All materials are characterized by size-exclusion chromatography (SEC), (1)H NMR spectroscopy, and differential scanning calorimetry (DSC). The furfuryl-functional samples exhibit monomodal molecular weight distributions with Mw/Mn in the range of 1.16 to 1.43 and molecular weights (Mn) between 2300 and 4300 g mol(-1). Thermal properties reflect the amorphous structure of the polymers. Both post-functionalization and…
Glutathione Conjugation of Bay- and Fjord-Region Diol Epoxides of Polycyclic Aromatic Hydrocarbons by Glutathione Transferases M1-1 and P1-1
1997
Metabolism of polycyclic aromatic hydrocarbons in mammalian cells results in the formation of vicinal diol epoxides considered as ultimate carcinogens if the oxirane ring is located in a bay- or fjord-region of the parent compound. In the present study, individual stereoisomers of the bay-region diol epoxides of chrysene, dibenz[a,h]anthracene, and benzo[a]pyrene as well as of the fjord-region diol epoxides of benzo[c]phenanthrene, benzo[c]chrysene, and benzo[g]-chrysene have been incubated with GSH in the presence of human glutathione transferases GSTM1-1 (a mu-class enzyme) and GSTP1-1 (a pi-class enzyme). As previously shown with GSTA1-1 (an alpha-class enzyme) both M1-1 and P1-1 demonst…
Influence of resin viscosity and vacuum level on mechanical performance of sandwich structures manufactured by vacuum bagging
2010
The choice of process parameters is critical in optimizing the mechanical properties of sandwich structures produced using the vacuum bagging technique. The aim of this paper is to analyze how the viscosity of the resin/curing agent system and the vacuum level influence the morphology and the mechanical behavior of sandwich beams with composite faces (epoxy resin and glass fiber fabric named COMBI 900) and a PVC foam core. Four different sandwich structures were produced by varying the viscosity of the epoxy resin/curing agent at constant maximum vacuum pressure. Three further structures were manufactured by varying the strength of the vacuum with the resin viscosity maintained constant at …
Electric strength, space charge and surface discharge characterization of nanostructured epoxy-silicate insulating materials
2005
A set of surface discharge ageing procedures, space charge observations and dielectric strength measurements has been implemented on a type of insulating nanofilled epoxy-resin (nanostructured by compatibilised synthetic layered silicates) and on its non-filled base resin. Promising improvements in the electrical behaviour of the nanofilled epoxy, particularly as concerns surface discharge endurance, were detected. Regarding space charge, it was found that its accumulation rate as a function of ageing time is lower for the nanostructured resin. Finally, the nanofilled material evidenced a highly homogeneous behaviour of the dielectric strength data distribution.
Hybrid Nanocomposite Coatings for Application in Construction Materials: Tribological Study
2009
The Nanocomposite group of AIDICO and the Nanomaterials Group of University of Valencia collaborate in the research of new organic-inorganic hybrid materials with application in construction products. Tribological properties and good thermal stability are some of the required specifications for such applications. Some hybrid coatings based on simultaneous formation of epoxy and silica networks are introduced in this work. Elastic modulus and hardness obtained from TDMA analyses and indentation techniques, together with thermal stability by TGA, are the main properties analysed in order to fulfil the requirements for construction coating applications. New routes for obtaining these coatings …