Search results for "Epoxy"
showing 10 items of 384 documents
Modelling the Influence of Nanoparticles in the Phase Behaviour of an Epoxy/Polystyrene Mixture, 2
2007
The influences of nanoparticle size and concentration on the thermodynamic behaviour of epoxy/polystyrene blends are evaluated in the framework of Ginzburg's simple analytical theory. Two approaches have been employed: NPEPO (for particles coated with epoxy groups) and NPFEN (for particles coated with phenyl groups). Using NPEPO, the particles are found to prefer the phase richer in epoxy, whereas the opposite occurs for NPFEN. The particles size significantly influences blend compatibility. When the particle radius Rp is about the same size as the radius of gyration R g of PS, the compatibility of blends increases with particle concentration, whereas for R p > R g , higher particle concent…
Influence of the Copolymer Content on the Miscibility, Phase Behaviour and Morphology of a DGEBA/Polystyrene/Styrene-co-Maleic Anhydride Ternary Blend
2009
The miscibility, phase behaviour and morphology of ternary systems, formed by a DGEBA-based epoxy resin, polystyrene (PS) and styrene-co-maleic anhydride (SMA) copolymers have been investigated through phase diagrams. The analysis has been done in the absence and in the presence of 4,4'-methylene bis(2,6-diethyl aniline) (MDEA) as curing agent. In both cases, the influence of the copolymer content on blend compatibility, has been discussed. The results show that miscibility is enhanced by the presence of SMA copolymer in the blend and as the MA content in the copolymer is increased (from 7 to 14wt.-%), due to specific H-bonding interactions between the H-donor hydroxyl groups on the epoxy r…
Effect of CTBN rubber inclusions on the curing kinetic of DGEBA–DGEBF epoxy resin
2003
Abstract The curing kinetics of an epoxy resin matrix, based on diglycil ether of bisphenol A and F (DGEBA–DGEBF), associated with an anhydride hardener, at different carboxyl-terminated copolymer of butadiene and acrylonitrile liquid rubber (CTBN) concentration (0–10 phr) are studied using a differential scanning calorimetry (DSC) and a stress-controlled rheometer in isothermal and dynamic conditions. The aim of this work is to correlate the presence of the rubber phase with the transition phenomena that occur during the curing process. The CTBN rubber induces a catalytic effect on the polymerization of the pure resin clearly observed by a significant enhancement of the curing rate. Calori…
Viscoelastic behavior of epoxy prepolymer/organophilic montmorillonite dispersions
2008
Dispersions of a bisphenol A-based epoxy resin with an organophilic montmorillonite (Nanofil 919) were studied by X-ray diffraction and oscillatory shear rheometry. X-ray studies reveal that the clay is intercalated by the epoxy and forms stable dispersions. The viscoelastic behavior of the nanodispersions was measured as a function of the Nanofil concentration and temperature. An increase in both G′ and G″ moduli was detected as the concentration increases. Furthermore, a transition from a liquid-like behavior, at low temperatures, to a solid-like behavior, at higher temperatures, was observed for all the samples. This transition is accounted for the formation of a percolated structure of …
Drop weight tensile impact testing of adhesively bonded carbon/epoxy laminate joints
2012
Abstract Crashworthiness of composite structures is a key issue for the design of lightweight vehicles. In particular the joined parts of the structures must be able to absorb a high amount of energy in order to protect the passengers. In this paper the dynamic behavior of adhesively bonded carbon/epoxy laminate joints is investigated. The adherends are made of unidirectional plies, whose orientations are carefully chosen in order to assess the influence of the adherend mechanical properties on the joint behavior. A drop weight machine has been modified in order to impact specimens under tension. Single lap joints are tested under impact tension at velocities from 1 to 4 m/s. Results of the…
Study and comparison of interaction parameters and phase behavior of epoxy/polystyrene and epoxies copolymer polystyrene-b-poly(methyl methacrylate) …
2008
Thermodynamic studies in terms of phase separation behavior and interaction parameters, in mixtures of epoxy resins (thermoset materials) with thermoplastic additives, consisting of polystyrene (PS) or polystyrene-b-poly(methyl methacrylate) P(S-MMA) (with small proportion of MMA), have been carried out. It can be confirmed that the solubility of P(S-MMA) is an improvement on that of PS, with the prepolymer epoxy resins. Moreover, the interaction parameters are positive at temperatures in which phase separation is observed, but negative at temperatures in which the phase separation window disappears, in the corresponding phase diagram. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engine…
Modeling the influence of mineral content and porosity on ultrasound parameters in bone by using synthetic phantoms
1999
Model composite media − 10×15×80 mm3 bone tissue phantoms based on an epoxy resin with fillers—were made to study the influence of porosity and mineral content on ultrasound velocity and attenuation. The pores were simulated by ∼ 1 mm3 particles of a soft rubber, while the mineral content was imitated by a mineral residue of natural bone obtained by burning and grinding. The porosity and mineral content were varied in the range of 0–70% by volume with a step of 10%. The velocity, attenuation, and prevalent frequency of ultrasound were measured by the pulse transition method, using transducers with nominal frequencies 0.1, 0.2, 0.5, and 1.0 MHz. It was experimentally found that the ultrasoun…
Cyclic moisture sorption and its effects on the thermomechanical properties of epoxy and epoxy/MWCNT nanocomposite
2019
The aim of this work was to reveal the moisture absorption&ndash
Effect of the several epoxy resin-based sealer compositions on adhesion interface in radicular dentin after calcium hydroxide intracanal medication r…
2021
Made available in DSpace on 2022-04-29T08:32:43Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-09-01 Background: This study evaluated the effects of several epoxy resin-based sealer compositions (AHP, AH Plus; ADS, Adseal; SPL, Sealer Plus) on bond strength and intratubular dentin penetration of the endodontic obturation, in root canal previously treated with calcium hydroxide intracanal medication (CH) and removed by continuous ultrasonic irrigation (CUI). Material and Methods: Forty-five maxillary canines were prepared up to F5 (ProTaper system), filled with CH, coronally sealed, and stored at 37ºC. After 1 week, CH was removed using 2.5% sodium hypochlorite energized by CUI. The …
Effect of Fiber-Reinforced Composite and Elastic Post on the Fracture Resistance of Premolars with Root Canal Treatment—An In Vitro Pilot Study
2020
(1) Background: To analyze the fracture resistance of endodontically upper premolar teeth restored with glass fiber reinforced posts, glass fiber elastic posts, conventional composite resin (CR) and glass fiber reinforced composite (FRC) resins as restorations. (2) Methods: Seventy premolars were submitted to root canal treatment and restored with the following restorative materials (n = 10): A. FRC posts restored with resin