Search results for "Entropy"

Thermodynamic Interaction Parameters of Tetra-n-undecylcalix[4]resorcinarenes with Selected Solvents Studied by Inverse Gas Chromatography

2004

The basic thermodynamic parameters, characterising intermolecular interactions of tetra-n-undecylcalix[4]resorcinarene and its octaacetate derivative with simple organic solutes, were calculated by using the inverse gas chromatography method. Free energy, enthalpy and entropy of sorption were determined.

Entropy Flux far from equilibrium in solids and in non-viscous gases

2004

Entropy Flux in Non-Equilibrium Thermodynamics

2004

Some Necessary Revisions of the Neuronal Model Concept of the Orienting Response

1978

Sokolov's neural trace model as well as his entropy model of the orienting response are examined. Both seem inadequate for empirical and theoretical reasons. The role of the relevance aspect of a stimulus is stressed. It is proposed to consider the information transmitted by a stimulus as in some way being weighted by the relevance of the context to which it belongs. It is furthermore proposed to restrict the neural trace concept to the physical properties of the stimulus. Major theoretical gain is achieved by viewing information content of a stimulus and its physical properties independently and by breaking the motivation determining the strength of an orienting response into a situation-s…

1977

The thermal behavior of cycloalkanes (CH2)n with 12 ≤ n ≤ 84 prepared by metathesis reaction of cyclododecene, GPC separation of the oligomers, and hydrogenation has been investigated. The molar enthalpies of fusion being lower by a certain amount than those of the corresponding n-alkanes are a linear function of the chain length n. The entropy of fusion per CH2 increases with chain length in a not-linear mode (when plotted vs. 1/n). The melting points of the cycloalkanes are lower than those of the corresponding n-alkanes, the difference becoming smaller with increasing chain length.

Evaluation of entropies of fusion of polychlorinated naphthalenes by model congeners: A DSC study

2006

Abstract Thirteen congeners of polychlorinated naphthalenes (PCN) were synthesized and studied by differential scanning calorimetry (DSC). Melting points (Tm) were obtained for all thirteen, and enthalpies of fusion (ΔHf) were obtained for nine congeners. Melting points of other PCNs, except for five, were found in literature. In addition, experimental ΔHf values determined by DSC were found only for 1- and 2-mono-chloronaphthalenes in the literature. The missing or uncertain values of the eight melting points and 64 enthalpies of fusion were estimated by multiple linear regressions using a set of thirteen molecular descriptors as candidates for independent variables. The stepwise model of …

Large solutions for nonlinear parabolic equations without absorption terms

2012

In this paper we give a suitable notion of entropy solution of parabolic $p-$laplacian type equations with $1\leq p<2$ which blows up at the boundary of the domain. We prove existence and uniqueness of this type of solutions when the initial data is locally integrable (for $1<p<2$) or integrable (for $p=1$; i.e the Total Variation Flow case).

A Fisher–Kolmogorov equation with finite speed of propagation

2010

Abstract In this paper we study a Fisher–Kolmogorov type equation with a flux limited diffusion term and we prove the existence and uniqueness of finite speed moving fronts and the existence of some explicit solutions in a particular regime of the equation.

Performance assessment of individual and ensemble data-mining techniques for gully erosion modeling

2017

Gully erosion is identified as an important sediment source in a range of environments and plays a conclusive role in redistribution of eroded soils on a slope. Hence, addressing spatial occurrence pattern of this phenomenon is very important. Different ensemble models and their single counterparts, mostly data mining methods, have been used for gully erosion susceptibility mapping; however, their calibration and validation procedures need to be thoroughly addressed. The current study presents a series of individual and ensemble data mining methods including artificial neural network (ANN), support vector machine (SVM), maximum entropy (ME), ANN-SVM, ANN-ME, and SVM-ME to map gully erosion …

Entropy-Based Behavioural Efficiency of the Financial Market

2021

The most known and used abstract model of the financial market is based on the concept of the informational efficiency (EMH) of that market. The paper proposes an alternative which could be named the behavioural efficiency of the financial market, which is based on the behavioural entropy instead of the informational entropy. More specifically, the paper supports the idea that, in the financial market, the only measure (if any) of the entropy is the available behaviours indicated by the implicit information. Therefore, the behavioural entropy is linked to the concept of behavioural efficiency. The paper argues that, in fact, in the financial markets, there is not a (real) informational effi…