Search results for "Energy Transfer"
showing 10 items of 240 documents
Photochemical and photocatalytic isomerization of trans -caffeic acid and cyclization of cis -caffeic acid to esculetin
2016
Abstract The photoisomerization of trans-caffeic acid to cis-caffeic acid has been studied in the presence of N2 in homogeneous aqueous solutions and in suspensions of various TiO2 catalysts. The results supported the hypothesis of an energy transfer process from TiO2 to the substrate due to the recombination of the photogenerated electron–hole pairs. The differences among the measured photostationary [cis]/[trans] ratios have been attributed to the different physico-chemical properties of the catalysts. In particular, the lowest ratio measured in the presence of Merck TiO2 was ascribed to the very low adsorption of trans-caffeic acid onto the surface of this sample. In the presence of O2 a…
The photophysics and photochemistry of cofacial free base and metallated bisporphyrins held together by covalent architectures
2007
Abstract This review focuses on the photophysical properties of bisporphyrin systems held in a face-to-face configuration by covalent bonds via flexible or rigid spacers and metal–metal bonds. The cofacial arrangement induces intramolecular bismacrocycle interactions promoting basic photophysical events such as excitonic interactions and energy and electron transfers. These events are relevant to mimic light harvesting and reactor devices known for photosynthesis in plants, and can be monitored by luminescence and flash photolysis methods.
Exergy recovery in regasification facilities – Cold utilization: A modular unit
2009
Abstract The paper deals with the problem of cold recovery for direct utilization both in the site of regasification facility and far from it. A modular LNG regasification unit is proposed having the regasification capacity of 2 billion standard cubic meters/year of gas. The modular plant is based on use of a power cycle working with ethane or ethylene which allows operation of cold energy transfer, contained in LNG to be regasified, in a range of temperatures suitable for multipurpose use of cold, reducing regasification process irreversibility. Some electric energy is produced by the power cycle, but the own mission of modular unit proposed is addressed to deliver cold suitable for indust…
A FRET-based probe for fluorescence sensing of sulfide/sulfite analytes, using a novel long-wavelength water-soluble 7-hydroxycoumarin as report…
2015
International audience; A FRET-based fluorescent probe for the detection of sulfide and/or sulfite in aqueous buffer, was constructed by connecting the quencher moiety nitrobenzofurazan (7-nitro-1,2,3-benzoxadiazole, NBD) to a water-soluble 3-(2-benzimidazolyl)-7-hydroxycoumarin carboxylic acid through a piperazine linker. This probe exhibits good selectivity and high sensitivity for sulfite and sulfide over cysteine and other potential analytes. Furthermore, this is one of the few examples of fluorogenic coumarins whose solubility in water is maintained upon its conversion into reaction-based fluorescent probes.
Analysis of the spatial distribution of free radicals in ammonium tartrate by pulse EPR techniques
2009
Using pulse electron paramagnetic resonance (EPR) on a series of l(+)-ammonium tartrate (AT) dosimeters exposed to radiations with different linear energy transfer (LET), we assessed the ability of pulse EPR spectroscopy to discriminate the quality of various radiation beams such as (60)Co gamma-ray photons, protons and thermal neutrons at various doses by analyzing the local radical distributions produced by the different beams. We performed two types of pulse EPR investigations: two-pulse electron spin echo decay obtained by varying the microwave power, and a double electron-electron resonance (DEER) study. Both methods provide information about the dipolar interactions among the free rad…
Studying RNA Using Single Molecule Fluorescence Resonance Energy Transfer
2014
Spatial modulation of the electromagnetic energy transfer by excitation of graphene waveguide surface plasmons
2019
We theoretically study the electromagnetic energy transfer between donor and acceptor molecules near a graphene waveguide (WG). The surface plasmons (SPs) supported by the structure provide decay channels which lead to an improvement in the energy transfer rate when the donor and acceptor are localized on the same side or even on opposite sides of the WG. The modification of the energy transfer rate compared to its value in absence of the WG are calculated by deforming the integration path into a suitable path in the complex plane. Our results show that this modification is dramatically enhanced when the symmetric and antisymmetric SPs are excited. Notable effects on the spatial dependence …
Uptake and Fate of Fluorescently Labeled DNA Nanostructures in Cellular Environments: A Cautionary Tale.
2019
[Image: see text] Fluorescent dye labeling of DNA oligonucleotides and nanostructures is one of the most used techniques to track their fate and cellular localization inside cells. Here, we report that intracellular fluorescence, and even FRET signals, cannot be correlated with the cellular uptake of intact DNA structures. Live cell imaging revealed high colocalization of cyanine-labeled DNA oligos and nanostructures with phosphorylated small-molecule cyanine dyes, one of the degradation products from these DNA compounds. Nuclease degradation of the strands outside and inside the cell results in a misleading intracellular fluorescent signal. The signal is saturated by the fluorescence of th…
High resistance to X-rays and therapeutic carbon ions in glioblastoma cells bearing dysfunctional ATM associates with intrinsic chromosomal instabili…
2014
To investigate chromosomal instability and radiation response mechanisms in glioblastoma cells.We undertook a comparative analysis of two patient-derived glioblastoma cell lines. Their resistance to low and high linear energy transfer (LET) radiation was assessed using clonogenic survival assay and their intrinsic chromosome instability status using fluorescence in situ hybridization. DNA damage was analyzed by pulsed-field gel electrophoresis and by γ-H2AX foci quantification. Expression of DNA damage response proteins was assessed by immunoblot.Increased radioresistance to X-rays as well as carbon ions was observed in glioblastoma cells exhibiting high levels of naturally occurring chromo…
Kinetik der energieverbrauchenden Rückreaktion in der Atmungskette
1964
Die Kinetik der energieabhangigen Ruckreaktionen der Atmungskette wird fur die Atmungskettenkomponenten gemessen. Energiezufuhr wird durch Zusatz von ATP ausgelost. Die relative Geschwindigkeit der Ruckreaktion und der untersuchten Reaktionsschritte ist gleich gros (0,30 sec−1) bei 15°. Die Halbsattigungskonstante fur ATP in der Ruckreaktion ist 40 μM. Geschwindigkeitslimitierend fur die Ruckreaktion in der Atmungskette ist die Energieuberfuhrung von ATP. Die Hinreaktionen der Atmungskette, soweit sie zur Phosphorylierung gekoppelt ist, wird ebenfalls durch die Energieuberfuhrung auf ADP limitiert. Hohe Geschwindigkeiten der Hinreaktion lassen sich bei Entkopplung messen. Die Befunde deuten…