Search results for "Elastic"

Inelastic neutron scattering study of proton dynamics in Ca(OH)2 at 20 K

1995

Abstract Inelastic neutron scattering (INS) spectra of Ca(OH) 2 at 20 K are presented from 30 to 4000 cm −1 for a powder sample, from 30 to 12000 cm −1 for an oriented single-crystal. INS band splitting due to the lattice density-of-states is observed. Polarization effects reveal the orientation of atomic displacements for each mode and a new band assignment scheme is proposed. For the single-crystal, the v OH mode and overtones are observed. This oscillator shows only moderate anharmonicity. Spectrum simulation reveals that INS spectral intensities are not consistent with simple normal coordinates and harmonic force-fields for Ca(OH) 2 entities. A new dynamical model is proposed, including…

Variable Cooperative Interactions in the Pressure and Thermally Induced Multistep Spin Transition in a Two-Dimensional Iron(II) Coordination Polymer

2020

Two types of experiments conducted to investigate the effect of pressure on the spin crossover (SCO) properties of the 2D Fe(II) coordination polymer formulated {Fe[bipy(ttr)2]}n are reported, namely, (1) magnetic measurements performed at variable temperature and at fixed pressure and (2) visible spectroscopy at variable pressure and fixed temperature. The magnetic experiments carried out under a hydrostatic pressure constraint of 0.04, 0.08, and 0.8 GPa reveal a two-step spin transition behavior. The characteristic critical temperatures of the spin transition are shifted upward in temperature as pressure increases. The slope of the straight-line of the Tc vs P plot, dTc/dP, is 775 K/GPa a…

Melange: A viscoelastic lattice-particle model applicable to the lithosphere

2012

[1] This article introduces the software Melange, a 3D lattice-particle hybrid model. The software was specifically designed in order to simulate ductile visco-elasto-plastic deformation and can be used to study tectonic processes in the lithosphere from the micro to the macro scale. Melange is under an open source license. The code takes both relevant yield mechanisms for the deformation of lithospheric material into account: dynamic brittle failure and ductile creep, where ductile creep is modeled as viscoelasticity. The software considers effects of the local geology, of the inherent disorder of geomaterials, of rheological layering of the lithosphere and applies repulsion when the mater…

Calculating pressure with elastic geobarometry: A comparison of different elastic solutions with application to a calc-silicate gneiss from the Rhodo…

2020

Abstract Raman elastic geobarometry has increasingly been used complementary to metamorphic phase equilibria to estimate the conditions of recrystallization in metamorphic rocks. The procedure of applying Raman elastic barometry to host-inclusion mineral systems requires several steps that involve various assumptions. One of the most essential assumptions is that the mineral host-inclusion system behaves in an elastic and reversible manner. We discuss the discrepant results obtained by different authors employing different analytical solutions for elasticity and explore the assumptions lying behind each method. Furthermore, we evaluate numerically linear and non-linear elastic solutions and…

The influence of rock heterogeneity on the scaling properties of simulated and natural stylolites

2009

International audience; Stylolites are among the most prominent deformation patterns in sedimentary rocks that document localized pressure solution. Recent studies revealed that stylolite roughness is characterized by two distinct scaling regimes. The main goal of the present study is to decipher whether this complex scaling behavior of stylolites is caused by the composition of the host-rock, i.e. heterogeneities in the material, or is governed by inherent processes on respective scales, namely the transition from a surface energy to an elastic energy dominated regime, as theoretically predicted. For this purpose we have developed a discrete numerical technique, based on a lattice spring m…

Growth of stylolite teeth patterns depending on normal stress and finite compaction

2007

Abstract Stylolites are spectacular rough dissolution surfaces that are found in many rock types. They are formed during a slow irreversible deformation in sedimentary rocks and therefore participate to the dissipation of tectonic stresses in the Earth's upper crust. Despite many studies, their genesis is still debated, particularly the time scales of their formation and the relationship between this time and their morphology. We developed a new discrete simulation technique to explore the dynamic growth of the stylolite roughness, starting from an initially flat dissolution surface. We demonstrate that the typical steep stylolite teeth geometry can accurately be modelled and reproduce natu…

2020

During winter insects face energetic stress driven by lack of food, and thermal stress due to sub-optimal and even lethal temperatures. To survive, most insects living in seasonal environments such as high latitudes, enter diapause, a deep resting stage characterized by a cessation of development, metabolic suppression and increased stress tolerance. The current study explores physiological adaptations related to diapause in three beetle species at high latitudes in Europe. From an ecological perspective, the comparison is interesting since one species (Leptinotarsa decemlineata) is an invasive pest that has recently expanded its range into northern Europe, where a retardation in range expa…

Cellulose ether emulsions as fat source in cocoa creams: Thermorheological properties (flow and viscoelasticity)

2019

Flow behaviour and viscoelastic properties at three different temperatures (20, 45 and 70 °C) of cocoa filling creams have been studied. These creams were composed of cocoa, starch, sugar, skimmed milk powder and non-digestible cellulose ether emulsions as fat source. Two types of methylcelluloses, MC, and two types of hydroxypropyl methylcelluloses, HPMC, with different chemical substitution degrees were employed. Results showed important differences in zero shear viscosity and shear thinning character at room temperature, due to the different internal structure revealed by the viscoelastic moduli spectra. Temperature sweeps of storage modulus showed different temperature gelation dependin…

Fractional-Order System Identification of Viscoelastic Behavior: A Frequency Domain Based Experimental Study

2020

In this work, the fractional-order modeling of viscoelastic behavior is investigated based on measurement data in the frequency domain. For the results of two different test setups we apply existing parameter estimation algorithms designed for fractional-order transfer functions. These algorithms require a priori knowledge of the system structure including the commensurate order of differentiation. An iterative procedure is used to evaluate the influence of the unknown structure. The measured polymer samples show a viscoelastic stress response. We can show that integer-order models are not capable of capturing this behavior. For a set of predefined structures, the best obtained fractional-o…

Practical Calculation Models for Column Footing and Comparison with Experimental Data

2017

In this paper, a simplified calculation model for the prediction of the load-carrying capacity of an RC column footing with a square cross section is presented. A detailed background of available experimental data and existing models for the prediction of the load-carrying capacity of slender and deep footings is presented. Cases of flexural failure and punching shear failures for slender footing and concrete strut crushing and tie yielding in deep members are analyzed. The aim of the paper is to propose a simple design formula for slender and deep footing verified by available experimental data and in agreement with other existing expressions. Expressions of the maximum mechanical ratio of…