Search results for "Fischer-Tropsch"
showing 3 items of 3 documents
H2-TPR, XPS and TEM Study of the Reduction of Ru and Re promoted Co/γ-Al2O3, Co/TiO2 and Co/SiC Catalysts
2016
<p class="1Body">Effects of Ru and Re promoters on Co-CoO<sub>x </sub>catalysts supported on γ-Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub> and SiC were investigated to improve the understanding of the role of promoters of the active phase of Co-CoO<sub>x</sub>-Ru and Co-CoO<sub>x</sub>-Re. The influence of promoter addition on the composition and activity of the catalysts was characterized by several methods, such as H<sub>2</sub>-TPR, XPS, chemisorption and TEM. Furthermore, the role of support and metal-support interaction was especially studied and different support materials were compared.</p&g…
Rutting analysis of different rubberised stone mastic asphalt mixtures: from binders to mixtures
2021
Stone Mastic Asphalt (SMA) has been broadly used on heavily trafficked roads and motorways in the UK due to its known stability and durability. In this study, several sets of SMA mixtures were produced using different rubberised bitumens, including a Fischer–Tropsch wax pre-treated rubberised bitumen. Properties associated with rutting were evaluated using both linear and nonlinear viscoelastic analyses, using different test methods such as the Strategic Highway Research Programme (SHRP), Shenoy rutting parameter, zero shear viscosity (ZSV) and multiple stress creep recovery (MSCR) tests. The rutting resistance of the resulting SMA mixtures was assessed using the Repeated Load Axial Test (R…
Superior Fischer-Tropsch performance of uniform cobalt nanoparticles deposited into mesoporous SiC
2020
Electrochemically-derived well-crystalline mesoporous silicon carbide (pSiC) was used as a host for cobalt nanoparticles to demonstrate superior catalytic performance during the CO hydrogenation according to Fischer-Tropsch. Colloidal Co nanoparticles (9 ± 0.4 nm) were prepared independently using colloidal recipes before incorporating them into pSiC and, for comparison purposes, into commercially available silica (Davisil) as well as foam-like MCF-17 supports. The Co/pSiC catalyst demonstrated the highest (per unit mass) catalytic activity of 117 µmol.g(CO)-1.g-1(Co).s-1 at 220 °C which was larger by about one order of magnitude as compared to both silica supported cobalt catalysts. Furthe…