Search results for "Eutectic system"
showing 10 items of 44 documents
Supramolecular Eutecto Gels: Fully Natural Soft Materials
2018
The obtainment of materials featured by high environmental compatibility is one of the main goals of modern research. On this subject, we herein report the first example of supramolecular gel in deep eutectic solvents. In particular, we prepared gels of the L-amino acids isoleucine and tryptophan in choline chloride/phenylacetic acid 1:2. All gel components are readily available and nontoxic. Gels have been fully characterized by standard gelation tests, rheology, X-ray diffraction, morphology and gelation kinetics. Data collected show that gels properties depend on the gelator nature. In particular, gel phases exhibit strong colloidal forces and, this high mechanical resistance, together w…
Environmentally Friendly Eutectogels Comprising l-amino Acids and Deep Eutectic Solvents: Efficient Materials for Wastewater Treatment.
2020
Current concerns for sustainability and the environment make low-impact materials desirable for environmental remediation and, in particular wastewater treatment. We obtained supramolecular gels of l-amino acids in the deep eutectic solvent formed by choline chloride and phenylacetic acid. After gel characterization, and investigating gel-sol transition temperatures, gelation kinetics, rheological properties, and morphology, the gels were applied as sorbents to remove cationic dyes from aqueous solutions. The effects of the pH, dye nature, volume, and concentration of wastewater were analyzed, and the best result was obtained with a l-phenylalanine-based eutectogel. It can be reused for at …
Physical methods to promote drug delivery on mucosal tissues of the oral cavity.
2013
Introduction: The successful of drug delivery through the mucosal tissue of the oral cavity represents a current challenge as well as a great future perspective. The need for more rapid onset of action and improved absorption of medications has resulted in great development of drug delivery technologies that use physical methods to overcome the barrier properties of oral mucosae. Areas covered: This review discusses the various physical techniques which have been, and are being, explored to sustain drug delivery in the oral cavity. In particular, supersaturation, eutectic formation, iontophoresis, electroporation, sonophoresis, laser radiation, photomechanical waves, and needleless injectio…
Experimental investigation of low-frequency pulsed Lorentz force influence on the motion of Galinstan melt
2016
Abstract The paper presents the results of the numerical and physical experiments, aimed at assessing the influence of pulsed force of electromagnetic field on the melt motion and the fluid velocities. The experiment was performed on the eutectic alloy Galinstan in the cylindrical volume, where an ultrasonic Doppler velocimeter was employed for velocity measurements under conditions of pulsed and steady EM field application. A numerical simulation of the melt flow, forced by the steady EM force, involved a 2D axisymmetric model. The k-e turbulence model was used to obtain the information about the melt velocities. The verification of the numerical model was carried out for the steady case. …
Parametric study of the influence of double-walled tubes layout on the DEMO WCLL breeding blanket thermal performances
2020
Abstract Within the framework of the EUROfusion activities regarding the EU-DEMO Breeding Blanket (BB) concept, the University of Palermo is long-time involved, in close cooperation with ENEA, in the design of the Water Cooled Lithium Lead (WCLL) BB, that is one of the two concepts under consideration for the DEMO reactor. It is mainly characterized by a liquid lithium-lead eutectic alloy acting as breeder and neutron multiplier, as well as by subcooled pressurized water flowing as coolant under PWR-like conditions (pressure of 15.5 MPa and inlet/outlet temperatures of 295 °C/328 °C). A research campaign has been recently carried out to study the potential influence of the Breeding Zone coo…
Velocity measurements in the liquid metal flow driven by a two-phase inductor
2012
We present the results of velocity measurements obtained by ultrasonic Doppler velocimetry and local potential probes in the flow of GaInSn eutectic melt driven by a two-phase inductor in a cylindrical container. This type of flow is expected in a recent modification to the floating zone technique for the growth of small-diameter single intermetallic compound crystals. We show that the flow structure can be changed from the typical two toroidal vortices to a single vortex by increasing the phase shift between the currents in the two coils from 0 to 90 degrees. The latter configuration is thought to be favourable for the growth of single crystals. The flow is also computed numerically and a …
A Bipyridine‐Palladium Derivative as General Pre‐Catalyst for Cross‐Coupling Reactions in Deep Eutectic Solvents
2019
A versatile and DES‐compatible bipyridine palladium complex has been developed as a general pre‐catalyst for different cross‐coupling reactions (Hiyama, Suzuki‐Miyaura, Heck‐Mizoroki and Sonogashira) in deep eutectic solvents. Hydrogen bond capacity of the ligand allows to keep the excellent level of results previously obtained in classical organic solvents. Palladium pre‐catalyst showed a high catalytic activity for many cross‐coupling reactions, demonstrating a great versatility and applicability. Also, this methodology employs sustainable solvents as a reaction medium and highlights the potential of DES as alternative solvents in organometallic catalysis. The catalyst and DES were easily…
Activity of a Heterogeneous Catalyst in Deep Eutectic Solvents: The Case of Carbohydrate Conversion into 5-Hydroxymethylfurfural
2019
Obtaining industrially relevant products from renewable resources and developing processes under the light of sustainable chemistry is a prominent endeavor of present-day chemical research. In this context, herein we investigated the dehydration of fructose and sucrose in deep eutectic solvents promoted by the ion-exchange resin Amberlyst 15 as heterogeneous catalyst. We optimized the reaction conditions in terms of temperature, catalyst loading, and initial amount of substrate. Then, we looked at the effect of structural variations in the solvent components on the reaction outcome. Under the best experimental conditions, we obtained very good yields of 78% at 60 °C and 69% at 80 °C for fru…
A comparison between the chemical behaviour of lead-gold and lead-bismuth eutectics towards 316L stainless steel
2013
Radiochimica acta, 101 (10)
Thermal-hydraulic and thermo-mechanical simulations of Water-Heavy Liquid Metal interactions towards the DEMO WCLL breeding blanket design
2019
Abstract The Water-Cooled Lithium Lead breeding blanket concept foresees the eutectic lithium-lead (Pb-15.7Li) alloy being cooled by pressurized sub-cooled water (temperature 295–328 °C; pressure 15.5 MPa) flowing in double wall tubes. Therefore, the interaction between the Pb-15.7Li and water (e.g. tube rupture) represents one of the main safety concerns for the design and safety analysis. Available LIFUS5/Mod2 experimental data are employed to assess the performances of thermal-hydraulic and thermo-mechanic codes. Thermal-hydraulic simulations, by SIMMER-III code, are focused on the prediction of the thermodynamic interaction among the fluids. ABAQUS Finite Element code, used for the desi…