Search results for "Ferro"

Ottimizzazione degli aspetti tecnici ed economici nella gestione della sicurezza in galleria

2010

Advances in Nanoliposomes Production for Ferrous Sulfate Delivery

2020

In this study, a continuous bench scale apparatus based on microfluidic fluid dynamic principles was used in the production of ferrous sulfate-nanoliposomes for pharmaceutical/nutraceutical applications, optimizing their formulation with respect to the products already present on the market. After an evaluation of its fluid dynamic nature, the simil-microfluidic (SMF) apparatus was first used to study the effects of the adopted process parameters on vesicles dimensional features by using ultrasonic energy to enhance liposomes homogenization. Subsequently, iron-nanoliposomes were produced at different weight ratios of ferrous sulfate to the total formulation components (0.06, 0.035, 0.02, an…

Functional molecular materials: supramolecular networks and coordination polymers with optical and/or magnetic properties

2020

El camp dels materials moleculars atrau l’atenció de molts científics degut al gran potencial de la química molecular en el disseny de materials amb un ajust precís de les seues propietats. Els dos projectes tractats en aquesta tesi representen dos temes que destaquen en aquesta àrea, materials de transició d’espín i polímers de coordinació amb propietats òptiques i/o magnètiques, gràcies al seu significant progrés i ràpid desenvolupament en els últims anys. La primera part d’aquesta tesi es basa en l’ús d’enllaços d’hidrogen en el disseny de xarxes multifuncionals de ferro(II) amb transicions d’espín abruptes. El capítol 1 és una introducció a aquest tema des de la perspectiva dels complex…

Terahertz Spin‐to‐Charge Conversion by Interfacial Skew Scattering in Metallic Bilayers

2021

The efficient conversion of spin to charge transport and vice versa is of major relevance for the detection and generation of spin currents in spin‐based electronics. Interfaces of heterostructures are known to have a marked impact on this process. Here, terahertz (THz) emission spectroscopy is used to study ultrafast spin‐to‐charge‐current conversion (S2C) in about 50 prototypical F|N bilayers consisting of a ferromagnetic layer F (e.g., Ni81Fe19, Co, or Fe) and a nonmagnetic layer N with strong (Pt) or weak (Cu and Al) spin‐orbit coupling. Varying the structure of the F/N interface leads to a drastic change in the amplitude and even inversion of the polarity of the THz charge current. Rem…

Integrating vehicle specific power methodology and microsimulation in estimating emissions on urban roundabouts

2021

In this study pollutant emissions were estimated from VSP modal emission rates and the distribution of time spent in each VSP mode obtained from the speed profiles both gathered in the field and simulated in AIMSUN at a sample of urban roundabouts. The versatility of the micro-simulation model for a calibration aimed at improving accuracy of emissions estimates was tested in order to ensure that second-by-second trajectories experienced in the field by a test vehicle through the sampled roundabouts properly reflected the simulated speed profiles. The first results which the thesis will refer, confirmed the feasibility of the smart approach that integrates the use of field-observed and simul…

A microsimulation calibration methodology based on speed-density relationships for freeways

2014

This paper describes the calibration methodology based on speed-density relationships in the microsimulation calibration process, stated that they represent the traffic flow phenomenon in a wide range of operational conditions and well summarize all the information that may be collected on field (or following a run of the microsimulation model) on two of the three key variables of traffic flow. The matching of speed-density relationships from field and simulation was evaluated using statistical analysis as technique of pattern recognition. A test freeway segment under uncongested traffic conditions was selected as case study; based on traffic data observed at A22 Brenner Freeway, Italy, sta…

Ultrafast Coherent THz Lattice Dynamics Coupled to Spins in the van der Waals Antiferromagnet FePS3

2022

Coherent THz optical lattice and hybridized phonon–magnon modes are triggered by femtosecond laser pulses in the antiferromagnetic van der Waals semiconductor FePS3. The laser-driven lattice and spin dynamics are investigated in a bulk crystal as well as in a 380 nm-thick exfoliated flake as a function of the excitation photon energy, sample temperature and applied magnetic field. The pump-probe magneto-optical measurements reveal that the amplitude of a coherent phonon mode oscillating at 3.2 THz decreases as the sample is heated up to the Néel temperature. This signal eventually vanishes as the phase transition to the paramagnetic phase occurs, thus revealing its connection to the long-ra…

Synthesis and Structure Elucidation of Novel Spirooxindole Linked to Ferrocene and Triazole Systems via [3 + 2] Cycloaddition Reaction

2022

In the present work, a novel heterocyclic hybrid of a spirooxindole system was synthesized via the attachment of ferrocene and triazole motifs into an azomethine ylide by [3 + 2] cycloaddition reaction protocol. The X-ray structure of the heterocyclic hybrid (1″R,2″S,3R)-2″-(1-(3-chloro-4-fluorophenyl)-5-methyl-1H-1,2,3-triazole-4-carbonyl)-5-methyl-1″-(ferrocin-2-yl)-1″,2″,5″,6″,7″,7a″-hexahydrospiro[indoline-3,3″-pyrrolizin]-2-one revealed very well the expected structure, by using different analytical tools (FTIR and NMR spectroscopy). It crystallized in the triclinic-crystal system and the P-1-space group. The unit cell p…

TRATTAMENTO CON CALCE DEI TERRENI ARGILLOSI: STATO ATTUALE DELLA TECNICA

2011

Thermoelectric radiation detector based on a superconductor-ferromagnet junction : Calorimetric regime

2018

We study the use of a thermoelectric junction as a thermal radiation detector in the calorimetric regime, where single radiation bursts can be separated in time domain. We focus especially on the case of a large thermoelectric figure of merit ZT affecting significantly, for example, the relevant thermal time scales. This work is motivated by the use of hybrid superconductor/ferromagnet systems in creating an unprecedentedly high low-temperature ZT even exceeding unity. Besides constructing a very general noise model which takes into account cross correlations between charge and heat noise, we show how the detector signal can be efficiently multiplexed by the use of resonant LC circuits givi…