Search results for "FS"

Confined Pt-1(1+) Water Clusters in a MOF Catalyze the Low-Temperature Water-Gas Shift Reaction with both CO2 Oxygen Atoms Coming from Water

2018

[EN] The synthesis and reactivity of single metal atoms in a low-valence state bound to just water, rather than to organic ligands or surfaces, is a major experimental challenge. Herein, we show a gram-scale wet synthesis of Pt-1(1+) stabilized in a confined space by a crystallographically well-defined first water sphere, and with a second coordination sphere linked to a metal-organic framework (MOF) through electrostatic and H-bonding interactions. The role of the water cluster is not only isolating and stabilizing the Pt atoms, but also regulating the charge of the metal and the adsorption of reactants. This is shown for the low-temperature water-gas shift reaction (WGSR: CO + H2O CO2 + H…

An X-shooter survey of star forming regions: Low-mass stars and sub-stellar objects

2011

We present preliminary results of our X-shooter survey in star forming regions. In this contribution we focus on sub-samples of young stellar and sub-stellar objects (YSOs) in the Lupus star forming region and in the TW Hya association. We show that the X-shooter spectra are suitable for conducting several parallel studies such as YSO + disk fundamental parameters, accretion and outflow activity in the very low-mass (VLM) and sub-stellar regimes, as well as magnetic activity in young VLM YSOs, and Li abundance determinations. The capabilities of X-shooter in terms of wide spectral coverage, resolution and limiting magnitudes, allow us to assess simultaneously the accretion/outflow, magnetic…

Discrete-valued-pulse optimal control algorithms: Application to spin systems

2015

International audience; This article is aimed at extending the framework of optimal control techniques to the situation where the control field values are restricted to a finite set. We propose generalizations of the standard GRAPE algorithm suited to this constraint. We test the validity and the efficiency of this approach for the inversion of an inhomogeneous ensemble of spin systems with different offset frequencies. It is shown that a remarkable efficiency can be achieved even for a very limited number of discrete values. Some applications in nuclear magnetic resonance are discussed.

Pressure Shift and Gravitational Red Shift of Balmer Lines in White Dwarfs. Rediscussion

2015

The Stark-induced shift and asymmetry, the so-called pressure shift (PS) of $H_\alpha$ and $H_\beta$ Balmer lines in spectra of DA white dwarfs (WDs), as masking effects in measurements of the gravitational red shift in WDs, have been examined in detail. The results are compared with our earlier ones from before a quarter of a century (Grabowski et al. 1987, hereafter ApJ'87; Madej and Grabowski 1990). In these earlier papers, as a dominant constituent of the Balmer-line-profiles, the standard, symmetrical Stark line profiles, shifted as the whole by PS-effect, were applied to all spectrally active layers of the WD atmosphere. At present, in each of the WD layers, the Stark-line-profiles (e…

Moderate-to-Strong Turbulence Generation in a Laboratory Indoor Free Space Optics Link and Error Mitigation via RaptorQ Codes

2016

Free Space Optics (FSO) is rapidly gaining interest as a line-of sight communication technology that offers capabilities similar - in terms of bandwidth and transfer rates - to optical fibre, also possessing several advantages compared with traditional radio frequency links. However, FSO link quality can be strongly affected by unfavourable weather conditions and also by the phenomenon of optical turbulence, even in clear sky. In this work, we have implemented an indoor FSO link and generated moderate-to-strong turbulence conditions along the optical path by using heaters and a mechanical ventilation system. In this way, we have been able to investigate the effects of the generated turbulen…

Rateless Codes Performance Tests On Terrestrial FSO Time-Correlated Channel Model

2012

Free Space Optics (FSO) links are affected by several impairments: optical turbulence, scattering, absorption, and pointing. In particular, atmospheric optical turbulence generates optical power fluctuations at the receiver that can degrade communications with fading events, especially, in high data rate links. A way to mitigate FSO link outages can be to add a coding to communications. Nevertheless, in order to study innovative solutions (software or hardware) and to improve the FSO link performance it needs accurate testing models. In this paper we describe an accurate time-correlated channel model able to predict random temporal fluctuations of optical signal irradiance caused by optical…

The optical blocking filter for the ATHENA wide field imager: Ongoing activities towards the conceptual design

2015

ATHENA is the L2 mission selected by ESA to pursue the science theme "Hot and Energetic Universe" (launch scheduled in 2028). One of the key instruments of ATHENA is the Wide Field Imager (WFI) which will provide imaging in the 0.1-15 keV band over a 40'x40' large field of view, together with spectrally and time-resolved photon counting. The WFI camera, based on arrays of DEPFET active pixel sensors, is also sensitive to UV/Vis photons. Optically generated electron-hole pairs may degrade the spectral resolution as well as change the energy scale by introducing a signal offset. For this reason, the use of an X-ray transparent optical blocking filter is needed to allow the observation of all …

Variable-Radius Offset Surface Approximation on the GPU

2020

Variable-radius offset surfaces find applications in various fields, such as variable brush strokes in 2D and 3D sketching and geometric modeling tools. In forensic facial reconstruction the skin surface can be inferred from a given skull by computing a variable-radius offset surface of the skull surface. Thereby, the skull is represented as a two-manifold triangle mesh and the facial soft tissue thickness is specified for each vertex of the mesh. We present a method to interactively visualize the wanted skin surface by rendering the variable-radius offset surfaces of all triangles of the skull mesh. We have also developed a special shader program which is able to generate a discretized vol…

Quantum Einstein Gravity: Towards an Asymptotically Safe Field Theory of Gravity

2007

Thermal deformations of inhomogeneous elastic plates

1995

We consider thermal deformations of transversally inhomogenous elastic plates. Thin plate equations are derived as limits of full three-dimensional models both in the linear was well as in the non-linear case with appropriate convergence proofs. In the non-linear case also the corresponding von Karman equations are formulated. Its is obtained that the inhomogeneity leads to the loss of some symmetry properties at the von Karman equations