Search results for "Electrode"
showing 10 items of 950 documents
An AC-assisted single-nanowire electromechanical switch
2013
A unique two-source controlled nanoelectromechanical switch has been assembled from individual, single-clamped Ge nanowires. The switching behaviour was achieved by superimposing the control signals of specific frequencies to the electrostatic potential of the output terminals, eliminating the need for an additional gate electrode. Using an in situ manipulation technique inside a scanning electron microscope, we demonstrate that the pull-out force required to overcome adhesion at the contact can be significantly reduced by exciting mechanical resonant modes within the nanowire.
Elaboration of ammonia gas sensors based on electrodeposited polypyrrole - cobalt phthalocyanine hybrid films
2013
The electrochemical incorporation of a sulfonated cobalt phthalocyanine (sCoPc) in conducting polypyrrole (PPy) was done, in the presence or absence of LiClO4, in order to use the resulting hybrid material for the sensing of ammonia. After electrochemical deposition, the morphological features and structural properties of polypyrrole/phthalocyanine hybrid films were investigated and compared to those of polypyrrole films. A gas sensor consisting in platinum microelectrodes arrays was fabricated using silicon microtechnologies, and the polypyrrole and polypyrrole/phthalocyanine films were electrochemically deposited on the platinum microelectrodes arrays of this gas sensor. When exposed to a…
Electrochemistry of Carbon Dioxide on Carbon Electrodes.
2016
Carbon electrodes have the advantages of being chemically inert at negative potential ranges in all media and high offset potentials for hydrogen evolution in comparison to metal electrodes, and therefore are the most suitable electrodes for electrochemistry and electrochemical conversion of CO2 into valuable chemicals. Herein we summarize on carbon electrodes the voltammetry, electrochemical and electrocatalytic CO2 reduction, as well as electron synthesis using CO2 and carbon electrodes. The electrocatalytic CO2 reduction using carbocatalyts and the future activities about electrochemical CO2 conversion are highlighted.
Copper(I) pseudorotaxane monolayers assembled on gold electrodes.
2003
Two new copper (I) pseudorotaxanes bearing a thioctic acid appended unit have been prepared and deposited onto a gold electrode surface, leading to surface-attached electroactive pseudorotaxanes.
Ionic and Free Solvent Motion in Poly(azure A) Studied by ac-Electrogravimetry
2011
International audience; This work is focused on the mechanistic aspects of the redox behavior of poly(azure A) taking advantage of the controlled modulation of their oxidation states by ac-electrogravimetry. The originality of this technique is its ability to discriminate between cation and anion involved in the charge compensation process and the accompanying free solvent transfer, directly or indirectly. Two processes were proposed where the faster ionic exchange is considered to be the participation of the anion species acting as counterions whereas the slower one is related to the proton transfer. The proton is implied as reactants for the two electroactive sites identified in the polym…
Electrocatalytic reduction of dioxygen to water by tren-capped porphyrins, functional models of cytochrome c oxidase
1999
International audience; Two different tren-capped porphyrins—in which the two metals, iron and copper, are more or less off-centered—are shown to be efficient catalysts for the reduction of O2 to H2O; surprisingly, their iron-only complexes are shown to be even more effective 4e- catalysts when adsorbed on a graphiteelectrode.
A study on the use of bare buried conductors in an extended interconnection of earthing systems inside a MV network
2005
In the field of electrical safety an important topic is the transmission of voltages, during an earth fault, inside an extended interconnection of local earthing systems. The paper presents a study, with reference to the MV networks, about those systems where the interconnection between the earth electrodes of the electrical installations is carried out using bare buried conductors. Starting from the description of the circuital model of a bare buried conductor interconnecting together the earth electrodes of two MV/lv substations, the mathematical model of the whole interconnected earthing system is found. Finally, the results of some simulations, giving the distribution of the fault curre…
Tunneling junctions of the heavy-fermion superconductor UPd2Al3
1998
Abstract Tunneling spectroscopy on planar Giaever-type junctions is a powerful tool for the investigation of the superconducting state of metals. Since it is possible to prepare high-quality epitaxial thin films of the heavy-fermion compound UPd 2 Al 3 , this method can be used to examine the energy gap of this presumably unconventional superconductor. We prepared cross-junctions consisting of a UPd 2 Al 3 base electrode and a metal counter electrode (Au, Al or Ag). These small area contacts without artificial barriers have only low junction resistances and suffer from irreproducibility. On the other hand, on some of those junctions we observed BCS-like tunneling conductivity. In order to i…
Measuring electrostatic double-layer forces on HOPG at high surface potentials
1999
Abstract The aim of this study was to investigate surface forces in aqueous electrolyte solutions between surfaces with high electric potentials. Therefore the force between a surface of highly oriented pyrolytic graphite (HOPG) and a silicon nitride tip of an atomic force microscope was measured. Various electric potentials by a counter electrode were applied to the HOPG, which served as working electrode. As predicted by the Poisson–Boltzmann theory the electrostatic double-layer force changed only in a narrow potential range of ≈300 mV. At high negative sample potentials, where the negatively charged tip was repelled from the sample, the force saturated. At positive potentials an attract…
Microelectrode Measurements of Oxygen Tension Distributions in Multicellular Spheroids Cultured in Spinner Flasks
1984
Since multicellular spheroids were introduced into cancer research by Sutherland et al. (1970, 1971), they have been widely used for studying the susceptibility of cancer cells to various treatment modalities. Many of these investigations provided evidence for a major role of oxygen in controlling the metabolic and cell cycle state of the tumor cells, thus modifying the responsiveness of the cells to therapy. Several investigators have measured O2 tension (PO2) distributions in spheroids with O2-sensitive microelectrodes (Carlsson et al. 1979; Kaufman et al. 1981; Mueller-Klieser and Sutherland 1982a, b, 1983; Mueller-Klieser et al. 1983). The measurements produced PO2 values that varied co…