Search results for "FEMTOSECOND"
showing 10 items of 238 documents
Ultrapure laser-synthesized Si nanoparticles with variable oxidation states for biomedical applications
2020
We employ a method of femtosecond laser fragmentation of preliminarily prepared water-dispersed microcolloids to fabricate aqueous solutions of ultrapure bare Si-based nanoparticles (Si-NPs) and assess their potential for biomedical applications. The nanoparticles appear spherical in shape, with low size dispersion and a controllable mean size, from a few nm to several tens of nm, while a negative surface charge (−35 mV ± 0.10 according to z-potential data) provides good electrostatic stabilization of colloidal Si-NP solutions. Structural analysis shows that the Si-NPs are composed of Si nanocrystals with inclusions of silicon oxide species, covered by a SiOx (1 < x < 2) shell, while the to…
From Seeds to Islands: Growth of Oxidized Graphene by Two-Photon Oxidation
2016
The mechanism of two-photon induced oxidation of single-layer graphene on Si/SiO2 substrates is studied by atomic force microscopy (AFM) and Raman microspectroscopy and imaging. AFM imaging of areas oxidized by using a tightly focused femtosecond laser beam shows that oxidation is not homogeneous but oxidized and nonoxidized graphene segregate into separate domains over the whole irradiated area. The oxidation process starts from point-like “seeds” which grow into islands finally coalescing together. The size of islands before coalescence is 30–40 nm, and the density of the islands is on the order of 1011 cm–2. Raman spectroscopy reveals growth of the D/G band ratio along the oxidation. Sha…
Second harmonic generation in selenium-metal structures
2009
The article examines the processes of second harmonic generation (SHG) when selenium-metal (Cu) film structures are illuminated by femtosecond radiation (180 fs, 80 MHz) at wavelength 800 – 1000 nm. Selenium-copper structures were obtained by successive thermal evaporation of selenium and copper onto the glass substrate in vacuum. Microanalysis of the film composition was performed to determine amount of copper in thin films. The as-evaporated selenium-copper structures were crystallised by annealing in inert atmosphere at temperature 85°C. Just evaporated as well as annealed thin films were explored. The experiment was performed by confocal microscope [1] where the femtosecond radiation fr…
Suspended core tellurite glass optical fibers for infrared supercontinuum generation
2011
International audience; We report the fabrication and characterization of tellurite TeO(2)-ZnO-Na(2)O (TZN) microstructured suspended core optical fibers (MOFs). These fibers are designed for infrared supercontinuum generation with zero dispersion wavelength (ZDW) at 1.451 mu m. The measured losses at this wavelength are approximately 6 dB/m for a MOF with a 2.2 mu m diameter core. The effective area of a particular fiber is 3.5 mu m(2) and the nonlinear coefficient is calculated to be 437 W(-1)km(-1). By pumping a 20 cm long fiber at 1.56 mu m with a sub-nj femtosecond laser source, we generate a supercontinuum (SC) spanning over 800 nm in the 1-2 mu m wavelength range.
Plasmon-Induced Direct Hot-Carrier Transfer at Metal-Acceptor Interfaces.
2019
Plasmon-induced hot-carrier transfer from a metal nanostructure to an acceptor is known to occur via two key mechanisms: (i) indirect transfer, where the hot carriers are produced in the metal nanostructure and subsequently transferred to the acceptor, and (ii) direct transfer, where the plasmons decay by directly exciting carriers from the metal to the acceptor. Unfortunately, an atomic-level understanding of the direct-transfer process, especially with regard to its quantification, remains elusive even though it is estimated to be more efficient compared to the indirect-transfer process. This is due to experimental challenges in separating direct from indirect transfer as both processes o…
Local photo-oxidation of individual single walled carbon nanotubes probed by femtosecond four wave mixing imaging
2014
Photo-oxidation of individual, air-suspended single walled carbon nanotubes (SWCNTs) is studied by femtosecond laser spectroscopy and imaging. Individual SWCNTs are imaged by four wave mixing (FWM) microscopy under an inert gas (Ar or N2) atmosphere. When imaging is performed in an ambient air atmosphere, the decay of the FWM signal takes place. Electron microscopy shows that SWCNTs are not destroyed and the process is attributed to photoinduced oxidation reactions which proceed via a non-linear excitation mechanism, when irradiation is performed with ∼30 fs pulses in the visible spectral region (500-600 nm). Photo-oxidation can be localized in specific regions of SWCNTs within optical reso…
Wavelength tuning of femtosecond pulses generated in nonlinear crystals by using diffractive lenses
2010
We demonstrate that diffractive lenses (DLs) can be used as a simple method to tune the central wavelength of femtosecond pulses generated from second-order nonlinear optical processes in birefringent crystals. The wavelength tunability is achieved by changing the relative distance between the nonlinear crystal and the DL, which acts in a focusing configuration. Besides the many practical applications of the so-generated pulses, the proposed method might be extended to other wavelength ranges by demonstrated similar effects on other nonlinear processes, such as high-order harmonic generation.
Towards CEP stable sub two cycle IR pulse compression with bulk material
2010
We demonstrate both experimentally and numerically that self-steepening during propagation in a hollow-fiber followed by linear propagation through glass in the anomalous dispersion enables pulse compression down to 1.9 cycles at 1.8 micron wavelength.
Amplifier similariton fibre laser with nonlinear spectral compression
2012
We propose and numerically demonstrate a new concept of fibre laser architecture supporting self-similar pulse evolution in the amplifier and nonlinear pulse spectral compression in the passive fibre. The latter process is beneficial for improving the power efficiency as it prevents strong spectral filtering from being highly dissipative.
The Peregrine soliton in nonlinear fibre optics
2010
International audience; The Peregrine soliton is a localized nonlinear structure predicted to exist over 25 years ago, but not so far experimentally observed in any physical system. It is of fundamental significance because it is localized in both time and space, and because it defines the limit of a wide class of solutions to the nonlinear Schrödinger equation (NLSE). Here, we use an analytic description of NLSE breather propagation to implement experiments in optical fibre generating femtosecond pulses with strong temporal and spatial localization, and near-ideal temporal Peregrine soliton characteristics. In showing that Peregrine soliton characteristics appear with initial conditions th…