Search results for "Epos"
showing 10 items of 1649 documents
GROWTH AND PHOTOELECTROCHEMICAL BEHAVIOUR OF ELECTRODEPOSITED ZnO THIN FILMS FOR SOLAR CELLS
2012
Thin zinc oxide films were deposited potentiostatically from zinc nitrate aqueous solutions on ITO substrates. The influence of experimental parameters (temperature, electrolyte concentration, deposition potential) on structure and morphology of films was investigated. Deposited films were generally polycrystalline in structure, even if growth according to preferential planes occurs in certain conditions. The effect of thermal treatments in air at 150 and 350 °C was also studied. In some cases, Cl species were incorporated into deposit by adding zinc chloride to the electrolyte. A photoelectrochemical investigation, performed in neutral solution before and after thermal treatment, gives mor…
Fabrication of metal nano-structures using anodic alumina membranes grown in phosphoric acid solution: Tailoring template morphology
2007
Abstract The influence of experimental parameters on the morphology of the porous structure and on the formation kinetics has been investigated for anodic alumina membranes (AAM) grown in aqueous H 3 PO 4 at 160 V. It was found that pore aspect ratio and membrane porosity on the solution-side surface are influenced by tensiostatic charge, bath temperature and the presence of Al 3+ ions in solution. Morphological and kinetic data, recorded in different conditions, give useful information on the growth mechanism of pore channels in phosphoric acid solution. Nickel nano-structures have been fabricated using AAM as template. Electroless deposition, performed by adding the reducing agent to a su…
ZnO nanorod arrays fabrication via chemical bath deposition: Ligand concentration effect study
2010
A new ligand, N, N, N', N'-tetramethylethylenediamine, has been used to grow ZnO nanorods on silicon substrates via a two steps approach. A preliminary seeding on silicon substrates has been combined with chemical bath deposition using a Zinc acetate - N, N, N', N'-tetramethylethylenediamine aqueous solution. The used diamino ligand has been selected as Zn(2+) complexing agent and the related hydrolysis generates the reacting ions (Zn(2-) and OH(-)) responsible for the ZnO growth. The seed layer has been annealed at low temperature (<200 degrees C) and the ZnO nanorods have been grown on this ZnO amorphous layer. There is experimental evidence that the ligand concentration (ranging from 5 t…
Study of the Chemical Conversion of Aluminum Alloys by Coupling CFDE and EQCM
2004
The ability of the channel flow double electrode (CFDE) technique and electrochemical quartz crystal microbalance (EQCM) for studying in situ chromate phosphate conversion coating on 5182 aluminum alloys was explored. It was first demonstrated that aqueous Cr(VI) can be analyzed quantitatively with the CFDE technique by reduction into Cr(III) on a graphite electrode. Samples used for EQCM were quartz plated by physical vapor deposition using a 5182 alloy target, allowing thin layers of aluminum alloys with a similar chemical composition to be obtained. EQCM was adapted in order to account for the hydrodynamic conditions in an industrial process, by placing the quartz in a flow cell. In orde…
Effect of temperature on the growth of alfa-PbO2 nanostructures
2010
Abstract Ordered arrays of α-PbO 2 nanostructures were grown by galvanostatic anodic deposition into the channels of alumina templates. Electrodepositions were performed in an aqueous solution containing lead acetate and sodium acetate at pH 5.4. Bath temperature and electrodeposition time were varied to check their effect on the growth of nanostructures. It has been found that filling of alumina pores is independent of the time and electrodeposition temperature, whilst height and growth kinetics of nanostructures vary with both parameters. Temperature greatly influences morphology: wires grown at room temperature consisted of clusters of particles, leading to poorly compact structures, whi…
Jurassic evolution of the Arabian carbonate platform edge in the central Oman Mountains
2005
International audience; The Jurassic Sahtan Group exposed in northern Oman was deposited in shallow marine environments at the edge of the Arabian Platform facing the Neo-Tethys (Hamrat Duru Basin). The upper Sahtan Group is made up of a mixed siliciclastic-carbonate unit overlain by pure carbonate deposits, assigned to a Bathonian and Early Callovian age on the basis of brachiopods and foraminifers. These carbonate depositional systems were composed of outer oolitic shoals that underwent subaerial exposure, and a deeper, somewhat restricted, gently dipping shelf interior. Oolitic material was shed off the platform edge into the deep-sea depositional complex of the Guweyza Formation. The Sa…
Continuity and discontinuity in the semantics of the Latin preposition per: a cognitive hypothesis
2009
We intend to analyse the semantic network of the preposition ‘per’ (“through”, “across” etc.) in Early Latin and the role of its conceptual structure in the spread from basic/spatial to abstract meanings. Although prepositions in ancient languages have raised a great deal of attention, there is little regarding Latin, and an in-depth semantic analysis of Latin prepositions is still lacking. A cognitive-based investigation of Plautus’ comedies (254-184 BCE) shows that, unlike other Indo-European languages, the spatial value rests on a schema representing ‘motion along a path’ not necessarily involving a bounded Landmark. The spatial meanings are predominant in Archaic Latin; the only abstrac…
Depositional model in subglacial cavities, Killiney Bay, Ireland. Interactions between sedimentation, deformation and glacial dynamics
2012
Subglacial meltwater drainage and sedimentary processes play a major role in ice-sheet dynamic but there is a lack of study of subglacial environment because modern ice-sheet beds remain inaccessible. Previous authors already intended to provide diagnostic criterion and recent investigations suggest that fluid pressure variations are a key factor in subglacial environment. This paper investigated the late Devensian sedimentary record in order to describe subglacial sedimentological facies associations and deformation features related to fluid overpressures. We used an integrated approach, based on stratigraphy, sedimentology and deformations styles to demonstrate a subglacial depositional m…
The Mediterranean Sea and the Gulf of Cadiz as a natural laboratory for paleotsunami research: Recent advancements
2021
International audience; After the 2004 Indian Ocean (IOT) and the 2011 Tohoku-oki tsunamis, new research in tsunami-related fields was strongly stimulated worldwide and also in the Mediterranean. This research growth yields substantial advancements in tsunami knowledge.Among these advancements is the “Paleotsunami” research that has marked particular progress on the reconstruction of the tsunami history of a region. As an integration of the historical documentation available in the Mediterranean and the Gulf of Cadiz areas, geological and geoarchaeological records provide the insights to define the occurrence, characteristics, and impact of tsunamis of the past. Here, we present the recent …
Materiales del Paleolítico Superior en Cova Negra (Xàtiva) y su interés para establecer los procesos de su secuencia estratigráfica
2017
En este trabajo se analizan los materiales líticos adscritos al Paleolítico Superior obtenidos en Cova Negra a lo largo de las campañas de excavación de los años 30, 50 y 80 del pasado siglo y en las campañas de 2013-2016. La atención se centra en el estudio de los soportes, los núcleos y el material retocado, y se efectúa una primera aproximación con respecto a la cronología y periodos a los que remiten las piezas retocadas. El principal interés de estos materiales reside en confirmar que la ocupación de la cavidad no se limitó al Paleolítico Medio, ni a momentos iniciales de la secuencia del Paleolítico Superior, lo que facilita una evaluación del alcance de los procesos de alteración pos…