Search results for "Effects"

Influence of the InAs coverage on the phonon-assisted recombination in InAs/GaAs quantum dots

2002

6 páginas, 3 figuras.

Trans-to-cis photoisomerization of cyclocurcumin in different environments rationalized by computational photochemistry

2020

International audience; Cyclocurcumin is a turmeric component that attracted much less attention compared to the well known curcumin. In spite of the less deep charcaterization of its properties, cyclocurcumin has shown promising anticancer effects when used in combination with curcumin. Especially, due to its peculiar molecular structure, cyclocurcumin can be regarded as an almost ideal photoswitch, whose capabilities can also be exploited for relevant biological applications. Here, by means of state-of-the-art computational methods for electronic excited-state calculations (TD-DFT, MS-CASPT2, XMS-CASPT2) we analyze in detail the absorption and photoisomerization pathways leading from the …

Comprehensive formulation of the temperature dependent dispersion of optical materials; illustration with the case of temperature tuning of a mid-IR …

2009

International audience; The temperature dependence of refractive indices of optical materials is characterized in this work by what we call their normalized thermo-optic coefficients. These ones are determined experimentally through interferometric measurements of thermal expansion, and changes in optical thickness at a few laser wavelengths as function of temperature. A suitable vectorial formalism applied to these data allows predicting the thermal evolution of the refractive index all over the useful range of transparency. The validity and reliability of our methodology is demonstrated through temperature tuning of a mid-IR HgGa2S4 OPO, pumped at 1.0642 μm by a Nd:YAG laser. Measured the…

A new discretization for the polarizable continuum model within the domain decomposition paradigm

2016

International audience; We present a new algorithm to solve the polarizable continuum model equation in a framework compatible with the strategy previously developed by us for the conductor-like screening model based on Schwarz’s domain decomposition method (ddCOSMO). The new discretization is systematically improvable and is fully consistent with ddCOSMO so that it reproduces ddCOSMO results for large dielectric constants.

MALTA: a CMOS pixel sensor with asynchronous readout for the ATLAS High-Luminosity upgrade

2018

Radiation hard silicon sensors are required for the upgrade of the ATLAS tracking detector for the High- Luminosity Large Hadron Collider (HL-LHC) at CERN. A process modification in a standard 0.18 μm CMOS imaging technology combines small, low-capacitance electrodes (∼2 fF for the sensor) with a fully depleted active sensor volume. This results in a radiation hardness promising to meet the requirements of the ATLAS ITk outer pixel layers (1.5 × 1015 neq /cm2 ), and allows to achieve a high signal-to-noise ratio and fast signal response, as required by the HL-LHC 25 ns bunch crossing structure. The radiation hardness of the charge collection to Non-Ionizing Energy Loss (NIEL) has been previ…

Different acute effects of single-axis and multi-axis hand-arm vibration.

1996

Under laboratory conditions the effects of single-axis and multi-axis hand-arm vibration exposure on several strain parameters were tested in up to 20 male subjects. As parameters of these acute effects, the biodynamic vibration behavior of the hand-arm system, the electrical activity of the most affected muscle groups, the skin temperature, the vibration sensitivity of the fingertips, and the subjective vibration sensation were measured. When comparing simulated three-axis vibration exposure with single-axis vibration exposure, synergistic effects in the form of an increasing reaction could be found. It could be proven that the vector sum of the frequency-weighted acceleration in the three…

Distilling angular momentum nonclassical states in trapped ions

2004

In the spirit of Quantum Non-Demolition Measurements, we show that exploiting suitable vibronic couplings and repeatedly measuring the atomic population of a confined ion, it is possible to distill center of mass vibrational states with well defined square of angular momentum or, alternatively, angular momentum projection Schr\"odinger cat states.

Field-free molecular alignment for probing collisional relaxation dynamics

2013

International audience; We report the experimental study of field-free molecular alignment in CO2 gas mixtures induced by intense femtosecond laser pulses in the presence of collisional processes. We demonstrate that the alignment signals exhibit specific features due to nontrivial collisional propensity rules that tend to preserve the orientation of the rotational angular momentum of the molecules. The analysis is performed with a quantum approach based on the modeling of rotational J- and M-dependent state-to-state transfer rates. The present work paves the way for strong-field spectroscopy of collisional dynamics.

Integral and differential approaches to Eringen's nonlocal elasticity models accounting for boundary effects with applications to beams in bending

2021

Molecular dynamics simulations of elementary chemical processes in liquid water using combined density functional and molecular mechanics potentials.…

1997

A new approach to carry out molecular dynamics simulations of chemical reactions in solution using combined density functional theory/molecular mechanics potentials is presented. We focus our attention on the analysis of reactive trajectories, dynamic solvent effects and transmission coefficient rather than on the evaluation of free energy which is another important topic that will be examined elsewhere. In a previous paper we have described the generalities of this hybrid molecular dynamics method and it has been employed to investigate low energy barrier proton transfer process in water. The study of processes with activation energies larger than a few kT requires the use of specific tech…