Search results for "Environmental remediation"

Quantitative study of the capture of silver nanoparticles by several kinds of soils

2018

The capacity of different soils to capture silver nanoparticles (AgNPs) by measuring changes of an AgNP intrinsic property such as the plasmon for the first time, was studied. In-tube solid-phase microextraction (IT-SPME) coupled on-line to capillary liquid chromatography (CapLC) with diode array detection (DAD) was employed for measuring the interactions between soil and in-contact AgNP dispersions. Its achieved LOD 9 pM assures quantitative retention measurements and selectivity for soil lixiviation was suitable. Electronic microscopy was employed for corroborating the entrapped Ag into the soils. Capture % of AgNPs was calculated in compost (>99%), mountain (>99%), orchard (15±1%) and ur…

Remediation of Soil Contamination with Heavy Metals by Using Zeolite and Humic Acid Additives

2012

- Soil remediation at contaminated sites very often needs customized approach, because of the different content of pollutants. Various technologies from simple soil excavation and transporting to hazardous waste landfills to different kinds of remediation by vitrification and the use of additives can be used for the treatment of soil. A series of remediation experiments using zeolites and humic acids were applied to soil contaminated with copper. Remediation can be performed with easily available additive materials of natural origin found near the place of application, in order to diminish the leaching of contaminants. Soils contaminated and spiked with copper were mixed with additives, and…

Carbon-based ionic liquid gels: alternative adsorbents for pharmaceutically active compounds in wastewater

2021

With the aim of obtaining adsorbent systems to be used for the removal of pharmaceutically active compounds (PhACs) from wastewater, some hybrid ionic liquid gels (HILGs) were obtained from the combination of ionic liquid-based supramolecular gels and carbon materials, like graphite, graphene and graphene oxide (graphene OX). The properties of HILGs were investigated by determining their gel–sol transition temperature and rheological features. They were tested for the removal of PhACs belonging to different pharmaceutical classes, like antibiotics, antidepressants, anti-inflammatory. In particular, the removal of carbamazepine (CBZ), diclofenac sodium salt (DCF), ciprofloxacin (CPX) and nal…

Ionic Liquid Gels: Tunable and Multifaceted Materials

Materials based on ionic liquids retain properties of solvent components, like low vapor pressure, high thermal stability and structure tunability. The latter allows changing properties of materials by making small variations in the cation or anion structure, opening the way to a plethora of different applications. In this context, ionic liquid gels can represent a challenge especially if they are obtained from gelation of ionic liquid binary mixtures or of organic salts in ionic liquids. In the framework of our interest in studying ionic liquids properties and applications, in the last few years, we have addressed our attention to the obtainment of ionic liquid gels.1 We have deeply invest…

Environmental remediation using nanomaterial as adsorbents for emerging micropollutants

2023

Water shortage and scarcity are issues of global concern. Water pollution caused by organic micropollutants further aggravates the problem, by rendering an already scarce resource unfit for human consumption. The existing conventional wastewater treatment methods and infrastructure were not designed to eliminate micropollutants. Therefore, their inefficiencies call for modern methods for removing emerging micropollutant residues such as Active Pharmaceutical Ingredients (APIs), Endocrine Disrupting Compounds (EDCs), personal care products and pesticides. The use of nanomaterials, for the abatement of micropollutants in water is gaining traction in recent years, due to the abundance of susta…