Search results for "Flash"
showing 10 items of 201 documents
Generation of hexahydroazulenes
2009
(Z)-Cyclodec-1-en-6-yne (3) generates three conjugated hexahydroazulenes 3→1k→1c, 1l under FVP conditions, whereas flash vacuum pyrolysis (FVP) of cyclodecyne (2) leads to 1,2,9-decatriene (9). We attribute the different thermal behavior of 2 (ring opening) and 3 (ring closure) to different transannular interactions. Altogether 22 constitutional isomers of hexahydroazulene should exist; three new isomers (1k, 1l, and 1m) are presented here, ten were described earlier, but the reinvestigation of the dehydration route of bicyclic alcohol 11 showed that one of the ten structures has to be revised.
Controlling Spin-Correlated Radical Pairs with Donor-Acceptor Dyads: A New Concept to Generate Reduced Metal Complexes for More Efficient Photocataly…
2021
Abstract One‐electron reduced metal complexes derived from photoactive ruthenium or iridium complexes are important intermediates for substrate activation steps in photoredox catalysis and for the photocatalytic generation of solar fuels. However, owing to the heavy atom effect, direct photochemical pathways to these key intermediates suffer from intrinsic efficiency problems resulting from rapid geminate recombination of radical pairs within the so‐called solvent cage. In this study, we prepared and investigated molecular dyads capable of producing reduced metal complexes via an indirect pathway relying on a sequence of energy and electron transfer processes between a Ru complex and a cova…
Cognitive Impairment in Multiple Sclerosis Is Reflected by Increased Susceptibility to the Sound-Induced Flash Illusion
2019
Objective: To determine whether the performance of multiple sclerosis (MS) patients in the sound-induced flash illusion (SiFi), a multisensory perceptual illusion, would reflect their cognitive impairment.Methods: We performed the SiFi task as well as an extensive neuropsychological testing in 95 subjects [39 patients with relapse-remitting MS (RRMS), 16 subjects with progressive multiple sclerosis (PMS) and 40 healthy control subjects (HC)].Results: MS patients reported more frequently the multisensory SiFi than HC. In contrast, there were no group differences in the control conditions. Essentially, patients with progressive type of MS continued to perceive the illusion at stimulus onset a…
A Methodology for Protection of Trees Against Lightning Strikes as a Measure to Prevent Fires and Loss of Human Life
2021
Some regions may be characterized by a very low annual lightning ground flash density, and yet lightning strikes seem to have been in those areas the cause of widespread wildfires in forested areas. Due to global climate change, these occurrences seem to be an increasing threat. In this paper, the authors discuss the withstand capability of trees against lightning and introduce the criteria for the deployment of tree lightning protection systems (TLPS) to protect forested areas, where deemed necessary by the tree risk assessment. This work analytically identifies the critical trunk radius of the tree below which the tree may explode in the case of a lightning strike and ignite the surroundi…
Through space singlet-singlet and triplet-triplet energy transfers in cofacial bisporphyrins held by the carbazoyl spacer
2007
The through space singlet-singlet and triplet-triplet energy transfers in cofacial bis(etio-porphyrins) rigidly held by the carbazoyl spacer were investigated. The studies on singlet-singlet transfer, which operates via a Förster mechanism, were performed using the zinc porphyrin and free base chromophores as energy donor and acceptor, respectively, while the investigation on triplet-triplet processes was performed using the palladium porphyrin, and the zinc porphyrin and free base chromophores as donor and acceptors, respectively. The rate for singlet-singlet transfer ( k ET ( singlet )) is unexpectedly slower than that reported for other similar, rigidly held bisporphyrins such as H 2( D…
Protection of Trees against Lightning Strikes as a Measure to Prevent Fires and Loss of Human Life
2021
Lighting strikes have been the catalyst of massive uncontrolled fires in areas of combustible vegetation. In some regions, lightning strikes may be a relatively unusual occurrence (e.g., California), but instead they seem to have become a major contributor to the propagation of wildfires, as a byproduct of climate change. Given such unusual weather, wildfires originating from lightning are an increasing threat. In this paper, the authors discuss the withstand capability of trees against lightning and introduce a proactive approach to prevent wildfires by the deployment of tree lighting protection systems (TLPS) to protect forested areas, where deemed necessary by the tree risk assessment.
Cathodal occipital tDCS is unable to modulate the sound induced flash illusion in migraine
2019
Migraine is a highly disabling disease characterized by recurrent pain. Despite an intensive effort, mechanisms of migraine pathophysiology still represent an unsolved issue. Evidence from both animal and human studies suggests that migraine is characterized by hyperresponsivity or hyperexcitability of sensory cortices, especially the visual cortex. This phenomenon, in turn, may affect multisensory processing. Indeed, migraineurs present with an abnormal, reduced, perception of the Sound-induced Flash Illusion (SiFI), a crossmodal illusion that relies on optimal integration of visual and auditory stimuli by the occipital visual cortex. Decreasing visual cortical excitability with transcrani…
Object Localization Does Not Imply Awareness of Object Category at the Break of Continuous Flash Suppression
2017
In continuous flash suppression (CFS), a dynamic noise masker, presented to one eye, suppresses conscious perception of a test stimulus, presented to the other eye, until the suppressed stimulus comes to awareness after few seconds. But what do we see breaking the dominance of the masker in the transition period? We addressed this question with a dual-task in which observers indicated (i) whether the test object was left or right of the fixation mark (localization) and (ii) whether it was a face or a house (categorization). As done recently Stein et al. (2011a), we used two experimental varieties to rule out confounds with decisional strategy. In the terminated mode, stimulus and masker wer…
A cross-cultural study using Napping (R): Do Korean and French consumers perceive various green tea products differently?
2013
http://www.elsevier.com/locate/foodres ; WOS:000323239400065; International audience; With the increasing demands of global trading, interests in cross-cultural comparisons have increased to gain understanding in the differences of sensory perception and consumer acceptability. The objective of this study was to compare the differences in perception by Korean and French consumers of green tea produced in Korea, China, and Japan, using Napping (R) followed by ultra flash profile. In addition, overall acceptability was examined in both countries. The results of Napping (R) showed that the Korean consumers were able to discriminate the green teas according to their origins and processing metho…
Single-event effects of space and atmospheric radiation on memory components
2017
Electronic memories are ubiquitous components in electronic systems: they are used to store data, and can be found in all manner of industrial, automotive, aerospace, telecommunication and entertainment systems. Memory technology has seen a constant evolution since the first practical dynamic Random- Access Memories (dynamic RAMs) were created in the late 60's. The demand for ever-increasing performance and capacity and decrease in power consumption was met thanks to a steady miniaturization of the component features: modern memory devices include elements barely a few tens of atomic layers thick and a few hundred of atomic layers wide. The side effect of this constant miniaturization was a…