Search results for "FFC NMR"

showing 2 items of 12 documents

FFC-NMR techniques for assessing the texture features of nanosponges

2021

Nanosponges (NSs), i.e. hyper cross linked polymeric materials obtained by reticulating cyclodextrin units with suitable linker units, constitute an emerging class of functional materials, due to their easy synthesis and chemical modification, and to their tunable absorption and controlled release abilities as well. NSs are supposed to possess a thick network of nanochannels in their highly disordered structure. However, their textural features (average pore size, specific surface and specific pore volume) are quite difficult to estimate, and classical evaluation methodologies (N2 absorption isotherms analyzed by BET or BJH methods, or dye absorption isotherms1) have afforded questionable r…

Textural propertiesNanospongesFFC NMRSettore AGR/13 - Chimica AgrariaSettore CHIM/06 - Chimica OrganicaRelaxometrySettore CHIM/02 - Chimica Fisica
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Differentiation among dairy products by combination of fast field cycling NMR relaxometry data and chemometrics

2021

A set of commercial milk and Sicilian cheeses was analysed by a combination of fast field cycling (FFC) nuclear magnetic resonance (NMR) relaxometry and chemometrics. The NMR dispersion (NMRD) curves were successfully analysed with a mathematical model applied on Parmigiano-Reggiano (PR) cheese. Regression parameters were led back to the molecular components of cheeses (water trapped in casein micelles, proteins and fats) and milk samples (water belonging to hydration shells around dispersed colloidal particles of different sizes and bulk water). The application of chemometric analysis on relaxometric data enabled differentiating milk from cheeses and revealing differences within the two sa…

milkRelaxometryMagnetic Resonance SpectroscopyChromatographyField cyclingdairy productsChemistryrelaxometryGeneral ChemistryBulk waterchemometricsMagnetic Resonance ImagingCasein micellescheeseChemometricsFFC NMRColloidal particleAnimalsGeneral Materials ScienceStatistical analysisTwo sampleMagnetic Resonance in Chemistry
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