Search results for "ESA"

Global modeling of the lower three polyads of PH_{3} Preliminary results

2009

International audience; In order to model the high-resolution infrared spectrum of the phosphine molecule in the 3 mu m region, a global approach involving the lower three polyads of the molecule (Dyad, Pentad and Octad) as been applied using an effective hamiltonian in the form of irreducible tensors. This model allowed to describe all the 15 vibrational states involved and to consider explicitly all relevant ro-vibrational interactions that cannot be accounted for by conventional perturbation approaches. 2245 levels (up to J=14) observed through transitions arising from 34 cold and hot bands including all available existing data as well as new experimental data have been fitted simultaneo…

Calculating pressure with elastic geobarometry: A comparison of different elastic solutions with application to a calc-silicate gneiss from the Rhodo…

2020

Abstract Raman elastic geobarometry has increasingly been used complementary to metamorphic phase equilibria to estimate the conditions of recrystallization in metamorphic rocks. The procedure of applying Raman elastic barometry to host-inclusion mineral systems requires several steps that involve various assumptions. One of the most essential assumptions is that the mineral host-inclusion system behaves in an elastic and reversible manner. We discuss the discrepant results obtained by different authors employing different analytical solutions for elasticity and explore the assumptions lying behind each method. Furthermore, we evaluate numerically linear and non-linear elastic solutions and…

Hyperspectral dimensionality reduction for biophysical variable statistical retrieval

2017

Abstract Current and upcoming airborne and spaceborne imaging spectrometers lead to vast hyperspectral data streams. This scenario calls for automated and optimized spectral dimensionality reduction techniques to enable fast and efficient hyperspectral data processing, such as inferring vegetation properties. In preparation of next generation biophysical variable retrieval methods applicable to hyperspectral data, we present the evaluation of 11 dimensionality reduction (DR) methods in combination with advanced machine learning regression algorithms (MLRAs) for statistical variable retrieval. Two unique hyperspectral datasets were analyzed on the predictive power of DR + MLRA methods to ret…

Top-of-Atmosphere Retrieval of Multiple Crop Traits Using Variational Heteroscedastic Gaussian Processes within a Hybrid Workflow.

2021

In support of cropland monitoring, operational Copernicus Sentinel-2 (S2) data became available globally and can be explored for the retrieval of important crop traits. Based on a hybrid workflow, retrieval models for six essential biochemical and biophysical crop traits were developed for both S2 bottom-of-atmosphere (BOA) L2A and S2 top-of-atmosphere (TOA) L1C data. A variational heteroscedastic Gaussian process regression (VHGPR) algorithm was trained with simulations generated by the combined leaf-canopy reflectance model PROSAILat the BOA scale and further combined with the Second Simulation of a Satellite Signal in the Solar Spectrum (6SV) atmosphere model at the TOA scale. Establishe…

Determination of water speciation in hydrous haplogranitic glasses with partial Raman spectra

2020

Abstract We use a mathematical approach to decompose the Raman water band at 3000 cm−1 to 3750 cm−1 into two partial Raman spectra corresponding to the individual Raman activity of the two water species, i.e., molecular water (H2Om) and OH-groups, present in hydrous rhyolitic glasses. The approach is based on a least-squares optimization algorithm and the assumption that the water band can be expressed as a linear combination of two partial Raman spectra. Our model makes no assumptions regarding the shape of the partial Raman spectra. The model input consists of about 700 Raman spectra from hydrous haplogranitic (HPG8) compositions with total water contents from 0.6 to 3.1 wt% and with know…

Enhancing the retrieval of stream surface temperature from Landsat data

2019

International audience; Thermal images of water bodies often show a radiance gradient perpendicular to the banks. This effect is frequently due to mixed land and water thermal pixels. In the case of the Landsat images, radiance mixing can also affect pure water pixels due the cubic convolution resampling of the native thermal measurements. Some authors recommended a general-purpose margin of two thermal pixels to the banks or a minimum river width of three pixels, to avoid near bank effects in water temperature retrievals. Given the relatively course spatial resolution of satellite thermal sensors, the three pixel margin severely restricts their application to temperature mapping in many ri…

Titan's surface albedo variations over a Titan season from near-infrared CFHT/FTS spectra

2006

International audience; We have observed Titan in a series of campaigns from 1991 to 1996 with the Fourier Transform Spectrometer on the CFH telescope. The data acquired provide a lightcurve from the geometric albedos in the 0.9–View the MathML source spectral region. The 1991–1993 data were previously analyzed in Coustenis et al. [1995. Titan's surface: composition and variability from its near-infrared albedo. Icarus 118, 87–104] with a spherical particle code by McKay et al. [1989. The thermal structure of Titan's atmosphere. Icarus 80, 23–53]. We present here three new datasets from the 1994, 1995 and 1996 observations, with additional information from the 0.94-μm methane window on Tita…

PHYSICS-based retrieval of scattering albedo and vegetation optical depth using multi-sensor data integration

2017

Vegetation optical depth and scattering albedo are crucial parameters within the widely used τ-ω model for passive microwave remote sensing of vegetation and soil. A multi-sensor data integration approach using ICESat lidar vegetation heights and SMAP radar as well as radiometer data enables a direct retrieval of the two parameters on a physics-derived basis. The crucial step within the retrieval methodology is the calculus of the vegetation scattering coefficient KS, where one exact and three approximated solutions are provided. It is shown that, when using the assumption of a randomly oriented volume, the backscatter measurements of the radar provide a sufficient first order estimate and …

High‐resolution stimulated Raman spectroscopy and analysis of line positions and assignments for the ν 2 and ν 3 bands of 13 C 2 H 4

2016

High-resolution stimulated Raman spectra of13C2H4 in the regions of the ν2 and ν3 Raman active modes have been recorded at two temperatures (145 and 296 K) based on the quasi continuous-wave (cw) stimulated Raman spectrometer at Instituto de Estructura de la Materia IEM-CSIC in Madrid. A tensorial formalism adapted to X2Y4 planar asymmetric tops with D2h symmetry (developed in Dijon) and a program suite called D2hTDS (now part of the XTDS/SPVIEW spectroscopic software) were proposed to analyze and calculate the high-resolution spectra. A total of 103 and 51 lines corresponding to ν2 and ν3 Raman active modes have been assigned and fitted in wavenumber with a global root mean square deviatio…

2019

Abstract. The flow of fluids through porous media such as groundwater flow or magma migration is a key process in geological sciences. Flow is controlled by the permeability of the rock; thus, an accurate determination and prediction of its value is of crucial importance. For this reason, permeability has been measured across different scales. As laboratory measurements exhibit a range of limitations, the numerical prediction of permeability at conditions where laboratory experiments struggle has become an important method to complement laboratory approaches. At high resolutions, this prediction becomes computationally very expensive, which makes it crucial to develop methods that maximize …