Search results for "Excitation"
showing 10 items of 1290 documents
Absolute frequency measurement of rubidium 5S-7S two-photon transitions.
2013
We report the absolute frequency measurements of rubidium 5S-7S two-photon transitions with a cw laser digitally locked to an atomic transition and referenced to an optical frequency comb. The narrow, two-photon transition, 5S-7S (760 nm) insensitive to first order in a magnetic field, is a promising candidate for frequency reference. The performed tests yield the transition frequency with accuracy better than reported previously.
Using optical clock transitions in Cu II and Yb III for time-keeping and search for new physics
2021
We study the $^1$S$_0 - ^3$D$_2$ and $^1$S$_0 - ^3$D$_3$ transitions in Cu II and the $^1$S$_0 - ^3$P$^{\rm o}_2$ transition in Yb III as possible candidates for the optical clock transitions. A recently developed version of the configuration (CI) method, designed for a large number of electrons above closed-shell core, is used to carry out the calculation. We calculate excitation energies, transition rates, lifetimes, scalar static polarizabilities of the ground and clock states, and blackbody radiation shift. We demonstrate that the considered transitions have all features of the clock transition leading to prospects of highly accurate measurements. Search for new physics, such as time va…
Alignment-to-orientation conversion in a magnetic field at nonlinear excitation of theD2line of rubidium: Experiment and theory
2015
We studied alignment-to-orientation conversion caused by excited-state level crossings in a nonzero magnetic field of both atomic rubidium isotopes. Experimental measurements were performed on the transitions of the $D_2$ line of rubidium. These measured signals were described by a theoretical model that takes into account all neighboring hyperfine transitions, the mixing of magnetic sublevels in an external magnetic field, the coherence properties of the exciting laser radiation, and the Doppler effect. In the experiments laser induced fluorescence (LIF) components were observed at linearly polarized excitation and their difference was taken afterwards. By observing the two oppositely circ…
Lifetime measurements of highly excited Rydberg states of strontium I
1993
Lifetimes of Rydberg states of the triplet-series 5s ns3S1 withn = 19–23, 35 and 5s nd3D3 withn = 18–20, 23–28 in the spectrum of neutral strontium have been determined. Observation of the exponential decay after excitation by a pulsed laser in a fast atomic beam and subsequent state-selective field ionization was employed. The lifetimes of the states of the3S1-series show the expectedn*3 dependence on the effective principal quantum number, while the3D3-series is disturbed by configuration mixing. Furthermore, state re-populations induced by black-body radiation have been observed.
Collinear two-photon excitation of indium rydberg states in a fast atomic beam
1986
The 29p-Rydberg state of neutral indium was produced by double resonant two-photon excitation in a fast atomic beam and detected via field ionization in a longitudinal electric field.
Robust quantum control by a single-shot shaped pulse
2013
Considering the problem of the control of a two-state quantum system by an external field, we establish a general and versatile method allowing the derivation of smooth pulses which feature the properties of high fidelity, robustness, and low area. Such shaped pulses can be interpreted as a single-shot generalization of the composite pulse-sequence technique with a time-dependent phase.
Hyperfine interaction in the Autler-Townes effect: The formation of bright, dark, and chameleon states
2017
This paper is devoted to clarifying the implications of hyperfine (HF) interaction in the formation of adiabatic (i.e., ``laser-dressed'') states and their expression in the Autler-Townes (AT) spectra. We first use the Morris-Shore model [J. R. Morris and B. W. Shore, Phys. Rev. A 27, 906 (1983)] to illustrate how bright and dark states are formed in a simple reference system where closely spaced energy levels are coupled to a single state with a strong laser field with the respective Rabi frequency ${\mathrm{\ensuremath{\Omega}}}_{S}$. We then expand the simulations to realistic hyperfine level systems in Na atoms for a more general case when non-negligible HF interaction can be treated as…
Efficient three-step, two-color ionization of plutonium using a resonance enhanced 2-photon transition into an autoionizing state
2004
Resonance ionization mass spectrometry (RIMS) has proven to be a powerful method for isotope selective ultra-trace analysis of long-lived radioisotopes. For plutonium detection limits of $\rm 10^{6}$ to $\rm 10^{7}$ atoms have been achieved for various types of samples. So far a three-step, three-color laser excitation scheme was applied for efficient ionization. In this work, a two-photon transition from an excited state into a high-lying autoionizing state, will be presented, yielding a similar overall efficiency as the three-step, three-color ionization scheme. In this way, only two tunable lasers are needed, while the advantages of a three-step, three-color excitation (high selectivity,…
Pairing-excitation versus intruder states inNi68andZr90
2010
A discussion on the nature of the 0{sup +} states in {sup 68}Ni (Z=28, N=40) is presented and a comparison is made with its valence counterpart {sup 90}Zr (Z=40, N=50). Evidence is given for a 0{sup +} proton-intruder state at only {approx}2.2-MeV excitation energy in {sup 68}Ni, while the analogous neutron-intruder states in {sup 90}Zr reside at 4126 and 5441 keV. The application of a shell-model description of 0{sup +} intruder states reveals that many pair-scattered neutrons across N=40 have to be involved to explain the low excitation energy of the proton-intruder configuration in {sup 68}Ni.
A comparison of density-functional-theory and coupled-cluster frequency-dependent polarizabilities and hyperpolarizabilities
2005
The frequency-dependent polarizabilities and hyperpolarizabilities of HF, CO, H2O and para-nitroaniline calculated by density-functional theory are compared with accurate coupled-cluster results. Whereas the local-density approximation and the generalized gradient approximation (BLYP) perform very similarly and overestimate polarizabilities and, in particular, the hyperpolarizabilities, hybrid density-functional theory (B3LYP) performs better and produces results similar to those obtained by coupled-cluster singles-and-doubles theory. Comparisons are also made for singlet excitation energies, calculated using linear response theory.