Search results for "Exchange"

Oxide-based nanomaterials for fuel cell catalysis:the interplay between supported single Pt atoms and particles

2017

The concept of single atom catalysis offers maximum noble metal efficiency for the development of low-cost catalytic materials. Among possible applications are catalytic materials for proton exchange membrane fuel cells. In the present review, recent efforts towards the fabrication of single atom catalysts on nanostructured ceria and their reactivity are discussed in the prospect of their employment as anode catalysts. The remarkable performance and the durability of the ceria-based anode catalysts with ultra-low Pt loading result from the interplay between two states associated with supported atomically dispersed Pt and sub-nanometer Pt particles. The occurrence of these two states is a co…

The effect of interface roughness on exchange bias in La0.7Sr0.3MnO3 - BiFeO3 heterostructures

2016

We characterized the interfaces of heterostructures with different stack sequences of La0.7Sr0.3MnO3/BiFeO3 (LSMO/BFO) and BFO/LSMO using TEM revealing sharp and rough interfaces, respectively. Magnetometry and magnetoresistance measurements do not show a detectable exchange bias coupling for the multistack with sharp interface. Instead, the heterostructures with rough and chemically intermixed interfaces exhibit a sizable exchange bias coupling. Furthermore, we find a temperature-dependent irreversible magnetization behavior and an exponential decay of coercive and exchange bias field with temperature suggesting a possible spin-glass-like state at the interface of both stacks.

Recent Progress in the Development of Composite Membranes Based on Polybenzimidazole for High Temperature Proton Exchange Membrane (PEM) Fuel Cell Ap…

2020

[EN] The rapid increasing of the population in combination with the emergence of new energy-consuming technologies has risen worldwide total energy consumption towards unprecedent values. Furthermore, fossil fuel reserves are running out very quickly and the polluting greenhouse gases emitted during their utilization need to be reduced. In this scenario, a few alternative energy sources have been proposed and, among these, proton exchange membrane (PEM) fuel cells are promising. Recently, polybenzimidazole-based polymers, featuring high chemical and thermal stability, in combination with fillers that can regulate the proton mobility, have attracted tremendous attention for their roles as PE…

Proton conductivity through polybenzimidazole composite membranes containing silica nanofiber mats

2019

The quest for sustainable and more efficient energy-converting devices has been the focus of researchers&prime

Diamond Films as Support for Electrochemical Systems for Energy Conversion and Storage

2019

Many efforts have been dedicated to develop and study different catalysts supported materials for energy storage and conversion. Polymer electrolyte membranes (PEM) and capacitors have been topics of special interest for the scientific community, then, the research to find excellent catalyst-supports has constantly increased. The use of conductive diamond films has been proposed due to their mechanical and chemical stability properties. In this context, the application of BDD-catalyst surfaces for PEM fuel cells as well as the production of electrochemical capacitors using BDD materials have been summarized and discussed in this chapter.

Impact of Ir modification on the durability of FeNC catalysts under start-up and shutdown cycle conditions

2022

A common problem associated with FeNC catalysts is their poor stability dominated by the carbon oxidation reaction (COR). In this work, the feasibility of stabilizing FeNC catalysts with small quantities of Ir was explored. With iridium being present, instead of COR the oxygen evolution reaction should be favored. The impact on structure and morphology was investigated by 57Fe Mössbauer spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and transmission electron microscopy. The catalytic activity and durability for the oxygen reduction reaction was evaluated by rotating ring disc electrode experiments and accelerated stress tests mimicking the start-up and shutdown cycle (SS…

The Azimuthal Dependence of Exchange Bias Effect and its Analysis by Spin Glass Model in Ni0.8Fe0.2/CoxNi1−xO Bilayers

2021

Exchange bias (EB) effect has been vigorously researched for many years due to its possible applications in information storage and spintronics, especially in spin valves for magnetic recording devices. Even though many models have been expounded to this day, they do not prove convincingly the origins of EB effect. We attempt to establish the azimuthal dependence of EB effect with respect to varying the composition of the antiferromagnet CoxNi $_{\mathrm {1-x}}\text{O}$ and temperature. In this report, we deposited the bilayer thin films of Ni0.8Fe0.2/Co x Ni1− x O with $x$ varying from 0.4 to 0.8 by magnetron sputtering and studied the variation of exchange bias field and coercivity. The E…

Charge Exchange and Electron Stripping

2005

How Electrical Heterogeneity Parameters of Ion-Exchange Membrane Surface Affect the Mass Transfer and Water Splitting Rate in Electrodialysis

2020

Electrodialysis (ED) has been demonstrated as an effective membrane method for desalination, concentration, and separation. Electroconvection (EC) is a phenomenon which can essentially increase the mass transfer rate and reduce the undesirable water splitting effect. Efforts by a number of researchers are ongoing to create conditions for developing EC, in particular, through the formation of electrical heterogeneity on the membrane surface. We attempt, for the first time, to optimize the parameters of surface electrical heterogeneity for ion-exchange membranes used in a laboratory ED cell. Thirteen different patterns on the surface of two Neosepta anion-exchange membranes, AMX and AMX-Sb, w…

Ionic Liquid Composite Polybenzimidazol Membranes for High Temperature PEMFC Applications

2019

A series of proton exchange membranes based on polybenzimidazole (PBI) were prepared using the low cost ionic liquids (ILs) derived from 1-butyl-3-methylimidazolium (BMIM) bearing different anions as conductive fillers in the polymeric matrix with the aim of enhancing the proton conductivity of PBI membranes. The composite membranes prepared by casting method (containing 5 wt. % of IL) exhibited good thermal, dimensional, mechanical, and oxidative stability for fuel cell applications. The effects of anion, temperature on the proton conductivity of phosphoric acid-doped membranes were systematically investigated by electrochemical impedance spectroscopy. The PBI composite membranes containin…