Search results for "Ferromagnetisme"
showing 2 items of 2 documents
Antiferromagnetic Interactions in Copper(II) µ-Oxalato Dinuclear Complexes: The Role of the Counterion
2018
We report the preparation, crystal structure determination, magnetic properties and DFT calculations of five oxalato-bridged dicopper(II) complexes of formula [Cu-2(bpy)(2-)(H2O)(2)(C2O4)](CF3SO3)(2) (1), [Cu-2(bpy)(2)(C2O4)](PF6)(2) (2), [Cu-2(bpy)(2)(C2O4)](ClO4)(2) (3), [Cu-2(bpy)(2)Cl-2(C2O4)]center dot H2O (4) and [Cu-2(bpy)(2)(NO2)(2)(C2O4)] (5) (bpy = 2,2'-bipyridine and C2O42-= oxalate). Compounds 1, 2, 4 and 5 crystallize in the monoclinic system and 3 crystallizes in the triclinic system. The oxalate ligands in 1-5 adopt the bis-bidentate coordination mode and the two bpy molecules act as terminal ligands. The coordination of the counterions and the surroundings of the copper(II) …
Emergence of the stripe-domain phase in patterned permalloy films
2016
The occurrence of stripe domains in ferromagnetic Permalloy (Py=Fe$_{20}$Ni$_{80}$) is a well known phenomenon which has been extensively observed and characterized. This peculiar magnetic configuration appears only in films with a thickness above a critical value ($d_{cr}$), which is strongly determined by the sputtering conditions (i.e. deposition rate, temperature, magnetic field). So far, $d_{cr}$ has usually been presented as the boundary between the homogeneous (H) and stripe-domains (SD) regime, respectively below and above $d_{cr}$. In this work we study the transition from the H to the SD regime in thin films and microstructured bridges of Py with different thicknesses. We find the…