Search results for "Equilibrium"
showing 10 items of 1021 documents
Agglomeration without trade: how non-traded goods shape the space-economy
2004
Abstract We develop a spatial general equilibrium model in which the absence of interregional trade is an endogenous outcome. Extending the model developed by Ottaviano, Tabuchi, and Thisse (Int. Econ. Rev. 43 (2002) 409), we show that equilibria without trade differ significantly from those obtained in the presence of trade, which suggests that the presence of non-traded goods has a significant impact on spatial structures. Somewhat surprisingly, equilibrium structures without trade are richer than those with trade because partial agglomeration becomes a feasible outcome. Equilibria now depend on the ratio of mobile to immobile factors and an increase in that ratio triggers a process of sp…
Condensation of classical nonlinear waves
2005
We study the formation of a large-scale coherent structure (a condensate) in classical wave equations by considering the defocusing nonlinear Schr\"odinger equation as a representative model. We formulate a thermodynamic description of the condensation process by using a wave turbulence theory with ultraviolet cut-off. In 3 dimensions the equilibrium state undergoes a phase transition for sufficiently low energy density, while no transition occurs in 2 dimensions, in analogy with standard Bose-Einstein condensation in quantum systems. Numerical simulations show that the thermodynamic limit is reached for systems with $16^3$ computational modes and greater. On the basis of a modified wave tu…
NMR relaxation and solvation equilibrium in the ternary system CCl4-polymethylmethacrylate-benzene
2007
In the ternary system CCl4-PMMA-benzene, benzene is preferentially adsorbed in the solvation shell of the polymer. One solvation equilibrium constant allows a satisfactory description of the preferential solvation for a large range of solvent compositions. The nuclear magnetic relaxation time T1 of benzene protons was measured for different values of the polymer concentration. The measurements are compared with analogous measurements in the system C6D6-PMMA-C6H6 where no preferential solvation is to be expected. For the system CCl4-PMMA-benzene the resulting dimensionless solvation equilibrium constant is K = c32c10/c12c30 = 2.5 ± 0.5 where c10 is the CCl4 concentration in the “free” solven…
Comparison of Dissipative Particle Dynamics and Langevin thermostats for out-of-equilibrium simulations of polymeric systems
2007
In this work we compare and characterize the behavior of Langevin and Dissipative Particle Dynamics (DPD) thermostats in a broad range of non-equilibrium simulations of polymeric systems. Polymer brushes in relative sliding motion, polymeric liquids in Poiseuille and Couette flows, and brush-melt interfaces are used as model systems to analyze the efficiency and limitations of different Langevin and DPD thermostat implementations. Widely used coarse-grained bead-spring models under good and poor solvent conditions are employed to assess the effects of the thermostats. We considered equilibrium, transient, and steady state examples for testing the ability of the thermostats to maintain const…
Can stability of foreign aid agreement reduce global income inequality?
2017
Abstract Global initiatives on debt relief call for increasing foreign aid assistance to alleviate income inequality. But the potential gains from foreign aid policy coordination may be limited by the willing participation of diverse and self-interested donor countries. If stability of the foreign aid agreement does not occur, then aid effectiveness fails. Thus, the aim of this paper is to investigate the effects of the stability of foreign aid agreement on income redistribution amongst countries. The findings show that stability has positive effects on income mobility from the rich to the poorest countries reducing global income inequality.
Comparing RADseq and microsatellites for estimating genetic diversity and relatedness : Implications for brown trout conservation
2019
The conservation and management of endangered species requires information on their genetic diversity, relatedness and population structure. The main genetic markers applied for these questions are microsatellites and single nucleotide polymorphisms (SNPs), the latter of which remain the more resource demanding approach in most cases. Here, we compare the performance of two approaches, SNPs obtained by restriction-site-associated DNA sequencing (RADseq) and 16 DNA microsatellite loci, for estimating genetic diversity, relatedness and genetic differentiation of three, small, geographically close wild brown trout (Salmo trutta) populations and a regionally used hatchery strain. The genetic di…
Persistence and turnover in regional unemployment disparities
1998
PEHKONEN J. and TERVO H. (1998) Reg. Studies, 32 , 445-458, Persistence and turnover in regional unemployment disparities. This study investigates persistence and turnover in regional unemployment disparities in Finland by examining time-series data on 10 labour districts and 423 municipalities. The data on the labour districts indicates that regional unemployment disparities are rather persistent and that steady-state unemployment rates differ considerably across the districts. The results on the municipality level data, however, suggest the presence of substantial intra-distribution dynamics and that the degree of persistence is less profound than the labour district data indicates. In al…
An extension of ASM2d including pH calculation
2003
This paper presents an extension of the Activated Sludge Model No. 2d (ASM2d) including a chemical model able to calculate the pH value in biological processes. The developed chemical model incorporates the complete set of chemical species affecting the pH value to ASM2d describing non-equilibrium biochemical processes. It considers the system formed by one aqueous phase, in which biochemical processes take place, and one gaseous phase, and is based on the assumptions of instantaneous chemical equilibrium under liquid phase and kinetically governed mass transport between the liquid and gas phase. The ASM2d enlargement comprises the addition of every component affecting the pH value and an i…
Floquet analysis of excitations in materials
2019
Abstract Controlled excitation of materials can transiently induce changed or novel properties with many fundamental and technological implications. Especially, the concept of Floquet engineering and the manipulation of the electronic structure via dressing with external lasers have attracted some recent interest. Here we review the progress made in defining Floquet material properties and give a special focus on their signatures in experimental observables as well as considering recent experiments realizing Floquet phases in solid state materials. We discuss how a wide range of experiments with non-equilibrium electronic structure can be viewed by employing Floquet theory as an analysis to…
Travelling Strings, Beams, Panels, Membranes and Plates
2013
In this chapter, we will introduce in a general manner some of the most common models for axially travelling materials, which will be used in the rest of the book. We will introduce the linear models of travelling strings, panels, and plates. It will be assumed that the material is thin, i.e. its planar dimensions are much larger than its thickness. We will work in the small displacement regime, that is, with linear models approximating the behaviour of the system near the trivial equilibrium. As is well known in the theory of elasticity, this approximation allows for a decoupling of the in-plane and out-of-plane components in the dynamics of the system. We will concentrate on small out-of-…