Search results for "FRAMEWORK"
showing 10 items of 942 documents
EXPLORING THE INPUT OF COMPETENCE ASSESSMENT TO GOAL-SETTING IN VARIOUS TYPES OF ORGANIZATIONS
2018
The aim of the present research is to investigate the existing practices of linking competence assessment to organizational goal-setting in various organisations in Latvia. The importance of linking employee competences to goal-setting within organizations has been established in scientific literature. Nevertheless, there is evidence gathered in this interdisciplinary research that existing methods of competence assessment used by various organizations in Latvia do not translate well into organizational goal-setting. The research is based on information gathered from semi-structured interviews with representatives of managerial positions in private and public, including educational service …
Future of e-Government: An integrated conceptual framework
2021
Abstract The information and hyper-connectivity revolutions have caused significant disruptions in citizens’ interactions with governments all over the world. Failures in implementing e-government interventions suggest the lack of an integrated approach in understanding e-government as a discipline. In this study, we present an overarching and integrated conceptual framework of e-government grounded in robust qualitative research to describe the factors that must be integrated to implement e-government successfully. Drawing insights from 168 in-depth interviews conducted with multiple stakeholders in India, this study defines e-government as a multidimensional construct with customer orient…
Future language teachers’ pedagogical landscapes during their subject studies
2015
This article examines the experiences, attitudes and perceptions language students have regarding the use of ICT in language teaching. In addition, the article analyses the key characteristics of language students’ pedagogical designs. The data come from a pedagogically oriented subject-studies course that focuses on the Common European Framework of Reference for Languages and the European Language Portfolio. The data, which consist of language students’ reflections and course plans, have been analysed using qualitative content analysis. The findings imply that language students’ pedagogical landscapes reflect their own experiences as learners. Furthermore, the literacy practices in languag…
Territorial Governance and Rural Development: Challenge or Reality?
2020
Governance has emerged as a very solid conceptual framework within which public policies are designed and implemented, but with different added values. It constitutes a truly new institutional culture. Aspects such as the coordination of actors and institutions (and in this context, individual and collective leadership); the integration and articulation of public policies and sectors; the mobilisation, participation and cooperation of stakeholders (networking); or the development of a certain capacity to adapt to changes in the environment, among others, play a fundamental role. Territorial governance provides the added value of the territorial approach, as conceived in the framework of dev…
Aspects of phosphorus transfer from soils in Europe
2008
Imbalanced nutrient management has caused soil phosphorus (P) to become an environmental rather an agronomic problem in more economically developed countries. This subject has been the topic of numerous journal special issues, conferences, and reviews but we consider yet another review of this subject is necessary with the main target of providing a point of view on non-point transfer from soils and control strategies for an improved environmental management of P. This review considers the causes of the excessive P transfer from soil to surface water in Europe and the scientific knowledge necessary to develop control strategies. There has been an increasing trend towards the P-research inte…
Metal–Organic Frameworks as Playgrounds for Reticulate Single-Molecule Magnets
2019
Achieving an accurate control on the final structure of Metal-Organic Frameworks (MOFs) is mandatory to obtain target physical properties. Here we describe how the combination of a metalloligand design strategy and a post-synthetic method is a versatile and powerful approach to success on this extremely difficult task. In a first stage, a novel oxamato-based tetranuclear cobalt(III) complex with a tetrahedron-shape geometry is used, for the first time, as metalloligand toward cal-cium(II) cations to lead a diamagnetic Ca(II)-Co(III) three-dimensional (3D) MOF (1). In a second stage, in a single-crystal to single-crystal manner the calcium(II) ions are replaced by terbium (III), dysprosium(I…
The construction of open GdIII metal–organic frameworks based on methanetriacetic acid: New objects with an old ligand
2010
11 páginas, 11 figuras, 2 esquemas.-- et al.
Divergent Adsorption-Dependent Luminescence of Amino-Functionalized Lanthanide Metal-Organic Frameworks for Highly Sensitive NO2 Sensors
2020
International audience; A novel gas sensing mechanism exploiting lanthanide luminescence modulation upon NO2 adsorption is demonstrated here. Two isostructural lanthanide-based metal–organic frameworks (MOFs) are used, including an amino group as the sensitive recognition center for NO2 molecules. The transfer of energy from the organic ligands to Ln is strongly dependent on the presence of NO2, resulting in an unprecedented photoluminescent sensing scheme. Thereby, NO2 exposition triggers either a reversible enhancement or a decrease in the luminescence intensity, depending on the lanthanide ion (Eu or Tb). Our experimental studies combined with density functional theory and complete activ…
In-depth structural analysis of lanthanoid coordination networks based on a flexible tripodal zwitterionic isonicotinate ligand
2019
Crystallizing metal–organic frameworks (MOFs) has been studied using a tripodal pyridinecarboxylic acid derivative ligand and selected lanthanoid salts. The zwitterionic ligand, 1,1′,1′′-((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(pyridin-1-ium-4-carboxylate) (TTTPC) introduced as a bromide salt, forms coordination networks in aqueous environments and under ambient conditions with neodymium bromide, trifluoromethanesulfonate (OTf) or acetate (OAc). Seven structures are elucidated in detail using single crystal X-ray crystallography. TTTPC NdBr3, TTTPC NdBr2OTf, TTTPC NdBr(OTf)2 and TTTPC Nd(OTf)3 are porous 3D networks with similar ligand–metal and ligand–anion interactions, b…
Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks
2019
<div>Tetrathiafulvalene-Lanthanide (TTF-Ln) Metal-Organic Frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined with electronic properties such as electrical conductivity, redox activity, luminescence and magnetism. Herein we report a new family of isostructural TTF-Ln MOFs, denoted as <b>MUV-5(Ln)</b> (Ln = Gd, Tb, Dy, Ho, Er), exhibiting semiconducting properties as a consequence of the short intermolecular S···S contacts established along the chain direction between partially oxidised TTF moieties. In addition, this family shows photoluminescence properties and single-molecule magnetic behaviour, finding near-infrared …