Search results for "Fabric"

Ruthenium Oxide Nanotubes Via Template Electrosynthesis

2011

Ruthenium oxide nanotubes were fabricated by a single-step galvanostatic deposition using porous anodic alumina membrane as template. For the electrodeposition process, we used a electrochemical cell specifically designed in order to employ only 0.5 ml of 0.02 M RuCl3•xH2O solution. The deposition from a very small volume was specifically addressed owing to the high cost of ruthenium compounds, which could be of some relevance from an applicative point of view. Several techniques were used to characterize the samples prior to and after thermal treatment, which was carried out at different temperatures in order to study the crystallization process of the deposit. Raman spectroscopy of as-dep…

Antonio Belguardo. Un maestro nella Palermo tra XV e XVI secolo: il regesto documentario

2016

Le informazioni documentarie emerse in questi ultimi anni sulla figura di Antonio Belguardo permettono di tracciare con maggiore compiutezza il profilo biografico e la parabola professionale di uno dei più prolifici protagonisti della stagione tardogotica dell’architettura siciliana; la sua attività, per quanto sinora noto, si concentra prevalentemente a Palermo tra l’ultimo quarto del XV secolo e i primi decenni del XVI. New documents that have come to light on Antonio Belguardo allow us to draw a more complete biographic profile of one of the most prolific protagonists of Late Gothic Sicilian architecture; His activity, as far as we know, was mainly carried out in Palermo, between the las…

From Historical Silk Fabrics to Their Interactive Virtual Representation and 3D Printing

2020

The documentation, dissemination, and enhancement of Cultural Heritage is of great relevance. To that end, technological tools and interactive solutions (e.g., 3D models) have become increasingly popular. Historical silk fabrics are nearly flat objects, very fragile and with complex internal geometries, related to different weaving techniques and types of yarns. These characteristics make it difficult to properly document them, at the yarn level, with current technologies. In this paper, we bring a new methodology to virtually represent such heritage and produce 3D printouts, also making it highly interactive through the tool Virtual Loom. Our work involves sustainability from different per…

Life cycle energy performances and environmental impacts of a prefabricated building module

2018

Abstract The paper explores the energy performances and environmental impacts of a prefabricated building module located in Messina (Sicily, Italy) through an approach that combines both the non-steady state building simulation and the Life Cycle Assessment methodology. The building uses renewable energy technologies and is usable in emergency situations or as simply temporary housing. Results show that the building module causes the emission of 1.5 t of CO2eq/m2 and consumes 29.2 GJ/m2 of primary energy during its life cycle. The building achieves the Net Zero Energy Building target even if it has relevant environmental impacts in the materials production stage (72% on average of the total…

Verso una dimensione narrativa delle mappe

2021

Tra il pensiero e la costruzione dell’architettura il disegno ha un ruolo baricentrico per connettere i diversi protagonisti di una realizzazione e per coinvolgere la collettività facendo percepire inedite prospettive. La scrittura si rivela utile per esplicitare ciò che nella grafica è sotteso e per stabilire un ordine nuovo nel ragionamento progettuale. I rapporti fra segni e significati si moltiplicano nei sistemi informativi recenti in cui si ha la sensazione di poter dire moltissimo (dati numerici e spaziali) ma a volte sfugge quella sintesi indispensabile per una interpretazione concreta, finalizzata alla costruzione di possibili esperienze fisiche. Per l’esplorazione dell’uso di dive…

BIO-Bragg gratings: structured molecular networks for on-fiber bioanalysis

2021

The research on photonic biosensors is a scientific hot topic at the moment, with a significant potential impact on industry and medicine. Label-free, miniaturized, inexpensive and low-loss biosensors are developed based on optical fiber technology. Our approach is based on a Bio-Bragg-Grating (BBG) patterned on the surface of a microfiber. We present the design, fabrication and proof of concept of our device, as well as its multiplexing and tunability perspectives [1] .

Influence of chitin nanocrystals on the dielectric behaviour and conductivity of chitosan-based bionanocomposites

2018

[EN] A series of bionanocomposite films based on chitosan, reinforced with chitin nanocrystals, were developed, and assessed in terms of dielectric behaviour and conductivity by using an experimental methodology that allows avoiding the conductivity contribution and the exclusion of contact and interfacial polarization effects. The dielectric relaxations at low and high frequency and temperatures were modeled by Havriliak-Negami functions. Below the glass transition temperature (Tg), the gamma and beta relaxations were observed, which were related to intramolecular and non-cooperative segmental movements. At higher temperatures, an intermolecular and cooperative macromolecular movement, rel…

Dielectric spectroscopy of novel thiol-ene/epoxy thermosets obtained from allyl-modified hyperbranched poly (ethyleneimine) and diglycidylether of bi…

2019

[EN] Dielectric Thermal Analysis (DETA) of a series of new thermoset obtained by click chemistry was performed. The new thermosets were obtained by a dual-curing process consisting in a first photochemical thiol-ene, followed by a thermal thiol-epoxy starting from an allyl-terminated hyperbranched poly(ethyleneimine) (HBPEI) and different proportions of diglycidylether of bisphenol A (DGEBA) and the corresponding stoichiometric proportions of pentaerythritol tetrakis (3-mercaptopropionate, PETMP). The dielectric behaviour was obtained experimentally supressing the conductive effects. Two sub-Tg intramolecular non-cooperative gamma and beta relaxations and an intermolecular cooperative alpha…

2020

Large segmental bone defects occurring after trauma, bone tumors, infections or revision surgeries are a challenge for surgeons. The aim of our study was to develop a new biomaterial utilizing simple and cheap 3D-printing techniques. A porous polylactide (PLA) cylinder was printed and functionalized with stromal-derived factor 1 (SDF-1) or bone morphogenetic protein 7 (BMP-7) immobilized in collagen type I. Biomechanical testing proved biomechanical stability and the scaffolds were implanted into a 6 mm critical size defect in rat femur. Bone growth was observed via x-ray and after 8 weeks, bone regeneration was analyzed with µCT and histological staining methods. Development of non-unions …

Advances in Perovskite Optoelectronics: Bridging the Gap Between Laboratory and Fabrication

2020

In 2019, hybrid halide perovskites celebrated their 10th anniversary as a "wonder material" for optoelectronic applications. Although the parent perovskite structures were elucidated in the late 19th century, the seminal work by Miyasaka et al. exploiting organic‐inorganic hybrid halide perovskites sensitizers for visible‐light conversion in solar cells marked the revisit of these materials and has proven to be a game‐changer in this field. Extensive investigations were undertaken to develop new materials (all inorganic and organic‐inorganic hybrids, in the form of films or alternate morphologies) and deposition techniques, explore interfaces and in‐depth characterization, while engineering…