Search results for "Fermi resonance"
showing 2 items of 12 documents
Vibrational and rotational collisional relaxation in CO2–Ar and CO2–He mixtures studied by stimulated Raman-infrared double resonance
1999
0021-9606; The collisional relaxation among vibrational levels of the Fermi dyad of CO2 mixed with Ar and He (10% CO2, 90% rare gas) has been studied at room temperature with a double resonance experiment. Stimulated Raman effect from the ground state achieved the pumping process with a Nd:YAG laser and a pulse amplified dye laser. After pumping the v(1) or 2v(2)(Sigma(+)g) level, a cw CO2 laser was used to probe either the depopulation rates of the pumped levels (vibrationally or rotationally resolved) or the energy transfer rates to neighboring states. The vibrational energy relaxation has been studied from experimental depopulation of v(1) and population of 2v(2) levels through a five-le…
High Resolution Coherent Anti-Stokes Raman Spectroscopy (CARS) Of O 2 And CO 2
1988
With the help of high spectral quality (linewidth , 6 MHz) injection-locked flashlamp-pumped dye lasers, high resolution Coherent Anti-Stokes Raman Spectroscopy (CARS) has been applied to the study of the Q-branches of 0 2 and CO 2 . The Q-branch linewidths of 02 were obtained from the first nine transitions (J 2 = 1 to 17) recorded at pressures from 0.094 to 1 atm at room temperature. A least squares program was employed to fit calculated spectra to experimental spectra by adjusting different parameters. The collisional broadening coefficients we have obtained are consistent with available Raman data. We have also studied the Q-branch of the fundamental v1 band of CO 2 in the Fermi resonan…