Search results for "EXCITATION"
showing 10 items of 1290 documents
Directional Second Harmonic Generation Controlled by Sub-wavelength Facets of an Organic Mesowire
2018
Directional harmonic generation is an important property characterizing the ability of nonlinear optical antennas to diffuse the signal in well-defined region of space. Herein, we show how sub-wavelength facets of an organic molecular mesowire crystal can be utilized to systematically vary the directionality of second harmonic generation (SHG) in the forward scattering geometry. We demonstrate this capability on crystalline diamonoanthraquinone (DAAQ) mesowires with subwavelength facets. We observed that the radial angles of the SHG emission can be tuned over a range of 130 degrees. This angular variation arises due to spatially distributed nonlinear dipoles in the focal volume of the excit…
Tuning optical/electrical properties of 2D/3D perovskite by the inclusion of aromatic cation
2018
The employment of bulky aliphatic cations in the manufacture of moisture-stable materials has triggered the development and application of 2D/3D perovskites as sensitizers in moisture-stable solar cells. Although it is true that the moisture stability increases, it is also true that the photovoltaic performance of 2D/3D PVK materials is severely limited owing to quantum and dielectric confinement effects. Accordingly, it is necessary the synthesis and deep optical characterization of materials with an adequate management of dielectric contrast between the layers. Here, we demonstrate the successful tuning of dielectric confinement by the inclusion of a conjugated molecule, as a bulky cation…
In-line fiber-optic sensors based on the excitation of surface plasma modes in metal-coated tapered fibers
2001
Abstract Metal-coated tapered fibers are reported as refractive index sensors based on the resonant excitation of surface plasma modes supported by the metal coating. The devices are easy to fabricate and constitute an alternative to metal-coated side-polished fibers and to other sensors made up of bulk components. We report the fabrication and power transmission properties of quasi-circular devices and asymmetric devices. Both sets of devices can be operated as wavelength output sensors, as well as amplitude output sensors. The transmittance of quasi-circular devices is polarization independent and it changes more than 30 dB as a function of external refractive index.
Ultrafast ionization and rotational dynamics of molecules in strong laser fields
2021
The investigation of ultrafast molecular dynamics is of great importance towards the understanding of a variety of natural phenomena in physical and chemical sciences. With the rapid development of femtosecond laser systems and precision detection technologies, it is possible now to visualize and steer the motion of molecules in matter as well as the ultrafast dynamics of electrons and nuclei in molecules on a microscopic timescale. When a molecule is exposed to a strong laser field, its electrons can be freed or excited, which often triggers a rapid dissociation of the system, in which the released electrons and nuclei exhibit a strong correlation, while the electronic motion on attosecond…
Characterization of nuclear effects in muon-neutrino scattering on hydrocarbon with a measurement of final-state kinematics and correlations in charg…
2018
This paper reports measurements of final-state proton multiplicity, muon and proton kinematics, and their correlations in charged-current pionless neutrino interactions, measured by the T2K ND280 near detector in its plastic scintillator (C$_8$H$_8$) target. The data were taken between years 2010 and 2013, corresponding to approximately 6$\times10^{20}$ protons on target. Thanks to their exploration of the proton kinematics and of kinematic imbalances between the proton and muon kinematics, the results offer a novel probe of the nuclear-medium effects most pertinent to the (sub-)GeV neutrino-nucleus interactions that are used in accelerator-based long-baseline neutrino oscillation measureme…
Ultraprecise Rydberg atomic localization using optical vortices
2020
We propose a robust localization of the highly-excited Rydberg atoms, interacting with doughnut-shaped optical vortices. Compared with the earlier standing-wave (SW)-based localization methods, a vortex beam can provide an ultrahigh-precision two-dimensional localization solely in the zero-intensity center, within a confined excitation region down to the nanometer scale. We show that the presence of the Rydberg-Rydberg interaction permits counter-intuitively much stronger confinement towards a high spatial resolution when it is partially compensated by a suitable detuning. In addition, applying an auxiliary SW modulation to the two-photon detuning allows a three-dimensional confinement of R…
Theoretical investigations of different excitation modes for Penning trap mass spectrometry
2013
Abstract In Penning trap mass spectrometry the motion of trapped ions is manipulated by external radio-frequency fields. This paper describes a general theoretical framework to classify the various types of excitation of the ion's motional modes, to identify the resonance frequencies, and to find the effective interaction Hamiltonians which are valid in the vicinity of the resonances. Instead of Cartesian or cylindrical coordinates and momenta our theoretical approach uses the complex oscillator amplitudes of the cyclotron, magnetron, and axial oscillators as its basic dynamical variables. Equations of motion are set up, which can be simplified in the vicinity of resonances by the resonatin…
High Yield Ultrafast Intramolecular Singlet Exciton Fission in a Quinoidal Bithiophene
2015
We report the process of singlet exciton fission with high-yield upon photoexcitation of a quinoidal thiophene molecule. Efficient ultrafast triplet photogeneration and its yield are determined by photoinduced triplet-triplet absorption, flash photolysis triplet lifetime measurements, as well as by femtosecond time-resolved transient absorption and fluorescence methods. These experiments show that optically excited quinoidal bithiophene molecule undergoes ultrafast formation of the triplet-like state with the lifetime ∼57 μs. CASPT2 and RAS-SF calculations have been performed to support the experimental findings. To date, high singlet fission rates have been reported for crystalline and pol…
Semiactive–passive structural vibration control strategy for adjacent structures under seismic excitation
2012
Abstract The objective of this paper is to study a structural vibration control strategy for seismic protection of multi-structure systems that combines interstructure passive damping elements with local feedback control systems implemented in the substructures. These local feedback control systems are independently designed and operated, and use semiactive devices with limited actuation capacity as force actuators. The combined action of local semiactive feedback control systems and passive interstructure links can produce an appropriate reduction in the substructures' vibrational response and, simultaneously, provides additional protection against interstructure collisions. The proposed s…
Dynamical Stark Effect in the nu(2)/nu(4) Vibrational Polyad of SiH(4): Theory and Observation.
2000
We report a theoretical and experimental investigation of the dynamical Stark effect in a tetrahedral molecule, silane (SiH(4)). We use a tetrahedral formalism and Floquet theory to calculate the absorption spectra for the molecule dressed by an intense nonresonant pulsed laser. Experimentally, the dynamical Stark effect is observed for transitions of the nu(2)/nu(4) vibrational polyad of SiH(4) by means of nanosecond diode laser absorption spectroscopy and a Nd:YAG laser excitation. Copyright 2000 Academic Press.