Search results for "Electric dipole transition"
showing 5 items of 25 documents
Spectroscopy of excited state positronium
1994
Electric dipole transitions in the microwave range have been induced between the fine-structure levels of positronium in the excited staten=2. As an indication of the transitions, we used the increase in Lyman-α radiation when the metastable 23S1-level is depopulated. The results for the transitions 23S1→23P0,1,2 areΝ 0=18499.65±1.20±4.00 MHz,Ν 1=13012.42 ±0.65±1.54 MHz andΝ 2=8624.38±0.54±1.40 MHz. The first error is statistical and the second systematic. The precision of the present measurement has improved by a factor of 3, compared to previous data. Recent bound state QED-calculations have been extended to the orderR t8 α 4lnα −1. The not yet completely calculated orderR t8 α 4 is estim…
New physics constraints from atomic parity violation in Cs133
2021
Our improved calculation of the nuclear spin-independent parity violating electric dipole transition amplitude ($E{1}_{\mathrm{PV}}$) for $6s{^{2}S}_{1/2}\ensuremath{-}7s{^{2}S}_{1/2}$ in $^{133}\mathrm{Cs}$ in combination with the most accurate (0.3%) measurement of this quantity yields a new value for the nuclear weak charge ${Q}_{W}=\ensuremath{-}73.71(26{)}_{ex}(23{)}_{th}$ against the Standard Model (SM) prediction ${Q}_{W}^{\mathrm{SM}}=\ensuremath{-}73.23(1)$. The advances in our calculation of $E{1}_{\mathrm{PV}}$ have been achieved by using a variant of the perturbed relativistic coupled-cluster theory, which treats the contributions of the core, valence, and excited states to $E{1…
Valence Topological Charge-Transfer Indices for Dipole Moments
2003
Valence topological charge-transfer (CT) indices are applied to the calculation of dipole moments. The dipole moments calculated by algebraic and vector semisums of the CT indices are defined. The combination of the CT indices allows the estimation of the dipole moments. The model is generalized for molecules with heteroatoms. The ability of the indices for the description of the molecular charge distribution is established by comparing them with the dipole moment of the valence-isoelectronic series of benzene and styrene. Two CT indices, μ v e c (vector semisum of vertex-pair dipole moments) and μ V v e c (valence μ v e c ) are proposed. μ v e c and μ V v e c are important for the predicti…
Shallow-donor impurities in indium selenide investigated by means of far-infrared spectroscopy.
1992
Shallow impurities in n-type indium selenide (InSe) have been investigated by means of Fourier-transform spectroscopy in the far-infrared region. Three electric dipole transitions have been identified: 1s-2${\mathit{p}}_{\ifmmode\pm\else\textpm\fi{}}$, 1s-2${\mathit{p}}_{0}$, and 1s-3${\mathit{p}}_{\ifmmode\pm\else\textpm\fi{}}$, corresponding to electrons bound to native donors and tin-, silicon-, and chlorine-related donors, whose ionization energies (17.6, 18.1, 18.8, and 19 meV, respectively) have been determined through the Guerlach-Pollmann model. That model was also used to calculate the oscillator strengths of those dipole transitions, and then to estimate the shallow-donor concentr…
Low-lying Rydberg states of HCl.
2008
Vertical excitation energies belonging to some different Rydberg series of hydrogen chloride have been determined with a coupled-cluster theoretical approach. These excitation energies have allowed us to calculate electric dipole transition intensities in HCl and allow additional assessment of the calculation approach presently used to provide an adequate description of the valence and Rydberg states of HCl. The molecular quantum defect orbital has been applied to the calculation of oscillator strengths. In particular, new insight is given on the assignment of states as the R1Pi, the 1Delta(4dpi and 5ppi), the 1Sigma+(4dpi), and the nddelta(1Pi, 1Phi) and 4f states.