Search results for "F.U.E."
showing 10 items of 709 documents
A simple model for computing diffuse solar radiation
1989
In this paper a very simple model for predicting the daily diffuse solar radiation at any Italian location using as input few extensively measured meteorological parameters is proposed. In fact the daily diffuse radiation D, MJ.m−2.day−1, here is correlated with only the relative sunshine duration sS and the noon altitude of the sun on the 15th of the month hn, degrees, by the following equation: D=7(sS−(sinhn)1.55 . The validity of this formula is verified using monthly mean daily data from four Italian stations displaced at various latitudes or altitudes or geographical situations (inland or coastal site). The test results show that the deviations between the measured and the computed val…
THE RELATIONSHIP BETWEEN DIFFUSE AND TOTAL SOLAR RADIATION IN COMPUTER SIMULATION OF SOLAR ENERGY SYSTEMS
1978
ABSTRACT The diffuse to total radiation correlation developed by Liu and Jordan [1] was tested for three Italian locations. An acceptable agreement was found between the regression lines in [1] and the ones found for two of the three locations. Using measured hourly values of total solar radiation on a horizontal surface, the corresponding hourly values of total solar radiation on an inclined surface at 45° facing south were computed with both the Liu and Jordan and the Loudon [6] method for estimating the diffuse radiation. Results show that approximately the same degree of accuracy in the prediction is achievable with both methods and that the difference between the measured total monthly…
Instantaneous hourly and daily radiation on tilted surfaces
1991
A simple model to evaluate the irradiance incident on tilted surfaces of various orientations is proposed in this paper. It is based on the knowledge of the monthly daily average values of global and diffuse radiation on horizontal surfaces and their distributions over a period of a day. These distributions are approximated by a modified Gaussian expression with two parameters, which take into account the morning-to-afternoon asymmetries. Integrating the irradiance over a period of an hour or a day, values of monthly hourly average and daily on variously oriented surfaces have been calculated for the locations of Barcelona, Genoa, and Montreal. The calculated values are generally in good ag…
Instantaneous distribution of global and diffuse radiation on horizontal surfaces
1991
Abstract The aim of this paper is to obtain a general expression for estimating both the instantaneous global and diffuse radiations on horizontal surfaces from the respective daily values. The proposed expression is a modified Gaussian distribution with two parameters which take into account its width and the asymmetries between morning and afternoon hours. The performance of the method has been tested by comparing the theoretical hourly results with the experimental data of six actinometric stations with different geographical location and climatic conditions. The comparison has shown that the method here proposed is accurate for both the diffuse and global radiation.
Diffuse UV erythemal radiation experimental values
2007
[1] Measurements of diffuse UV erythemal radiation (UVER) using a shadowband have been corrected using the models proposed by Drummond (1956), LeBaron et al. (1990), and Batlles et al. (1995). Two different methods were used to validate these models: intercomparison with an Optronic OL754 spectroradiometer and comparison with the values simulated by two radiative transfer codes, SMARTS and SBDART. For this comparison only clear days have been used. The corrected experimental values were analyzed in order to study the average values of the diffuse UVER fraction in relation to the clearness index kt. These varied between 62%, for kt close to 0.8, and 93% for kt of 0.2–0.3. Finally, a study of…
Inorganic gels as precursors of TiO2 photocatalysts prepared by low temperature microwave or thermal treatment
2008
Abstract A simple procedure for preparing active TiO2 photocatalysts is presented. The starting materials were unusual TiO2 gels formed from TiCl4. The use of microwaves for a very short time enhanced the TiO2 crystallinity preventing an increase of particle size and minimizing the decrease of specific surface area. This result makes this preparation very attractive. The formation of the gels was monitored through measurements of viscosity. All the samples were characterized by means of X-ray diffraction, diffuse reflectance spectroscopy and BET specific surface area measurements. The photoactivity of the samples was evaluated using the photodegradation of 4-nitrophenol in liquid–solid regi…
Sol-gel synthesis and photocatalytic activity of ZnO-SnO2 nanocomposites
2014
Abstract ZnO–SnO 2 nanocomposites were synthesized by a facile sol–gel synthesis route and characterized through X-ray diffraction, BET specific surface area analysis, UV–vis diffuse reflectance spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy. The photocatalytic activity of the samples was tested using the degradation of 4-nitrophenol under UV light as model reaction. The ZnO/SnO 2 molar ratio was varied in order to study its influence on the photoefficiency of the samples. The ZnO–SnO 2 nanocomposites showed higher photoactivity than the pure oxides and in particular the sample with ZnO/SnO 2 mol…
Photocatalytic behaviour of metal-loaded TiO2 aqueous dispersions and films
2007
Abstract Titanium dioxide nanoparticles loaded with Ce, Co, Eu, Sm, W and Yb species were prepared by coprecipitation in mild conditions using TiCl 4 as precursor with the aim to enhance the photocatalytic activity, especially under visible light irradiation. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), specific surface area (SSA) determination and UV–Vis diffuse reflectance spectroscopy. The photocatalytic activity of the powders of pure and loaded TiO 2 was investigated by employing the photodegradation of 4-nitrophenol as probe reaction in a liquid–solid system. Loading with suitable amounts of W, Co and Sm resulted in a significan…
Peracetylated β‐cyclodextrin as solubilizer of arylphosphines in supercritical carbon dioxide
2006
Abstract Effect of peracetylated β-cyclodextrin on the solubility of diphenyl(4-phenylphenyl)phosphine in supercritical carbon dioxide medium has been investigated. As shown by gravimetric measurements, the presence of cyclodextrin (CD) (1 equivalent) allows to increase the solubility of phosphine (P) in supercritical carbon dioxide (scCO 2 ) (40 °C, 35.2 MPa, nominal system density 0.89 g/mL). This solubility enhancement was attributed to host–guest interactions in scCO 2 as the P was recovered in the form of an inclusion complex. Furthermore, a diffuse reflectance spectroscopy study on the samples recovered after the experiments and on various CD/P solid mixtures obtained by co-grinding i…
Characterization of estuarine sediments by near infrared diffuse reflectance spectroscopy
2008
It has been developed a partial least squares near infrared (PLS-NIR) method for the determination of estuarine sediment physicochemical parameters. The method was based on the chemometric treatment of first order derivative reflectance spectra obtained from samples previously lyophilized and sieved through a lower than 63 μm grid. Spectra were scanned from 833 to 2976 nm, averaging 36 scans per spectrum at a resolution of 8 cm-1, using chromatographic glass vials of 9.5 mm internal diameter as measurement cells. Models were built using reference data of 31 samples selected through the use of a hierarchical cluster analysis of NIR spectra of sediments obtained from the Ria de Arousa estuary…