Search results for "Electricity"
showing 10 items of 1225 documents
Polaronic-type excitons in ferroelectric oxides: Microscopic calculations and experimental manifestation
2002
We discuss the current experimental and theoretical understanding of new polaronic-type excitons in ferroelectric-oxides charge-transfer vibronic excitons ~CTVE’s!, which are pairs of strongly correlated electronic and hole polarons. It is shown that charge-transfer‐lattice distortion interactions are the driving forces for CTVE formation. Hartree-Fock-type calculations performed in the framework of the intermediate neglect of differential overlap ~INDO! method as well as photoluminescence, second-harmonic generation, and UVabsorption high-temperature studies performed for ABO3 ferroelectric oxides strongly support the CTVE existence. Both single CTVE and a phase of strongly correlated CTVE…
Semiadiabatic High-Field Polarization Response in Ferroelectrics I: Hysteresis and Nonlinear Susceptibility
2004
Ginzburg-Landau theory for ferroelectric phase instability is combined with Langevin, Fokker-Planck and imaginary time Schrodinger equation techniques to model impact of thermal noise in the kinetics of ferroelectric polarization. The proposed real space/real time numerical method allows to efficiently simulating relaxation, dynamic hysteresis and general dielectric response.
Enhanced ferroelectric phase-transition temperature in perovskite-based solid solutions
2004
We explain how the phenomena of ferroelectric phase transition temperature ${T}_{c}$ enhancement beyond the end members in perovskite solid solution such as $\mathrm{Bi}M{\mathrm{O}}_{3}\text{\ensuremath{-}}{\mathrm{PbTiO}}_{3}$ ($M=\mathrm{Sc}$, In, etc.) is related to nonlinear and spatial correlation effects. The explanation is based on the calculation of ${T}_{c}$ in the framework of our random field theory with additional account for nonlinear effects in the above substances. We show that the maximum of ${T}_{c}$ for certain ${\mathrm{PbTiO}}_{3}$ content takes place when coefficient of nonlinearity is positive, the value of this coefficient is found from best fit between theory and ex…
Intrinsic localized excitations in nonlinear lattices: Heuristic explanation for the nature of polar nanoregions?
2010
The study is addressed to a topical problem of self-localization in condensed state with special emphasis on a class of complex oxides categorized as ferroelectric relaxors. Basically, their anomalous temperature response is associated with the dynamics of microscopic scale polar regions supported by somewhat artificial metastable configurations. A unified approach to the spontaneous emergence and stability of the polar nanoregions is assigned to intrinsic localized excitations in Hamiltonian lattices with nonlinearity and non-Gibbsian statistics as necessary and sufficient ingredients of the theory.
Thermal fluctuation effects in ferroelectric liquid-crystal polarization reversal: Light scattering from a transient domain-wall foam
1991
Thermal orientation fluctuations of the director field during electric-field-induced polarization reversal in ferroelectric liquid crystals lead to the nondeterministic formation of a transient domain-wall foam that strongly scatters light. This foam comprises domains of molecules that have reoriented locally in the same sense on the smectic-C tilt cone and are separated from one another by 2\ensuremath{\pi} inversion walls. The dynamics of formation and the subsequent annealing of the foam have been probed using laser light scattering. Anisotropic coarsening of the foam, which is accounted for by including electrostatic (space-charge) interactions in the theoretical description of the ferr…
Peculiarities of coherent optical oscillation in Sn_2P_2S_6 crystals
2010
We show analytically and numerically that the unusual photorefractive nonlinear response of Sn2P2S6 crystals leads to a variety of new features of coherent optical oscillation. In addition to the explanation of the known peculiarities, new features are predicted.
Coherent Spin Dependent Landau-Zener Tunneling in Mixed Valence Dimers
2011
In this contribution we introduce the concept of single molecule ferroelectric based on the vibronic pseudo Jahn-Teller model of mixed valence dimeric clusters belonging to the Robin and Day class II compounds. We elucidate the main factors controlling the nonadiabatic Landau-Zener tunneling between the low lying vibronic levels induced by a pulse of the electric field. The transition probabilities are shown to be dependent on the both time of the pulse and the total spin of the cluster. A possibility to control the spin-dependent Landau-Zener tunneling by applying a static magnetic field is discussed.
Infinite single-particle bandwidth of a Mott–Hubbard insulator
2016
The conventional viewpoint of the strongly correlated electron metal-insulator transition is that a single band splits into two upper and lower Hubbard bands at the transition. Much work has investigated whether this transition is continuous or discontinuous. Here we focus on another aspect and ask the question of whether there are additional upper and lower Hubbard bands, which stretch all the way out to infinity — leading to an infinite single-particle bandwidth (or spectral range) for the Mott insulator. While we are not able to provide a rigorous proof of this result, we use exact diagonalization studies on small clusters to motivate the existence of these additional bands, and we discu…
Microscopic approach to the kinetics of pattern formation of charged molecules on surfaces.
2010
A microscopic formalism based on computing many-particle densities is applied to the analysis of the diffusion-controlled kinetics of pattern formation in oppositely charged molecules on surfaces or adsorbed at interfaces with competing long-range Coulomb and short-range Lennard-Jones interactions. Particular attention is paid to the proper molecular treatment of energetic interactions driving pattern formation in inhomogeneous systems. The reverse Monte Carlo method is used to visualize the spatial molecular distribution based on the calculated radial distribution functions (joint correlation functions). We show the formation of charge domains for certain combinations of temperature and dy…
Mesoscopic Scale Structural Instability in Ferroelectrics
2009
First-principles statistics addressed to structural phase transitions and temperature development of ferroelectric response is derived within the framework of the Fokker-Planck (Smoluchowsky) equation as complementary to the Monte Carlo [R.D King-Smith., D Vanderbilt, Phys. Rev. B 49, 5828–5844 (1994)] and molecular dynamics [T. Nishimatsu, U. V Waghmare, Y. Kawazoe., D. Vanderbilt, arXiv:0804.1853v2] simulations. Illustrative example of is given for 5 × 5 × 5 BaTiO 3 supercell.