Search results for "Explosive"

Tests against stationary and explosive alternatives in vector autoregressive models

2008

.  The article proposes new tests for the number of unit roots in vector autoregressive models based on the eigenvalues of the companion matrix. Both stationary and explosive alternatives are considered. The limiting distributions of test statistics depend only on the number of unit roots. Size and power are investigated, and it is found that the new test against some stationary alternatives compares favourably with the widely used likelihood ratio test for the cointegrating rank. The powers are prominently higher against explosive than against stationary alternatives. Some empirical examples are provided to show how to use the new tests with real data.

Molecularly Imprinted Silver Nanocomposites for Explosive Taggant Sensing

2021

Exposure assessment of a burning ground for chemical ammunition on the Great War battlefields of Verdun

2007

The destruction of arsenical shells from the 1914/18 war in the vicinity of Verdun (France) during the 1920s resulted in a locally limited but severe soil contamination by arsenic and heavy metals. At the study site, the main part of the contaminant inventory occurs in the upper 20 cm of the topsoil which is essentially composed of combustion residues. Besides, some Cu (cmax.=16,877 mg/kg) and Pb (cmax.=26,398 mg/kg) in this layer, As (cmax.=175,907 mg/kg) and Zn (cmax.=133,237 mg/kg) were detected in very high concentrations. The mobilities of Cu, Mn, Pb and Zn in the soil system were derived from ammonium nitrate eluates. They are strongly influenced by the soil pH and can be described by…

Submarine deposits from pumiceous pyroclastic density currents traveling over water: An outstanding example from offshore Montserrat (IODP 340)

2017

© 2016. Geological Society of America. All right reserved. Pyroclastic density currents have been observed to both enter the sea, and to travel over water for tens of kilometers. Here, we identified a 1.2-m-thick, stratified pumice lapilli-ash cored at Site U1396 offshore Montserrat (Integrated Ocean Drilling Program [IODP] Expedition 340) as being the first deposit to provide evidence that it was formed by submarine deposition from pumice-rich pyroclastic density currents that traveled above the water surface. The age of the submarine deposit is ca. 4 Ma, and its magma source is similar to those for much younger Soufrière Hills deposits, indicating that the island experienced large-magnitu…

Generation of CO2-rich melts during basalt magma ascent and degassing

2013

International audience; To test mechanisms of basaltic ma gma degassing, continuous decompressions of volatile-bearing (2.7-3.8 wt% H2O, 600-1300 ppm CO2) Stromboli melts were performed from 250-200 to 50-25 MPa at 1180-1140°C. Ascent rates were varied from 0.25 to ~ 1.5 m/s. Glasses after decompression show a wide range of textures, from totally bubble-free to bubble-rich, the latter with bubble number densities from 104 to 106/cm3, similar to Stromboli pumices. Vesicularities range from 0 to ~ 20 vol%. Final melt H2O concentrations are homogeneous and always close to solubilities. In contrast, the rate of vesiculation controls the final melt CO2 concentration. High vesicularity charges ha…

Turmoil at Turrialba Volcano (Costa Rica): Degassing and eruptive processes inferred from high-frequency gas monitoring

2016

OVSICORI Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San José. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high‐frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2‐rich gas (CO2/Stotal > 4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2 weeks before eruptions, which are acc…

Rapid laccolith intrusion driven by explosive volcanic eruption

2016

Magmatic intrusions and volcanic eruptions are intimately related phenomena. Shallow magma intrusion builds subsurface reservoirs that are drained by volcanic eruptions. Thus, the long-held view is that intrusions must precede and feed eruptions. Here we show that explosive eruptions can also cause magma intrusion. We provide an account of a rapidly emplaced laccolith during the 2011 rhyolite eruption of Cordón Caulle, Chile. Remote sensing indicates that an intrusion began after eruption onset and caused severe (>200 m) uplift over 1 month. Digital terrain models resolve a laccolith-shaped body ∼0.8 km3. Deformation and conduit flow models indicate laccolith depths of only ∼20–200 m and ov…

Protection concepts from optical radiation used in places of danger from explosion of gases, vapour or cloud of particles

2005

Use of optical systems in hazardous locations can result in ignition of surrounding explosive atmosphere. The conducted research work allowed to propose three protection concepts. The primary protection concept - inherently safe optical radiation - consists in use of optical radiation with power, energy or irradiance incapable of causing ignition of surrounding explosive atmosphere. However, the arbitrary determination of values of these parameters is considered as excessively rigorous. The work presents the proposed protection concepts in relation to zone classification. The author describes his own method to determine safe values based on probability mathematics that can be used not only …

Degassing of halogens from basaltic volcanism: Insights from volcanic gas observations

2009

Abstract The currently available data set of S–Cl–F abundances in volcanic gas plumes and high-temperature fumarolic gas samples from basaltic volcanism is reviewed here in the attempt to derive constraints on the modes of halogen degassing from mafic silicate melts. Apart from large volcano-to-volcano variations, reflecting remarkable differences in volatile abundances in the source magmas, each of the explored volcanoes displays large changes of SO2/HCl and SO2/HF ratios with the style of volcanic activity, with HCl/HF staying fairly constant. Halogen abundances are low and SO2/HCl and SO2/HF are high when fresh (volatile-rich) magmas sustain degassing, as during explosive eruptions, at t…

Exploring the explosive-effusive transition using permanent ultraviolet cameras

2017

Understanding the mechanisms that cause effusive eruptions is the key to mitigating their associated hazard. Here, we combine results from permanent ultra-violet (UV) cameras, and from other geophysical observations (seismic very long period, thermal, and infrasonic activity), to characterize volcanic SO2 flux regime in the period prior, during, and after Stromboli's August-November 2014 effusive eruption. We show that, in the two months prior to effusion onset, the SO2 flux levels are two times average level. We explain this anomalously high SO2 regime as primarily determined by venting of rapidly rising, pressurized SO2-rich gas pockets, produced by strombolian explosions being more frequ…