Search results for "Figur"

showing 10 items of 1122 documents

Protonation and methylation reactions of 2-pyridyl-palladium(II) and -platinum(II) complexes

1983

Abstract The reactions of strong acids HX and HClO4 with the 2-pyridyl complexes [PdX(μ-C5H4N-C2,N)(PPh3)]2 (X = Cl, Br), trans-[PdCl(C5H4N-C2)(PEt3)2] and [PdCl(C5H4N-C2)(dppe)] yield the N-protonated derivatives cis-[PdX2-(C5H5N-C2)(PPh3)], trans-[PdCl(C5H5N-C2)(PEt3)2]ClO4 and [PdCl-(C5H5N-C2)(dppe)]ClO4, respectively. The terminal 2-pyridyl group of trans-[PdCl(C5H4N-C2)(PEt3)2] and [PdCl(C5H4N-C2)(dppe)] also reacts with Me2SO4/NaClO4 to give trans-[PdClC5H4(l-Me)N-C2(PEt3)2]ClO4 and [PdClC5H4(l-Me)N-C2(dppe)]ClO4. Analogous N-protonation or N-methylation reactions occur with trans-[PtBr(C5H4N-C2)(L)2] (L = PEt3, PPh3). The complexes trans-[MX(C5H5N-C2)(PMe2Ph)2]ClO4 (M = Pd, X = Cl an…

LigandChemistryStereochemistryOrganic Chemistrychemistry.chemical_elementProtonationMethylationCarbon-13 NMRBiochemistryMedicinal chemistryInorganic ChemistryYield (chemistry)Materials ChemistryElectron configurationPhysical and Theoretical ChemistryPlatinumPalladiumJournal of Organometallic Chemistry
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La ceramica figurata lilibetana "in added colour": breve nota di riesame

2023

The paper offers a contribution to the study of Lilibeo’s figured vases, which make extensive use of added color. The examination of some contexts allows us to clarify the old idea of a derivation of the Lilibetane vases from the workshops of Lipari, due to a displacement of artisans who would operate first in Lipari and then in Lilibeo (like the Swans Painter). It is not completely excludes the movement of craftsmen due to destructions or political changes. However it reconstructs complex interactions in which a main role had to play the influence and the action of medium exercised by the same imported artifacts (Lipari vases, mainly, but not only).

Lilibeovases in added colorred figured vaseSettore L-ANT/07 - Archeologia ClassicaLipari
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The unspeakable through the works of some contemporary Spanish composers

2016

The concept of unspeakable, as complex as it may be, can base itself on an experience of the sensitive, and find a common context in the events exceeding the limit and pointing a certain chaos. Those of the Spanish Civil War have constituted, by numerous aspects, examples of these unthinkable excesses. The impact of the environment on the creators has been heard in the thematic traces which are imperative in the works composed on the themes of death, violence or war: from the sound phenomena, some figures making sensitive the exceeding of the limit and chaotic connotation have been highlighted and echo what is beyond belief, as the destruction of man or the inaudibility of death. These figu…

Limit-experienceGuerre d’EspagneAltérationUnspeakablePhénomènesDémesureViolenceProto-intrigueTopiquesSpanish Civil WarTopicsFigures[SHS.ART] Humanities and Social Sciences/Art and art historyPhenomenaIndicibleAlterationExpérience-limiteImmoderation
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How Idioms Are Recognized when Individuals Are “Thrown Off the Track”, “Off the Rack” or “Off the Path”: A Decision Time Experiment in Healthy Volunt…

2021

Figurative elements in language have their own particularities, including words that deviate from their generally accepted definition to amplify our language or to paraphrase an issue. It is still unclear how individuals process idioms that are figurative or ambiguous, especially when they additionally become distracted by modified idioms that are similar in appearance. In our study, 47 healthy adults (mean age of 27.3 years, SD = 2.9) participated in a decision time experiment to determine how participants recognize well-formed, genuine German idioms alongside certain idiom modifications. All participants were initially exposed to a prime on a screen. Then, they had to detect the target id…

Linguistics and LanguageComputer sciencebusiness.industryCommunicationTrack (disk drive)Experimental and Cognitive Psychologycomputer.software_genreLiteral and figurative languageParaphraseReady-to-wearHealthy volunteersPath (graph theory)Artificial intelligencebusinesscomputerNatural language processing
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Análisis y revisión del sarcasmo y la lítote: propuesta desde la Teoría de la Relevancia

2009

Overall, sarcasm and litote have been considered rhetorical fi gures and, therefore, dislocated uses of language. Classical studies accept the existence of two different languages: the literal one and the fi gurative one, whereas more recent theoretical frameworks, such as Relevance Theory, disagree with this standpoint. In that sense, this paper attempts to revisit some classical considerations from the perspective of Relevance Theory; one signifi cant conclusion will be that there is only one language with different uses guided by communicative relevance.

Linguistics and LanguageHistorysarcasmoLiterature and Literary TheorySarcasmRelevance theorymedia_common.quotation_subjectPhilosophyrelevanciaLanguage and LinguisticsEpistemologylítoteRhetorical questionRelevance (law)figuras retóricasironíalenguajemedia_common
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ALL OR NOTHING: A SEMANTIC ANALYSIS OF HYPERBOLE

2009

This paper focuses on hyperbole, a long neglected form of non-literal language despite its pervasiveness<br />in everyday speech. It addresses the production process of exaggeration, since a crucial limitation in<br />figurative language theories is the production and usage of figures of speech, probably due to the intensive<br />research effort on their comprehension. The aim is to analyse hyperbole from a semantic perspective in order<br />to devise a semasiological taxonomy which enables us to understand the nature and uses of the trope. In<br />order to analyse and classify hyperbolic items a corpus of naturally occurring conversations extracted from<br …

Linguistics and LanguageHyperbolemedia_common.quotation_subjectFigurative languagesemantic fieldHyperbolecorpus analysisSemantic fieldLiteral and figurative languageLanguage and LinguisticsLinguisticsFigure of speechlcsh:Philology. LinguisticsComprehensionfigurative languageCorpus analysislcsh:P1-1091British National CorpusTaxonomy (general)ExaggerationPsychologyhyperbolemedia_commonSemantic field
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Coercive metaphors in news headlines :a cognitive-pragmatic approach

2014

This article explores the application of metaphors in news headlines with a view to interrogating their potential for coercion. Coercion in news discourse is understood as a strategic deployment of pragma-linguistic devices, including metaphors, to foreground the representations of socio-political reality that are compatible with the interests of the news outlet rather than those that inform public debate. It is argued that coercion can be exposed through systematic discourse analysis. Methodologically, the study aims to integrate the cognitive and pragmatic approaches to metaphor in regarding it as both a conceptual building block of news representations and a strategic framing device in n…

Linguistics and LanguageLiterature and Literary TheoryMetaphormedia_common.quotation_subjectDiscourse analysisPublic debateHeadlineLiteral and figurative languageLanguage and LinguisticsLinguisticsNewspaperFraming (social sciences)DramatizationSociologymedia_commonBrno Studies in English
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The race to educational reform in the USA: the race to the top

2011

From the cognitive perspective of embodiment and relying mostly on the powerful and revealing tool of metaphor, we approach the issue of education in the Obama administration's discourse trying to unveil the ideological preferences hidden behind the use of the different metaphors. It is assumed that this body of metaphors will contribute to the political and cultural understanding of such strategic issue to a nation. The analysis of speeches on education by leading figures plus the media reflection of educational problems (Washington Post) will let us see from a close distance how education is talked about. After the analysis of the four metaphors, it will be seen that traditional values su…

Linguistics and LanguageMetaphormedia_common.quotation_subjectDiscourse analysisMedia studiesLiteral and figurative languageLanguage and LinguisticsEducationPoliticsIndividualismTraditional valuesIdeologySociologySocial scienceRace to the Topmedia_commonLanguage and Education
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Irony and the moral order of secondary school classrooms

2011

Abstract This paper describes how irony is used to negatively evaluate student behaviour in sequences where students disrupt or resist the official business of the lesson and thus challenge the teacher's authority. Irony-implicative utterances, i.e. utterances hearable as ironic in their context, are examined from two complementary perspectives: (i) the intricate interactional work utterances involve; how utterances are hearable as ironic and how participants negotiate their implications within the sequences of action in which the utterances are occasioned and used, and (ii) the use of irony in the local management of moral orders in the classroom. Findings show that irony-implicative utter…

Linguistics and LanguageSarcasmmedia_common.quotation_subjectOpposition (politics)ta6121Moral orderLiteral and figurative languageLanguage and LinguisticsLinguisticsEducationIronyNegotiationConversation analysisCriticismPsychologymedia_commonLinguistics and Education
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Neptuno Alegórico: emblemático arco en la obra de sor Juana

2013

ABSTRACT: Frequently but unevenly valued, sor Juana Ines de la Cruz’s (1648-1695) Neptuno alegorico [Allegorical Neptune] has received increased attention in recent years, as though —by virtue of its nature as «ephemeral art»— «that» art (emblematic) had become increasingly more meaningful than the fugacious situation from which it emerged. An exceptional text, the design of the triumphal archway that welcomed the new viceroy Tomas Antonio de la Cerda and his wife Maria Luisa Manrique de Lara in 1680, reveals not only the importance that sor Juana had already attained, to a great extent, as a writer, but also, and more emphatically, it shows the relevance of her public figure and, in a prog…

Linguistics and LanguageVisual Arts and Performing ArtsBaroqueCommunicationmedia_common.quotation_subjectArtCartographyHumanitiesLanguage and LinguisticsPublic figuremedia_common
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