Search results for "EXPA"
showing 10 items of 820 documents
Orthorhombic Phase of Crystalline Polyethylene: A Monte Carlo Study
1996
In this paper we present a classical Monte Carlo simulation of the orthorhombic phase of crystalline polyethylene, using an explicit atom force field with unconstrained bond lengths and angles and periodic boundary conditions. We used a recently developed algorithm which apart from standard Metropolis local moves employs also global moves consisting of displacements of the center of mass of the whole chains in all three spatial directions as well as rotations of the chains around an axis parallel to the crystallographic c-direction. Our simulations are performed in the NpT ensemble, at zero pressure, and extend over the whole range of temperatures in which the orthorhombic phase is experime…
Ab initiolattice dynamical studies of silicon clathrate frameworks and their negative thermal expansion
2014
The thermal and lattice dynamical properties of seven silicon clathrate framework structures are investigated with ab initio density functional methods (frameworks I, II, IV, V, VII, VIII, and H). The negative thermal expansion (NTE) phenomenon is investigated by means of quasiharmonic approximation and applying it to equal time displacement correlation functions. The thermal properties of the studied clathrate frameworks, excluding the VII framework, resemble those of the crystalline silicon diamond structure. The clathrate framework VII was found to have anomalous NTE temperature range up to 300 K and it is suitable for further studies of the mechanisms of NTE. Investigation of the displa…
Thermodynamic properties at the phase transition of Pb(Zr, Sn, Ti)O3solid solutions
2000
Abstract Field induced deformation and electrocaloric effect are investigated in the vicinity of phase transition at 163°C. The sharp increase of electrostriction below Tc is explained by the field induced ferroelectric to antiferroelectric phase transition. The antiferroelectric phase appears and remains stable below Tc in the absence of field. Elastic compliance and thermal expansion as functions of temperature are studied.
Phase transitions of Pb0.99Nb0.02(Zr0.75Sn0.20Ti0.05)O3ceramics
2001
Abstract The dielectric, elastic and electromechanical properties, electrocaloric effect and thermal expansion of poled and depoled Pb0.99Nb0.02(Zr0.75Sn0.20Ti0.05)O3 samples are presented to evaluate the nature of polar phases existing in the solid solution above room temperature. The Kittel's free energy expansion is used to explain some essential features of physical properties.
Anomalies in low-temperature lattice parameters of ErFeO3 and ErAlO3 single crystals: correlation with magnetic properties
2005
Abstract The paper presents the results of an experimental study of thermal expansion of isostructural orthorhombic ErFeO3 and ErAlO3 single crystals. Changes of lattice parameters have been investigated by X-ray measurements in the 10–300 K temperature range. Above ∼150 K, experimental results correspond well to the phonon mechanism. At low temperatures distinct anisotropic anomalies were observed in both compounds; and a correlation with the magnetic properties of the relevant ions is noted.
Vibrational properties of ZnTe at high pressures
2002
Raman spectra of ZnTe were measured under hydrostatic pressures up to 15 GPa at T = 300 K. Results for the frequencies of first- and second-order Raman features of the zincblende phase (0-9.5 GPa) are used to set up a rigid-ion model of the phonon dispersion relations under pressure. Calculated phonon densities of states, mode Gruneisen parameters and the thermal expansion coefficient as a function of pressure are discussed. The effect of pressure on the widths and intensities of Raman spectral features is considered. Raman spectra of high-pressure phases of ZnTe are reported. These spectra indicate the possible existence of a new phase near 13 GPa, intermediate between the cinnabar and ort…
Communicating with home, coping without home – Trusting to the mediating capacity of blogging
2021
Abstract In the early 21st century, blogs exploded onto the digital media scene and soon became a popular means of travel writing. However, rather than considering blogs as a straightforward tool to simply share stories and experiences, in this article, we set out to explore the role of blogs as a mediating technology (Verbeek, 2005a), especially during difficult times abroad. By analysing the blogs of expatriate Australians who were volunteers in Bangladesh in 2014/2015 as well as interviews with the bloggers, we are able to show how the blogs' affordances inform the coping process, highlighted, in particular, in an active and highly reflective engagement with the blog's unique situatednes…
The clustering of galaxies in the SDSS-III Baryon Oscillation Spectroscopic Survey: Measuring D_A and H at z=0.57 from the Baryon Acoustic Peak in th…
2014
We present measurements of the angular diameter distance to and Hubble parameter at z = 0.57 from the measurement of the baryon acoustic peak in the correlation of galaxies from the Sloan Digital Sky Survey III Baryon Oscillation Spectroscopic Survey. Our analysis is based on a sample from Data Release 9 of 264 283 galaxies over 3275 square degrees in the redshift range 0.43 z DA(0.57) = 1408 ± 45 Mpc and H(0.57) = 92.9 ± 7.8 km s-1 Mpc-1 for our fiducial value of the sound horizon. These results from the anisotropic fitting are fully consistent with the analysis of the spherically averaged acoustic peak position presented in Anderson et al. Our distance measurements are a close match to th…
Testing theories of Gravity and Supergravity with inflation and observations of the cosmic microwave background
2016
Many extensions of Einstein's theory of gravity have been studied and proposed with various motivations like the quest for a quantum theory of gravity to extensions of anomalies in observations at the solar system, galactic and cosmological scales. These extensions include adding higher powers of Ricci curvature $R$, coupling the Ricci curvature with scalar fields and generalized functions of $R$. In addition when viewed from the perspective of Supergravity (SUGRA) many of these theories may originate from the same SUGRA theory interpreted in different frames. SUGRA therefore serves as a good framework for organizing and generalizing theories of gravity beyond General Relativity. All these …
Lifestyle counseling in type 2 diabetes prevention: a case study of a nurse's communication activity to produce change talk.
2006
As a case study, this article describes a nurse's communication activity, focusing on change talk during lifestyle counseling in primary healthcare. All videotaped counseling sessions with a single patient within a period of two years were transcribed verbatim. In the analysis, an emphasis was placed on the nurse's communication activity that produced change talk, how the nurse initiated change talk, and how the patient received it. The observations provide evidence that the dilemma of simultaneously maintaining professional authority and patient perspective leads to sensitivity in lifestyle counseling. Three categories of change talk were identified: rejected, restrictive, and expansive ch…