Search results for "FUEL CELL"
showing 10 items of 260 documents
Design of experiment approach applied to reducing and oxidizing tolerance of anode supported solid oxide fuel cell. Part I: Microstructure optimizati…
2011
The main drawback of Ni/YSZ anode supports for solid oxide fuel cell application is their low tolerance to reducing and oxidizing (RedOx) atmosphere changes, owing to the Ni/NiO volume variation. This work describes a structured approach based on design of experiments for optimizing the microstructure for RedOx stability enhancement. A full factorial hypercube design and the response surface methodology are applied with the variables and their variation range defined as: (1) NiO proportion (40-60 wt% of the ceramic powders), (2) pore-former proportion (0-30 wt% corresponding to 0-64 vol.%), (3) NiO particle size (0.5-8 mu m) and (4) 8YSZ particle size (0.6-9 mu m).
Applicability of Waste Engine Oil for the Direct Production of Electricity
2021
New methods for the use of waste products as input for other technologies are a constant subject of research efforts. One such product is waste engine oil. Due to the constantly increasing number of motor vehicles in the world, the recycling or application of engine oils for energy production purposes is currently of considerable importance. This paper contains research regarding the analysis of the electro-oxidation potential of waste engine oil, and thus the possibility of using such oil as a material in fuel cells. The research demonstrates the basic possibility of the electro-oxidation of this oil emulsion on a platinum electrode in an acid electrolyte (aqueous solution of H2SO4). It wa…
The Membrane-Less Microbial Fuel Cell (ML-MFC) with Ni-Co and Cu-B Cathode Powered by the Process Wastewater from Yeast Production
2020
Research related to measurements of electricity production was combined with parallel wastewater parameter reduction in a membrane-less microbial fuel cell (ML-MFC) fed with industry process wastewater (from a yeast factory). Electrodes with Ni–Co and Cu–B catalysts were used as cathodes. A carbon electrode (carbon cloth) was used as a reference due to its widespread use. It was demonstrated that all analyzed electrodes could be employed as cathodes in ML-MFC fed with process wastewater from yeast production. Electricity measurements during ML-MFC operations indicated that power (6.19 mW) and current density (0.38 mA·cm−2) were the highest for Ni–Co electrodes. In addition, during the explo…
Indium doping of proton-conducting solid oxides
2008
Solid oxides protonic conductors are prepared by doping the pure matrix compounds with cationic species. Barium cerate and barium zirconate are perovskite-like compounds, characterized by a network of corner-sharing MeO6 octahedra (Me=Ce, Zr). Barium lies in the cavities between octahedra. Insertion of trivalent species in the octahedral site involves the formation of charge- compensating oxygen vacancies, that can be filled by hydroxyls coming from dissociative water absorption. Then, proton delocalization among structural oxygens ensures conductivity. The most effective conductors are obtained by yttrium doping that, on the other hand, enters only in limited amounts in both BaZrO3 and BaC…
Experimental characterization of a proton exchange membrane fuel-cell for hybrid electric pedal assisted cycles
2017
This paper presents a feasibility study on the prototyping of a hybrid EPAC (Electric Pedal Assisted Cycle) Through an FC-B-UC (Fuel Cell - Battery - Ultra-Capacitors) power system. Aim of this work is the characterization of a PEMFC (Proton Exchange Membrane Fuel Cell) in order to confirm its theoretical performances and to verify the possibility of its installation on an e-bike.
A comparative evaluation of palladium and platinum nanoparticles as catalysts in proton exchange membrane electrochemical cells
2008
The goal of the present study is the development and comparative characterisation of carbon-supported and nanostructured Pd- and Pt-based electrocatalysts for hydrogen oxidation in Proton Exchange Membrane (PEM) H2/O2(air) fuel cells and proton reduction in PEM water electrolysers. Catalysts have been synthesised in a solution using a combined impregnation/reduction polyol method. They have been characterised using X-ray Diffraction (XRD) analysis, Transmission Electron Microscopy (TEM), Thermogravimetric Analysis (TGA) and cyclic voltammetry. NanoPt, nanoPd and nanoPt-Pd catalysts deposited onto a carbon carrier have been used to prepare Membrane-Electrode Assemblies (MEAs) which, in turn,…
Experimental analysis of materials in proton exchange membrane electrolysis cells
2019
Abstract An accelerated supply and demand of energy has resulted in an increased need for efficient energy storage options, where storing energy in hydrogen gas emerges as one of the most attractive. In this study, a singular proton exchange membrane (PEM) electrolysis cell was designed using adequately low-cost materials, and tested using polarisation curves, cyclic voltammetry and AC impedance. A comparative study of various micro porous layer (MPL) materials was performed in an effort to find suitable options which are able to steadily operate under anodic conditions. The best performance was achieved using carbon cloth, however this material was unstable. Untreated porous titanium and n…
Design of a LLC Resonant Converter for Powering a PEM Electrolyzer
2021
International audience; This paper proposes the design of a LLC resonant converter to supply a proton exchange membrane (PEM) electrolyzer. The PEM requires a low voltage with high current, a reduced output voltage ripple, and an overdamped dynamic behavior of the converter to avoid voltage overshoots. The designed converter allows satisfying the design constraints, minimizing switching and reverse recovery losses; the efficiency is influenced mainly by the output rectifier's conduction losses.
Design and Development of a Labview Application for the Measurement of the Complex Impedance of a Fuel Cell in Real Time
2014
International audience; To optimize the performance of fuel cells and to deepen the knowledge of their behavior, it is necessary to make measurements in real time. To run such a measure, it is necessary to use specific software and hardware tools to instrumentation fuel cells. In this context, we presented the steps of designing and developing an application for the measurement of the complex impedance by electrochemical impedance spectroscopy method (EIS) using LabVIEW® software. The experimental results are obtained using a Ballard Nexa® PEM fuel cell, an electronic load produced in our laboratory and application developed by the LabVIEW® software.
A semi-empirical multipurpose steady-state model of a fuel cell for household appliances
2013
In this paper, a multipurpose model of a proton exchange membrane fuel cell for household appliances is proposed. According to a conventional mathematical approach, the proposed model is derived from the physical and electro-chemical equations that rule the fuel cell behaviour. Differently from existing models, a parametric analysis is carried out and a few tunable parameters are accurately selected and identified. Furthermore, this paper proposes an innovative technique of unique model architecture which enables the designer to solve by himself the trade-off between complexity and accuracy on the basis of the specific applications. Three different choices could be performed by the designer…