Search results for "F300"
showing 10 items of 13 documents
Exceptionally long-lived light-emitting electrochemical cells: multiple intra-cation π-stacking interactions in [Ir(C^N)2(N^N)][PF6] emitters
2015
A series of cyclometalated iridium(iii) complexes [Ir(C^N)2(N^N)][PF6] (N^N = 2,2′-bipyridine (1), 6-phenyl-2,2′-bipyridine (2), 4,4′-di-tert-butyl-2,2′-bipyridine (3), 4,4′-di-tert-butyl-6-phenyl-2,2′-bipyridine (4); HC^N = 2-(3-phenyl)phenylpyridine (HPhppy) or 2-(3,5-diphenyl)phenylpyridine (HPh2ppy)) are reported. They have been synthesized using solvento precursors so as to avoid the use of chlorido-dimer intermediates, chloride ion contaminant being detrimental to the performance of [Ir(C^N)2(N^N)][PF6] emitters in light-electrochemical cell (LEC) devices. Single crystal structure determinations and variable temperature solution 1H NMR spectroscopic data confirm that the pendant pheny…
Magnetic phase diagram of La2−xSrxCoO4 revised using muon-spin relaxation
2016
We report the results of a muon-spin relaxation (mu SR) investigation of La2-xSrxCoO4, an antiferromagnetic insulating series which has been shown to support charge ordered and magnetic stripe phases and an hourglass magnetic excitation spectrum. We present a revised magnetic phase diagram, which shows that the suppression of the magnetic ordering temperature is highly sensitive to small concentrations of holes. Distinct behavior within an intermediate x range (0.2 <= x less than or similar to 0.6) suggests that the putative stripe ordered phase extends to lower x than previously thought. Further charge doping (0.67 <= x <= 0.9) prevents magnetic ordering for T greater than or similar to 1.…
Magnetic field dynamos and magnetically triggered flow instabilities
2017
The project A2 of the LIMTECH Alliance aimed at a better understanding of those magnetohydrodynamic instabilities that are relevant for the generation and the action of cosmic magnetic fields. These comprise the hydromagnetic dynamo effect and various magnetically triggered flow instabilities, such as the magnetorotational instability and the Tayler instability. The project was intended to support the experimental capabilities to become available in the framework of the DREsden Sodium facility for DYNamo and thermohydraulic studies (DRESDYN). An associated starting grant was focused on the dimensioning of a liquid metal experiment on the newly found magnetic destabilization of rotating flow…
Probing the physics of the solar atmosphere with the Multi-slit Solar Explorer (MUSE): I. Coronal Heating
2022
The Multi-slit Solar Explorer (MUSE) is a proposed NASA MIDEX mission, currently in Phase A, composed of a multi-slit EUV spectrograph (in three narrow spectral bands centered around 171A, 284A, and 108A) and an EUV context imager (in two narrow passbands around 195A and 304A). MUSE will provide unprecedented spectral and imaging diagnostics of the solar corona at high spatial (<0.5 arcsec), and temporal resolution (down to ~0.5s) thanks to its innovative multi-slit design. By obtaining spectra in 4 bright EUV lines (Fe IX 171A , Fe XV 284A, Fe XIX-Fe XXI 108A) covering a wide range of transition region and coronal temperatures along 37 slits simultaneously, MUSE will for the first time …
Modelling of asymmetric nanojets in coronal loops
2021
Context. Observations of reconnection jets in the solar corona are emerging as a possible diagnostic for studying highly elusive coronal heating. Such jets, and in particular those termed nanojets, can be observed in coronal loops and have been linked to nanoflares. However, while models successfully describe the bilateral post-reconnection magnetic slingshot effect that leads to the jets, observations reveal that nanojets are unidirectional or highly asymmetric, with only the jet travelling inward with respect to the coronal loop’s curvature being clearly observed. Aims. The aim of this work is to address the role of the curvature of the coronal loop in the generation and evolution of asym…
Quasi-Periodic Pulsations in Solar and Stellar Flares: A Review of Underpinning Physical Mechanisms and Their Predicted Observational Signatures
2021
The phenomenon of quasi-periodic pulsations (QPPs) in solar and stellar flares has been known for over 50 years and significant progress has been made in this research area. It has become clear that QPPs are not rare—they are found in many flares and, therefore, robust flare models should reproduce their properties in a natural way. At least fifteen mechanisms/models have been developed to explain QPPs in solar flares, which mainly assume the presence of magnetohydrodynamic (MHD) oscillations in coronal structures (magnetic loops and current sheets) or quasi-periodic regimes of magnetic reconnection. We review the most important and interesting results on flare QPPs, with an emphasis on the…
In Situ Generation of Transverse Magnetohydrodynamic Waves from Colliding Flows in the Solar Corona
2018
This research has received funding from the UK Science and Technology Facilities Council (Consolidated Grant ST/K000950/1) and the European Union Horizon 2020 Research and Innovation Programme (grant agreement No. 647214). V.M.N. acknowledges the support of the BK21 plus program through the National Research Foundation funded by the Ministry of Education of Korea. Transverse magnetohydrodynamic (MHD) waves permeate the solar atmosphere and are a candidate for coronal heating. However, the origin of these waves is still unclear. In this Letter, we analyze coordinated observations from Hinode/Solar Optical Telescope (SOT) and Interface Region Imaging Spectrograph (IRIS) of a prominence/corona…
MHD simulations of the in situ generation of kink and sausage waves in the solar corona by collision of dense plasma clumps
2019
Funding: This research has received funding from the UK Science and Technology Facilities Council (Consolidated Grant ST/K000950/1) and the European Union Horizon 2020 research and innovation programme (grant agreement No. 647214). P.A. acknowledges funding from his STFC Ernest Rutherford Fellowship (No. ST/R004285/1). This research was supported by the Research Council of Norway through its Centres of Excellence scheme, project number 262622. Context. Magnetohydrodynamic (MHD) waves are ubiquitous in the solar corona where the highly structured magnetic fields provide efficient wave guides for their propagation. While MHD waves have been observed originating from lower layers of the solar …
Focus on the Essential: Extracting the Decisive Energy Barrier of a Complex Process
2019
Molecular processes at surfaces can be composed of a rather complex sequence of steps. The kinetics of even seemingly simple steps are demonstrated to depend on a multitude of factors, which prohibits applying a simple Arrhenius law. This complexity can make it challenging to experimentally determine the kinetic parameters of a single step. However, a molecular-level understanding of molecular processes such as structural transitions requires elucidating the atomistic details of the individual steps. Here, a strategy is presented to extract the energy barrier of a decisive step in a very complex structural transition by systematically addressing all factors that impact the transition kineti…
[Cu(bpy)(P^P)]+ containing light-emitting electrochemical cells: improving performance through simple substitution
2014
Light-emitting electrochemical cells (LECs) containing [Cu(POP)(N^N)][PF6] (POP = bis(2-diphenylphosphinophenyl)ether, N^N = 6-methyl- or 6,6′-dimethyl-2,2′-bipyridine) exhibit luminance and efficiency surpassing previous copper(i)-containing LECs.