Search results for "Elastic"

Influence of hydrogen bonding on the viscoelastic properties of thermoreversible networks: analysis of the local complex dynamics

1995

Abstract The viscoelastic properties of thermoreversible polybutadiene networks in which junctions are formed by binary contacts between polar stickers (phenylurazole) are investigated by a dynamic mechanical spectroscopy within the frequency range 0.0079–79.5 Hz (0.05–500 rads−1). Time-temperature superposition is applicable in the terminal flow region and the glass transition regime, whereas thermorheologically complex behaviour is observed within the rubbery plateau region. For the terminal relaxation zone the polar stickers enhance the relaxation time and broaden the relaxation time spectrum. The thermorheologically complex behaviour within the rubbery plateau region results from the oc…

A method for determination of time- and temperature-dependences of stress threshold of linear-nonlinear viscoelastic transition: Energy-Based Approach

2011

A methodology for determination of time- and temperature-dependences of stress threshold of linear–nonlinear viscoelastic transition is proposed and validated by example of uniaxial creep of epoxy resin. Energy approach is applied for characterization of the region of linear viscoelasticity (LVE) and the threshold of LVE is given in the stress–strain representation as the master curve independent of time and temperature. Time- and temperature-dependences of the stress threshold are calculated by extending LVE theory and time–temperature superposition principles (TTSP) to the energy relations. Reasonable agreement between experimental data and calculations is obtained. It is shown that numbe…

1980

Compression creep and stress-relaxation tests have been performed on PMMA at several deformations after the sample yielding. At large loading rates, the behaviour observed was found significantly affected by the temperature rise due to the plastic deformation. Creep and stress-relaxation data taken holding the samples at constant temperature after the material loading could be collected into single curves by means of a time shift factor proportional to the loading rate. Retardations- und Relaxationsuntersuchungen bei Druckbeanspruchung von PMMA wurden bei verschiedenen Deformationen oberhalb des Fliespunktes durchgefuhrt. Bei hohen Beanspruchungsgeschwindigkeiten wurde festgestellt, das das…

Pulsatile protein release and protection using radiation-crosslinked polypeptide hydrogel delivery devices

2011

Abstract In the recent years recombinant technology has identified numerous protein based therapeutics. Their effective delivery, though, can be challenging due to the poor stability of most proteins along their pathway to the target site in the body. Hydrogels have been identified as good candidates for protein encapsulation and delivery thanks to both material and manufacturing process advantages. In this work we propose high energy irradiation as a synthetic methodology of choice to engineer hydrogel-based delivery devices for encapsulation and pulsatile release of proteins, triggered by pH, and for prevention of their denaturation when encapsulated. In particular, maleic anhydride funct…

Infrared linear dichroism spectroscopy by a double modulation technique

1990

A linear IR dichroism experiment has been devised using a FTIR instrument in combination with a photoelastic modulator. Based on the Mueller-Stokes calculus, a method to directly obtain the absorbance spectra Av parallel and Av perpendicular from the modulated interferogram is developped, which allows the sensitive evaluation of the dichroic ratio. The photoelastic modulator, in combination with a FTIR instrument, offers high sensitivity, high speed, excellent signal to noise ratio and a broad spectral range from 3300 to 850 cm-1. First experimental results obstained from SBS block copolymer are reported.

Linear infrared dichroism by a double modulation technique

1991

In the first part of this paper an experimental setup using Fourier-transform infrared spectroscopy (FTIR) in combination with a photoelastic modulator (PEM) for linear dichroism measurements is described. The second part shows the influence of PEM-amplitude and scan-velocity on the sensitivity of the instrument. The third part deals with the fringe-problem in the baselines of absorbance spectra and its influence on the determination of the linear dichroic ratio.

Physicochemical and Rheological Characterization of Different Low Molecular Weight Gellan Gum Products and Derived Ionotropic Crosslinked Hydrogels

2021

A series of four different low molecular weight gellan gum products was obtained by alkaline hydrolysis with the aim to investigate the impact of the molecular weight on the rheological properties of the polysaccharide aqueous dispersions and on the physicochemical characteristics of derived ionotropic crosslinked hydrogels. In particular, thermo-rheological analysis was conducted on aqueous dispersions to study the influence of molecular weight on the thermogelation properties typical of the native polysaccharide while strain sweep experiments were conducted to establish if aqueous dispersion shows a viscoelastic behavior. The effect of different Ca2+ on the rheological properties of hydro…

Application of time-temperature superposition to energy limit of linear viscoelastic behavior

2009

The energy approach for evaluation of the limits of linear viscoelastic (LVE) behavior is considered. The approach of Foux and Bruller based on the Reiner-Weissenberg dynamic theory of strength is developed for the temperature effect. Value of the stored energy at the limit of LVE is considered as the material characteristic independent on loading conditions and temperature. Time–temperature superposition principle is extended for the energy calculations. Curves of the stored energy calculated for different temperatures are shifted to each other in the logarithmic time axes similarly as creep compliance and relaxation modulus curves in creep and tension tests, respectively. Temperature is c…

Minimal Absent Words in Rooted and Unrooted Trees

2019

We extend the theory of minimal absent words to (rooted and unrooted) trees, having edges labeled by letters from an alphabet \(\varSigma \) of cardinality \(\sigma \). We show that the set \(\text {MAW}(T)\) of minimal absent words of a rooted (resp. unrooted) tree T with n nodes has cardinality \(O(n\sigma )\) (resp. \(O(n^{2}\sigma )\)), and we show that these bounds are realized. Then, we exhibit algorithms to compute all minimal absent words in a rooted (resp. unrooted) tree in output-sensitive time \(O(n+|\text {MAW}(T)|)\) (resp. \(O(n^{2}+|\text {MAW}(T)|)\) assuming an integer alphabet of size polynomial in n.

On Codimensions of Algebras with Involution

2020

Let A be an associative algebra with involution ∗ over a field F of characteristic zero. One associates to A, in a natural way, a numerical sequence \(c^{\ast }_n(A),\)n = 1, 2, …, called the sequence of ∗-codimensions of A which is the main tool for the quantitative investigation of the polynomial identities satisfied by A. In this paper we focus our attention on \(c^{\ast }_n(A),\)n = 1, 2, …, by presenting some recent results about it.