Search results for "Exchange"
showing 10 items of 2035 documents
Donnan dialysis for tap-water softening
2018
In this presentation, Abdusalam Alhadid, started by introducing the problem of hard water in both domestic and industrial applications,caused by an excess of calcium and magnesium ions. It significantly decreases thelifetime and efficiency of equipment which has negative technical and economic consequences. Existing water softening technologies have several disadvantages, such as a high chemical use (crystallization, ion exchange), water and energy consumption (nanofiltration)
Electric Field Control of Spin-Dependent Dissipative Electron Transfer Dynamics in Mixed-Valence Molecules
2015
We demonstrate that the borderline class II/III magnetic MV dimers, which can be referred to as single molecule multiferroics, provide a unique possibility to achieve electric field control of the electron transfer (ET) dynamics. As an example, we consider a MV dimer d2-d1 in which an extra electron is delocalized over two spin-cores (s0 = 1/2), and the ET is spin-dependent due to the double exchange mechanism. It is assumed that the “extra” electron is coupled to the only intramolecular vibration, and a weak coupling to the dissipative subsystem (thermal bath) is taken into account. The vibronic energy levels and the wave functions of the isolated dimer (quantum part of the system) are num…
Interplay of spin-dependent delocalization and magnetic anisotropy in the ground and excited states of [Gd2@C78]− and [Gd2@C80]−
2017
The magnetic properties and electronic structure of the ground and excited states of two recently characterized endohedral metallo-fullerenes, [Gd2@C78]- (1) and [Gd2@C80]- (2), have been studied by theoretical methods. The systems can be considered as [Gd2]5+ dimers encapsulated in a fullerene cage with the fifteen unpaired electrons ferromagnetically coupled into an S = 15/2 high-spin configuration in the ground state. The microscopic mechanisms governing the Gd-Gd interactions leading to the ferromagnetic ground state are examined by a combination of density functional and ab initio calculations and the full energy spectrum of the ground and lowest excited states is constructed by means …
Assessing fat-tailed sequential forecast distributions for the Dow-Jones index with logarithmic scoring rules
2007
We use the logarithmic scoring rule for distributions to assess a variety of fat-tailed sequential forecasting distributions for the Dow-Jones industrial stock index from 1980 to the present. The methodology applies Bruno de Finetti''s contributions to understanding how to compare the quality of different coherent forecasting distributions for the same sequence of observations, using proper scoring rules. Four different forms of forecasting distributions are compared: a mixture Normal, a mixture of convex combinations of three Normal distributions, a mixture exponential power distribution, and a mixture of a convex combination of three exponential power distributions. The mixture linear com…
A framework for data integration of offshore wind farms
2013
Abstract Operation and maintenance play an important role in maximizing the yield and minimizing the downtime of wind turbines, especially offshore wind farms where access can be difficult due to harsh weather conditions for long periods. It contributes up to 25–30% to the cost of energy generation. Improved operation and maintenance (O&M) practices are likely to reduce the cost of wind energy and increase safety. In order to optimize the O&M, the importance of data exchange and knowledge sharing within the offshore wind industry must be realized. With more data available, it is possible to make better decisions, and thereby improve the recovery rates and reduce the operational costs. This …
Controlled transdermal iontophoresis by ion-exchange fiber
2000
The objective of this study was to assess the transdermal delivery of drugs using iontophoresis with cation- and anion-exchange fibers as controlled drug delivery vehicles. Complexation of charged model drugs with the ion-exchange fibers was studied as a method to achieve controlled transdermal drug delivery. Drug release from the cation-exchange fiber into a physiological saline was dependent on the lipophilicity of the drug. The release rates of lipophilic tacrine and propranolol were significantly slower than that of hydrophilic nadolol. Permeation of tacrine across the skin was directly related to the iontophoretic current density and drug concentration used. Anion-exchange fiber was te…
Hexafluoro complex of rutherfordium in mixed HF/HNO3 solutions
2008
Formation of anionic fluoride-complexes of element 104, rutherfordium, produced in the 248 Cm( 18 O, 5n) 261 Rf reaction was studied by anion-exchange on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF 6 ] 2- , was formed in the studied fluoride ion concentrations of 0.0005-0.013 M. Formation of [RfF 6 ] 2- was significantly different from that of the homologues Zr and Hf, [ZrF 6 ] 2- and [HfF 6 ] 2- ; the evaluated formation constant of [RfF 6 ] 2- is at least one-order of magnitude smaller than those of [ZrF 6 ] 2- and [HfF 6 ] 2- .
Adsorption of Db and its homologues Nb and Ta, and the pseudo-homologue Pa on anion-exchange resin in HF solution
2009
Anion-exchange chromatography of element 105, dubnim (Db), produced in the 206 Cm( 19 F, 5n) 262 Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (K d ) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta ≈ Nb > Db > Pa.
PELIGROSIDAD, ALGORITMOS Y DUE PROCESS: EL CASO STATE vs. LOOMIS
2020
El movimiento contemporáneo tendente a la sustitución de la noción de peligrosidad por el enfoque de la valoración del riesgo (risk assessment), que se inició en el ámbito del derecho penitenciario y de ejecución de las penas, está llegando a otras fases del proceso penal, como la de sentencia. Presentándose como una práctica «basada en la evidencia» (evidence-based sentencing), propugna tomar en consideración las valoraciones estructuradas del riesgo de reincidencia a la hora de determinar la clase y cuantía de la pena a imponer, para adecuarla mejor a las necesidades de prevención especial. El presente trabajo analiza críticamente una de las primeras sentencias de un tribunal supremo esta…
Echovirus 1 Entry into Polarized Caco-2 Cells Depends on Dynamin, Cholesterol, and Cellular Factors Associated with Macropinocytosis
2013
ABSTRACT Enteroviruses invade their hosts by crossing the intestinal epithelium. We have examined the mechanism by which echovirus 1 (EV1) enters polarized intestinal epithelial cells (Caco-2). Virus binds to VLA-2 on the apical cell surface and moves rapidly to early endosomes. Using inhibitory drugs, dominant negative mutants, and small interfering RNAs (siRNAs) to block specific endocytic pathways, we found that virus entry requires dynamin GTPase and membrane cholesterol but is independent of both clathrin- and caveolin-mediated endocytosis. Instead, infection requires factors commonly associated with macropinocytosis, including amiloride-sensitive Na + /H + exchange, protein kinase C, …