Search results for "Energy engineering"
showing 10 items of 1099 documents
FAPb0.5Sn0.5I3: A Narrow Bandgap Perovskite Synthesized through Evaporation Methods for Solar Cell Applications
2020
The tunability of the optoelectrical properties upon compositional modification is a key characteristic of metal halide perovskites. In particular, bandgaps narrower than those in conventional lead‐based perovskites are essential to achieve the theoretical efficiency limit of single‐absorber solar cells, as well as develop multijunction tandem devices. Herein, the solvent‐free vacuum deposition of a narrow bandgap perovskite based on tin-lead metal and formamidinium cation is reported. Pinhole‐free films with 1.28 eV bandgap are obtained by thermal codeposition of precursors. The optoelectrical quality of these films is demonstrated by their use in solar cells with a power conversion effici…
Improving the Long‐Term Stability of Doped Spiro‐Type Hole‐Transporting Materials in Planar Perovskite Solar Cells
2021
The improvement of the long-term stability of perovskite-based solar cells (PSCs) toward commercialization is closely linked to the development of cutting-edge charge-transporting materials. The progress on the design and the synthesis of new hole-transporting materials (HTMs) is synergistically attaining both top efficiencies and promising stability. Herein, the synthesis and characterization of two doped-HTMs based on electron-rich spiranic cores, namely, 9H-quinolinophenoxazine (spiro-POZ) and 9H-quinolinophenothiazine (spiro-PTZ), are presented. The novel HTMs exhibit excellent solubility, optimal highest occupied molecular orbital energy, and excellent thermal stability with glass tran…
Femtosecond Raman time-resolved molecular spectroscopy
2004
Abstract The applicability of several femtosecond time resolved non-linear coherent techniques such as Raman induced polarization spectroscopy (RIPS), degenerate four-wave mixing (DFWM) and coherent anti-Stokes Raman spectroscopy (CARS) for molecular spectroscopy is presented. All methods rely on the initial coherent excitation of molecular states producing wavepackets, whose time evolution is then measured. In the case of RIPS and DFWM only pure rotational transitions are involved, whereas in CARS vibrational states can be excited. First the methodology of concentration and temperature measurements using RIPS in gas mixtures involving N2, CO2, O2, and N2O is shown. In addition some applica…
Numerical analysis of light soaking phenomenon in Ruthenium based Dye Sensitized Solar Cells
2017
Dye Sensitized Solar Cells (DSSCs) are widely considered one of the most promising third generation photovoltaic devices, especially thanks to their relatively low cost if compared to conventional solar cells. An interesting phenomenon affecting such devices is the so-called light soaking effect, consisting in the increase of cell main electrical parameters after the exposition to solar light. In this work, starting from the experimental characterization carried out on Ruthenium-based DSSCs, we report on a series of numerical analysis performed to better describe the above-mentioned light soaking effect in order to show the relationship between such phenomenon and the main physical paramete…
Enamine-based hole transporting materials for vacuum-deposited perovskite solar cells
2020
In a short period of time, the rapid development of perovskite solar cells attracted a lot of attention in the science community with the record for power conversion efficiency being broken every year. Despite the fast progress in power conversion efficiency there are still many issues that need to be solved before starting large scale commercial applications, such as, among others, the difficult and costly synthesis and usage of toxic solvents for the deposition of hole transport materials (HTMs). We herein report new enamine-based charge transport materials obtained via a simple one step synthesis procedure, from commercially available precursors and without the use of expensive organomet…
Preparation of Highly Porous Carbonous Electrodes by Selective Laser Sintering
2019
Selective laser sintering (SLS) 3D printing was utilized to fabricate highly porous carbonous electrodes. The electrodes were prepared by using a mixture of fine graphite powder and either polyamide-12, polystyrene, or polyurethane polymer powder as SLS printing material. During the printing process the graphite powder was dispersed uniformly on the supporting polymer matrix. Graphite’s concentration in the mixture was varied between 5 and 40 wt % to find the correlation between the carbon content and conductivity. The graphite concentration, polymer matrix, and printing conditions all had an impact on the final conductivity. Due to the SLS printing technique, all the 3D printed electrodes …
Experimental Characterization of the Human Meniscal Tissue
2018
The meniscus plays a critical role in load transmission, stability and energy dissipation in the knee joint. Loss of the meniscus leads to joint degeneration and osteoarthritis. In a number of cases replacement of the resected meniscal tissue by a synthetic implant might avoid the articular cartilage degeneration. None of the available implants presents optimal biomechanics characteristic due to the fact the biomechanics functionality of the meniscus is not yet fully understood. Mimicking the native biomechanical characteristics of the menisci seems to be the key factor in meniscus replacement functioning. This is extremely challenging due to its complex inhomogeneous microstructure, the la…
Hybrid Tribo-Piezo-Electric Nanogenerator with Unprecedented Performance Based on Ferroelectric Composite Contacting Layers
2019
This research was supported by the European Regional Development Fund within the project ‘‘Hybrid energy harvesting systems’’ 1.1.1.1./16/A/013.
Opportunity of metallic interconnects for ITSOFC : Reactivity and electrical property.
2006
International audience; Iron-base alloys (Fe-Cr) are proposed hereafter as materials for interconnect of planar-type intermediate temperature solid oxide fuel cell (ITSOFC); they are an alternative solution instead of the use of ceramic interconnects. These steels form an oxide layer (chrornia) which protects the interconnect from the exterior environment, but is an electrical insulator. One solution envisaged in this work is the deposition of a reactive element oxide coating, that slows down the formation of the oxide layer and that increases its electric conductivity. The oxide layer, formed at high temperature on the uncoated alloys, is mainly composed of chromia; it grows in accordance …
Elastic configurations of self-supported oxide membranes for fuel cells
2013
Abstract Ultra-thin oxide films are of interest in energy conversion technologies such as low temperature solid oxide fuel cells and permeation membranes. Understanding their thermo-mechanical stability is an important problem. Edge clamped, self-supported thin film membranes show hierarchical wrinkles; with the largest wavelengths in the center, while smaller ones arise near the clamped boundary; correspondingly the largest strains, with tensile stress comparable to the residual stress, are in the vicinity of the clamped boundary. Our results can be understood by simple scaling arguments and are valid for membranes in the post-buckling regime far from threshold. We confirm the validity of …