Search results for "Elite"
showing 10 items of 370 documents
Effect of pressure on the luminescence properties of Nd3+ doped SrWO4 laser crystal
2008
Abstract The luminescence spectra of the 4 F 3/2 → 4 I 9/2 transition of Nd 3+ ions in a SrWO 4 crystal have been analyzed as a function of pressure at room temperature. Experiments have been performed in a diamond-anvil cell up to 13 GPa. At around 10 GPa some changes in the emission spectra have been observed which are attributed to a structural phase transition of the SrWO 4 matrix. These results are in good agreement with a previous paper, in which in a pure SrWO 4 matrix a scheelite to fergusonite phase transition is found around 10.5 GPa. Moreover, with increasing pressure, the decay curves from the 4 F 3/2 are nonexponential and faster indicating that the energy transfer processes …
On the ferroelastic nature of the scheelite-to-fergusonite phase transition in orthotungstates and orthomolybdates
2009
Abstract New evidence supporting the ferroelastic nature of the pressure-induced scheelite-to-fergusonite phase transition in ABO 4 orthotungstates and orthomolybdates (A = Ca, Sr, Ba, Pb, Eu and B = W, Mo) has been obtained from the analysis of Raman spectroscopy data. In the studied scheelite-type compounds, one external translational mode of B g symmetry in the scheelite phase softens up to the transition pressure and then becomes a hard A g mode in the fergusonite high-pressure phase. However, other scheelite-type compounds not undergoing the scheelite-to-fergusonite transition do not show softening of the B g mode. The reported results have allowed us to establish a relationship betwee…
Quasi-hydrostatic X-ray powder diffraction study of the low- and high-pressure phases of CaWO4 up to 28 GPa
2014
We have studied CaWO4 under compression using Ne as pressure-transmitting medium at room temperature by means of synchrotron X-ray powder diffraction. We have found that CaWO4 beyond 8.8 GPa transforms from its low-pressure tetragonal structure (scheelite) into a monoclinic structure (fergusonite). The high-pressure phase remains stable up to 28 GPa and the low-pressure phase is totally recovered after full decompression. The pressure dependence of the unit-cell parameters, as well as the pressure volume equation of state, has been determined for both phases. Compared with previous studies, we found in our quasi-hydrostatic experiments a different behavior for the unit-cell parameters of th…
In-situ high-pressure Raman scattering studies in PbWO4 up to 48 GPa
2016
The effect of pressure on the Raman spectrum of PbWO4 has been investigated up to 48 GPa in a diamond-anvil cell using neon as pressure-transmitting medium. Changes are detected in the Raman spectrum at 6.8 GPa as a consequence of a structural phase transition from the tetragonal scheelite structure to the monoclinic PbWO4-III structure. Two additional phase transitions are detected at 15.5 and 21.2 GPa to the previously unknown crystalline phases IV and V. The last one remains stable up to 43.3 GPa. At 47.7 GPa all Raman modes disappear, which could be caused by a pressure-induced amorphization. All structural changes are reversible, being the scheelite phase recovered at ambient pressure.…
Lattice dynamics ofYVO4at high pressures
2010
We report an experimental and theoretical lattice-dynamics study of yttrium orthovanadate $({\text{YVO}}_{4})$ up to 33 GPa together with a theoretical study of its structural stability under pressure. Raman-active modes of the zircon phase are observed up to 7.5 GPa, where the onset of an irreversible zircon-to-scheelite phase transition is detected, and Raman-active modes in the scheelite structure are observed up to 20 GPa, where a reversible second-order phase transition occurs. Our ab initio total-energy calculations support that the second-order phase transition in ${\text{YVO}}_{4}$ is from the scheelite to the monoclinic M-fergusonite structure. The M-fergusonite structure remains u…
Polymorphism of praseodymium orthovanadate under high pressure
2021
Zircon-type $\mathrm{PrV}{\mathrm{O}}_{4}$ has been studied at high pressures and room temperature by means of synchrotron powder x-ray diffraction. At room temperature, we observed the previously known zircon-to-monazite phase transition at 5.5(4) GPa and a second phase transition from monazite to a monoclinic structure at 12.7(8) GPa, which we identified as a $\mathrm{PbW}{\mathrm{O}}_{4}$-III-type phase. This conclusion is supported by our ab initio calculations, which also predict a scheelite-type phase to be stable at high pressure. Motivated by this finding, we subjected zircon-type $\mathrm{PrV}{\mathrm{O}}_{4}$ samples to high pressure (7 GPa) and temperature (600, 800, and 1000 \if…
Lattice dynamics of zircon-type NdVO4 and scheelite-type PrVO4 under high-pressure
2021
Abstract Zircon-type NdVO4 and scheelite-type PrVO4 have been studied by means of Raman spectroscopy up to approximately 20 GPa. In the first compound, zircon-scheelite and scheelite-fergusonite phase transitions are reported at 6.4(3) and 19.6(4) GPa, respectively. In the case of scheelite-type PrVO4, a reversible phase transition to a PbWO4-III structure is observed at 16.8(5) GPa. In both cases, a scheelite-type structure is recovered in a metastable state at low pressures. The pressure evolution of the Raman modes is also reported. Our experimental findings are supported by ab initio calculations, which allowed us to discuss the role of mechanic and dynamical instabilities in the phase …
The Psycho-Biological Bases of Sports Supporters' Behaviour: The Virtuous Supporter
2012
Given current studies in moral psychology and following recent cases of wrong behaviour occurred in elite sporting events – e.g. the racist chants scandals in the English Premier League or the events following Mourinho's poke in the eye scandal – I shall analyse the extent to which supporters' brain make-up is determining them to behave in an ‘unfair way’. Yet this paper is not just a work on descriptive ethics, but a normative ethics work. Therefore, once I have developed the ‘psycho-biological account of sports supporters’, I shall explore whether or not a more virtuous account of sports supporting can be drawn. In order to fulfil this normative task I shall appeal to the concept of ‘fair…
Reasons for officiating soccer : the role of passion-based motivations among Norwegian elite and non-elite referees
2015
Les raisons de l’arbitrage en football : Le role des motivations basees sur la passion parmi les arbitres elite et non-elite norvegiensCette etude examine les raisons de l’investissement des arbitres de football elite et non-elite norvegiens. Quatre-vingt-trois arbitres elite et 44 non-elite ont complete un questionnaire en ligne (SurveyXact) interrogeant leurs trois principales raisons d’exercer la fonction d’arbitre de football. Les donnees ont ete obtenues par epoche, intuition et description de leurs differentes raisons. Trois principales categories descriptives emergent (pourcentage elite/non-elite) : les motivations liees a la passion (57/25 %), les motivations sociales (25/25 %) et l…
Sedimentological implications of an unusual form of the trace fossil Rhizocorallium from the Lower Muschelkalk (Middle Triassic), S. Poland
2011
Specimens of the trace fossil Rhizocorallium isp. with retrusive limbs occur in 10–20-cm-thick composite beds: the bottom layers contain abundant Planolites and Thalassinoides trace fossils, and the top layers are built of horizontally bedded pelitic limestone and contain less bioturbational structures. The first specimens of Rhizocorallium isp. occur just 2–3 cm above the lower surfaces of the top layers. The horizontal protrusive sections are 1 cm high and 1 cm wide. At some sites, the horizontal tunnels end, and the limbs become first obliquely retrusive (45°) at a distance of 1.5–2.5 cm, and then vertically retrusive at a distance of 4–6 cm, or at once vertically retrusive at a similar …