Search results for "F800"
showing 10 items of 11 documents
Intra- and inter-annual uranium concentration variability in a Belizean stalagmite controlled by prior aragonite precipitation: A new tool for recons…
2016
Aragonitic speleothems are increasingly utilised as palaeoclimate archives due to their amenability to high precision U–Th dating. Proxy records from fast-growing aragonitic stalagmites, precisely dated to annual timescales, can allow investigation of climatic events occurring on annual or even sub-annual timescales with minimal chronological uncertainty. However, the behaviour of many trace elements, such as uranium, in aragonitic speleothems has not thus far been as well constrained as in calcitic speleothems. Here, we use uranium concentration shifts measured across primary calcite-to-aragonite mineralogical transitions in speleothems to calculate the distribution coefficient of uranium …
The SISAL database: a global resource to document oxygen and carbon isotope records from speleothems
2018
Stable isotope records from speleothems provide information on past climate changes, most particularly information that can be used to reconstruct past changes in precipitation and atmospheric circulation. These records are increasingly being used to provide “out-of-sample” evaluations of isotope-enabled climate models. SISAL (Speleothem Isotope Synthesis and Analysis) is an international working group of the Past Global Changes (PAGES) project. The working group aims to provide a comprehensive compilation of speleothem isotope records for climate reconstruction and model evaluation. The SISAL database contains data for individual speleothems, grouped by cave system. Stable isotopes of oxyg…
Sr-isotope analysis of speleothems by LA-MC-ICP-MS: High temporal resolution and fast data acquisition
2017
Speleothems are well established climate archives. A wide array of geochemical proxies, including stable isotopes and trace elements are present within speleothems to reconstruct past climate variability. However, each proxy is influenced by multiple factors, often hampering robust interpretation. Sr isotope ratios (87Sr/86Sr) can provide useful information about water residence time and water mixing in the host rock, as they are not fractionated during calcite precipitation. Laser ablation multi-collector-inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) has rarely been used for determination of Sr isotope signatures in speleothems, as speleothems often do not possess appropriate…
Determination of aragonite trace element distribution coefficients from speleothem calcite–aragonite transitions.
2016
The processes that govern the incorporation of (trace) elements into speleothems can often be linked to environmental changes. Although element incorporation into speleothem calcite is now reasonably well understood, current knowledge regarding trace element variability in speleothem aragonite is very limited. Of particular interest is whether trace element distribution coefficients are above or below one in order to assess the extent to which prior aragonite precipitation has affected speleothem aragonite trace element records. This study uses nine calcite-to-aragonite transitions in seven speleothems from diverse environmental settings to derive the first quantitative estimates of the dis…
SISALv2: a comprehensive speleothem isotope database with multiple age–depth models
2020
Characterizing the temporal uncertainty in palaeoclimate records is crucial for analysing past climate change, correlating climate events between records, assessing climate periodicities, identifying potential triggers and evaluating climate model simulations. The first global compilation of speleothem isotope records by the SISAL (Speleothem Isotope Synthesis and Analysis) working group showed that age model uncertainties are not systematically reported in the published literature, and these are only available for a limited number of records (ca. 15 %, n = 107/691). To improve the usefulness of the SISAL database, we have (i) improved the database’s spatio-temporal coverage and (ii) create…
Sensitivity of Bunker Cave to climatic forcings highlighted through multi-annual monitoring of rain-, soil-, and dripwaters
2017
The last two decades have seen a considerable increase in studies using speleothems as archives of past climate variability. Caves under study are now monitored for a wide range of environmental parameters and results placed in contextwith speleothemdata. The present study investigates trends froma seven year longmonitoring of Bunker Cave, northwestern Germany, in order to assess the hydraulic response and transfer time of meteoric water fromthe surface to the cave. Rain-, soil-, and dripwaterwere collected fromAugust 2006 to August 2013 at a monthly to bimonthly resolution and their oxygen and hydrogen isotope composition wasmeasured. Furthermore, drip rates were quantified. Due to differe…
Holocene interaction of maritime and continental climate in Central Europe: New speleothem evidence from Central Germany
2019
Central European climate is strongly influenced by North Atlantic (Westerlies) and Siberian High circulation patterns, which govern precipitation and temperature dynamics and induce heterogeneous climatic conditions, with distinct boundaries between climate zones. These climate boundaries are not stationary and shift geographically, depending on long-term atmospheric conditions. So far, little is known about past shifts of these climate boundaries and the local to regional environmental response prior to the instrumental era.\ud \ud High resolution multi-proxy data (stable oxygen and carbon isotope ratios, S/Ca and Sr/Ca) from two Holocene stalagmites from Bleßberg Cave (Thuringia) are used…
Climate variations of Central Asia on orbital to millennial timescales
2016
AbstractThe extent to which climate variability in Central Asia is causally linked to large-scale changes in the Asian monsoon on varying timescales remains a longstanding question. Here we present precisely dated high-resolution speleothem oxygen-carbon isotope and trace element records of Central Asia’s hydroclimate variability from Tonnel’naya cave, Uzbekistan and Kesang cave, western China. On orbital timescales, the supra-regional climate variance, inferred from our oxygen isotope records, exhibits a precessional rhythm, punctuated by millennial-scale abrupt climate events, suggesting a close coupling with the Asian monsoon. However, the local hydroclimatic variability at both cave sit…
Improving the prediction of air pollution peak episodes generated by urban transport networks
2016
Abstract This paper illustrates the early results of ongoing research developing novel methods to analyse and simulate the relationship between trasport-related air pollutant concentrations and easily accessible explanatory variables. The final scope is to integrate the new models in traditional traffic management support systems for a sustainable mobility of road vehicles in urban areas. This first stage concerns the relationship between the hourly mean concentration of nitrogen dioxide (NO2) and explanatory factors reflecting the NO2 mean level one hour back, along with traffic and weather conditions. Particular attention is given to the prediction of pollution peaks, defined as exceedanc…
Effects of organic matter complexation on partitioning of transition metals into calcite: Cave-analogue crystal growth experiments
2022
We highlight the potential for first row transition metals to carry paleohydrological signals in speleothems, and argue that these metals constitute valuable proxies for climate reconstructions. Metal availability to speleothems is hypothesised to be restricted by organic complexation, which strongly limits the free ion activity of transition metals (Co2+, Ni2+ and Cu2+) in dripwater, thereby creating a kinetic overprint on metal concentrations and isotope ratios in speleothem calcite. This study presents the results of the first cave-analogue experiments of transition metal partitioning into calcite in the absence and presence of organic ligands. The Geological Microclimate (GeoMic) system…