Search results for "Excitation"

showing 10 items of 1290 documents

Determination of the first ionization potential of technetium

2010

Using resonance ionization spectroscopy the first-ionization potential of actinium has been determined by analyzing different Rydberg series in two-color resonant laser excitation. Three individual Rydberg series were investigated, converging toward the ionic ground state and toward the first- and second-excited state of the actinium ion, respectively. A combined analysis of the convergence limits leads to a consistent value for the first-ionization potential of Ac of $43\phantom{\rule{0.16em}{0ex}}394.45\phantom{\rule{0.16em}{0ex}}(19)\phantom{\rule{0.28em}{0ex}}{\text{cm}}^{\ensuremath{-}1}$, equivalent to $5.380\phantom{\rule{0.16em}{0ex}}226\phantom{\rule{0.16em}{0ex}}(24)$ eV.

Physicschemistry.chemical_elementAtomic and Molecular Physics and OpticsIonsymbols.namesakeActiniumchemistryExcited stateRydberg formulasymbolsAtomic physicsIonization energySpectroscopyGround stateExcitationPhysical Review A
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Coherent Light Harvesting through Strong Coupling to Confined Light

2018

When photoactive molecules interact strongly with confined light modes, new hybrid light–matter states may form: the polaritons. These polaritons are coherent superpositions of excitations of the molecules and of the cavity photon. Recently, polaritons were shown to mediate energy transfer between chromophores at distances beyond the Forster limit. Here we explore the potential of strong coupling for light-harvesting applications by means of atomistic molecular dynamics simulations of mixtures of photoreactive and non-photo-reactive molecules strongly coupled to a single confined light mode. These molecules are spatially separated and present at different concentrations. Our simulations sug…

Physicsconfined lightPhotonLetterta114010405 organic chemistryChromophore010402 general chemistry7. Clean energy01 natural sciences0104 chemical sciencesDelocalized electronMolecular dynamicscoherent light harvestingChemical physicsstrong couplingPolaritonStrong couplingMoleculeGeneral Materials SciencevalokemiaPhysical and Theoretical ChemistryPhysics::Chemical Physicsta116ExcitationJournal of Physical Chemistry Letters
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Double-resonance measurements of isotope shifts and hyperfine structure in Gd I with hyperfine-state selection in an intermediate level

2000

Isotope shifts and hyperfine structure have been measured in the 4f7 5d6s2 9D6 -- X9 D6 (;38 024. 9 cm-1) transition in atomic gadolinium using high- resolution resonance ionization mass spectroscopy. Excitation was performed as a resonance-enhanced two-photon transition with the 4f7 5d6s6p 9F7 state as an intermediate level. Selective population of hyperfine states in the first excitation step allowed assignment of all transitions in the complex hyperfine spectrum of the odd isotopes 155,157Gd and evaluation of the magnetic dipole and electric quadrupole hyperfine structure constants for the X 9D6 state. Measured values for the isotope shifts of all stable Gd isotopes have been used to der…

Physicseducation.field_of_studyIsotopePopulationResonanceAtomic and Molecular Physics and OpticsKinetic isotope effectQuadrupolePhysics::Atomic PhysicsAtomic physicseducationSpectroscopyHyperfine structureExcitationPhysical Review A
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Experimental lifetime of the metastable 5D 3/2 state in Ba+

1992

A discrepancy exists between theoretical and experimental lifetimes of the metastable 5D3/2 state in Ba+. In order to redertermine that lifetime, we probe the population of the metastable 5D3/2 state of a Ba+ ion cloud stored in a Paul ion trap in the presence of He buffer gas as the function of time delay after pulsed laser excitation of this state. The measured decay rates at different buffer gas pressures are extrapolated to zero pressure and we obtain a radiative decay time of 48.0±5.9 s. This is not in agreement with theoretical predictions of about 80 s, but reduces the discrepancy from a previously reportet experimental value of 17.5 s. If the possibility of finestructure mixing to a…

Physicseducation.field_of_studyMetastabilityBuffer gasPopulationRadiative transferIon trapAtomic physicseducationAtomic and Molecular Physics and OpticsExcitationMixing (physics)IonZeitschrift f�r Physik D Atoms, Molecules and Clusters
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Nonlinear effects in optical pumping of a cold and slow atomic beam

2015

By photoionizing hyperfine (HF) levels of the Cs state $6{\phantom{\rule{0.16em}{0ex}}}^{2}{P}_{3/2}$ in a slow and cold atom beam, we find how their population depends on the excitation laser power. The long time (around $180\phantom{\rule{4pt}{0ex}}\ensuremath{\mu}\mathrm{s})$ spent by the slow atoms inside the resonant laser beam is large enough to enable exploration of a unique atom-light interaction regime heavily affected by time-dependent optical pumping. We demonstrate that, under such conditions, the onset of nonlinear effects in the population dynamics and optical pumping occurs at excitation laser intensities much smaller than the conventional respective saturation values. The ev…

Physicseducation.field_of_studyPopulation02 engineering and technologysaturation spectroscopy; mutilevel atoms; cesium; laser; absorption: photoionization; intesity; systems; state; trap021001 nanoscience & nanotechnologyLaser01 natural sciencesAtomic and Molecular Physics and OpticsNumerical integrationlaw.inventionOptical pumpinglawUltracold atom0103 physical sciencesPhysics::Atomic PhysicsLaser power scalingAtomic physics010306 general physics0210 nano-technologyeducationHyperfine structureExcitationPhysical Review A
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Photon localization versus population trapping in a coupled-cavity array

2014

We consider a coupled-cavity array (CCA), where one cavity interacts with a two-level atom under the rotating-wave approximation. We investigate the excitation transport dynamics across the array, which arises in the atom's emission process into the CCA vacuum. Due to the known formation of atom-photon bound states, partial field localization and atomic population trapping in general take place. We study the functional dependance on the coupling strength of these two phenomena and show that the threshold values beyond which they become significant are different. As the coupling strength grows from zero, field localization is exhibited first.

Physicseducation.field_of_studyQuantum Physicscavity array quantum transport open quantum systems cavity QEDPhotonQuantum decoherenceField (physics)PopulationFOS: Physical sciencesTrappingAtomic and Molecular Physics and OpticsAtomBound stateAtomic physicseducationQuantum Physics (quant-ph)Excitation
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Stimulated nutation echo: application to the driven decoherence study

2003

We study experimentally the dynamical and decay properties of the stimulated nutation echo (SNE) in a two-level spin system, the signal of which allows the observation timescale of the driven coherence relaxation to be extended. This signal appears in the transient response of the system to the second pulse at time τ1 from its start and coinciding with the duration of the first pulse. The information about the first pulse duration is imprinted into the population difference of the inhomogeneously broadened ensemble of the two-level absorbers. The decay of the SNE signal has two contributions. One originates from the population decay during the time τ between the two pulses. Another is cause…

Physicseducation.field_of_studyQuantum decoherenceCondensed matter physicsNutationPopulationPulse durationCondensed Matter PhysicsBloch equationsGeneral Materials ScienceTransient responseAtomic physicseducationExcitationCoherence (physics)Journal of Physics: Condensed Matter
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Theoretical study of energy transfer in Rb(7S) + Rb(5S) and Rb(5D) + Rb(5S) collisions

2000

We present results of theoretical studies of the non-resonant excitation transfer in Rb(7S) + Rb(5S) and Rb(5D) + Rb(5S) collisions at thermal collision energies. Rb2 adiabatic molecular terms correlating with the 5S+7S, 5S+5D and 5P+5P states of separated atoms were calculated for internuclear distances R > 20 a.u. using asymptotic approximation. Mechanisms of collisional population and quenching of the 5D state were treated on the basis of the computed molecular terms, and the respective cross-sections were calculated. Theoretical cross-sections are in good agreement with the experimental values at thermal collision energies (\(\) K).

Physicseducation.field_of_studyQuenching (fluorescence)PopulationOptical physicschemistry.chemical_elementPlasmaInelastic scatteringAtomic and Molecular Physics and OpticsRubidiumchemistryAtomic physicsAdiabatic processeducationExcitationThe European Physical Journal D
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Piezoelectric Actuated Nonlinear Energy Sink With Tunable Attenuation Efficiency

2019

Abstract Comparing to linear vibration absorbers, nonlinear energy sinks (NESs) have attracted worldwide attention for their intrinsic characteristics of targeted energy transfer or energy pumping in a relatively wide frequency range. Unfortunately, they are highly dependent on the vibration amplitude to be attenuated and will play its role only if the external load exceeds a specific threshold value. Different from the passive bistable NES, a novel piezoelectric nonlinear energy sink (PNES) is designed by introducing in-phase actuation to compensate or enhance the external vibration loads, thus triggering the NES operating in high attenuation efficiency. The nonlinear mathematic model of t…

Physicsgeographygeography.geographical_feature_categoryCantileverbusiness.industryMechanical EngineeringAttenuationCondensed Matter Physics01 natural sciencesPiezoelectricitySink (geography)010305 fluids & plasmasNonlinear systemMechanics of Materials0103 physical sciencesOptoelectronicsbusiness010301 acousticsExcitationJournal of Applied Mechanics
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High-frequency Ramsey excitation in a Penning trap

2007

The Ramsey excitation method for high-precision mass-measurements of highly-charged ions has been investigated and benchmarked using H2+ ions in the Penning-trap mass-spectrometer SMILETRAP. The reason for using H2+ ions are their high cyclotron frequency which is typical for the highly-charged ions usually used at SMILETRAP. Two-, three- and four-pulse Ramsey excitation data are analyzed with the help of recent theoretical work and are compared with the previously used single-pulse excitation data. An improvement factor of 2.9 in the statistical uncertainty is achieved. Furthermore the mass of 76Se, included in the previous Q-value measurement of the 76Ge neutrinoless double beta decay, is…

PhysicslawDouble beta decayCyclotronAtomic physicsMass spectrometryPenning trapInstrumentationMathematical PhysicsExcitationIonlaw.inventionJournal of Instrumentation
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