Search results for "Flume"
showing 10 items of 85 documents
FI-chemiluminometric study of thiazides by on-line photochemical reaction
2004
The present manuscript deals with a simple and sensitive flow-injection method for the chemiluminescent determination of thiazides. The method is based on the on-line photodegradation and chemiluminescent determination of the resulting photo-fragments. The on-line photodegradation is performed in basic medium by using a photoreactor consisting of a 550 cm long x 0.8 mm ID piece of PTFE tubing helically coiled around an 8 W low-pressure mercury lamp. The determination of the photo-irradiated thiazides is performed by a chemiluminescent oxidative reaction with Ce(IV) in sulphuric acid medium. A heterogeneous group of thiazides (indapamide, metolazone, hydroflumethiazide, chlorthalidone and be…
Performance of micellar mobile phases in reversed-phase chromatography for the analysis of pharmaceuticals containing beta-blockers and other antihyp…
1996
A rapid and simple reversed-phase micellar liquid chromatographic procedure for the simultaneous determination of the beta-blockers atenolol, metoprolol and oxprenolol, the diuretics amiloride, bendroflumethiazide, chlorthalidone and hydrochlorothiazide and the vasodilator hydralazine in pharmaceuticals, is proposed. An interpretive optimization procedure, which uses the chromatographic data for only five mobile phases, was applied to select a suitable micellar mobile phase. A comparative study was also made of the performance of micellar and aqueous-organic mobile phases in the analysis of pharmaceuticals that combine beta-blockers and diuretics. The determination of all the drugs could be…
Determination of quinolone residues in chicken and fish by capillary electrophoresis-mass spectrometry
2006
A specific pressure-assisted CE-MS method is described for the analysis of five quinolone residues. MS using a single quadrupole is compared with multiple-stage MS using a quadrupole IT (QIT-MS(n)). The procedure involves a common sample preparation by SPE on disposable cartridges. The most suitable electrolyte is 60 mM (NH(4))(2)CO(3) at pH 9.2. Single quadrupole does not provide enough fragmentation to confirm identities according to the current legislation. However, QIT-MS(n) achieves selective fragmentation. Using this method, danofloxacin, enrofloxacin, flumequine, ofloxacin, and pipemidic acid are analyzed in fortified samples of chicken and fish. Recoveries at levels of 50 ng/g were …
Dye-tracer technique for rill flows by velocity profile measurements
2020
Abstract Water flow on hillslope soil surface supplies energy which is required to detach soil particles, to transport and deposit sediments, therefore flow velocity is a key variable related to hillslope hydrodinamics of soil erosion processes. Among the different methods available for measuring velocity of shallow interrill and rill flow, the trace technique is widely used. Trace technique is applied by adding a material (salt, magnetic material, water isotope, floating object) and then measuring the speed of the material to travel a known distance from the injection point. When flow velocity is measured using a dye-tracing method, the mean velocity is calculated by multiplying the measur…
Flume experiments for assessing the dye-tracing technique in rill flows
2021
Abstract Flow velocity controls hillslope soil erosion and is a key hydrodynamic variable involved in sediment transport and deposition processes. The dye-tracer technique is one of the most applied methods for measuring velocity of shallow interrill and rill flow. The technique is based on the injection of a tracer in a specific point and the measurement of its speed to travel the known distance from the injection point to a given channel section. The dye-tracer technique requires that the measured surface flow velocity has to be corrected to obtain the mean flow velocity using a correction factor which is generally empirically deduced. The technique has two sources of uncertainties: i) th…
Flow resistance law under equilibrium bed-load transport conditions
2018
Abstract The uniform flow resistance equation, in the form due to Manning or Darcy-Weisbach, is often applied to determine the stage-discharge relationship of a river cross-section. The application of this equation, namely the slope-area method, allows to indirectly measure by water level readings the corresponding river discharge. In this paper, a recently deduced flow resistance equation for open channel flow was tested during conditions of equilibrium bed-load transport. First the flow resistance equation was determined by dimensional analysis and applying the condition of incomplete self-similarity for the flow velocity profile. Then the analysis was developed by the following steps: (i…
Assessing flow resistance in gravel bed channels by dimensional analysis and self-similarity
2018
Abstract In this paper a new flow resistance equation for open channel flow, based on the integration of a power velocity profile, was tested for gravel bed channels. First this flow resistance equation, theoretically deduced by dimensional analysis and incomplete self-similarity condition, was reported. Then a relationship between the Γ function of the velocity profile, the channel slope and the Froude number was calibrated by the available laboratory measurements of flow velocity, water depth and bed slope carried out in 416 flume experimental runs with a gravel bed. Then the relationship for estimating Γ function and the theoretical resistance equation was tested by 83 independent flume …
Experimental study of boulder concentration effect on flow resistance in gravel bed channels
2021
Abstract Previous studies demonstrated that for open channel flows the power velocity profile can be integrated to obtain the flow resistance law. In this paper the relationship between Γ coefficient of the power velocity distribution, the channel slope and Froude number (Eq. (9) ) is firstly presented. Then the measurements carried out in a laboratory flume covered by hemispheric elements for two different hydraulic conditions (partially inundated and inundated) are used to calibrate this relationship. These elements are placed with a square arrangement and have a concentration range 4–64%. For the two investigated hydraulic conditions, this analysis demonstrates that the relationship to e…
Simultaneous determination of different classes of antibiotics in fish and livestock by CE-MS
2007
A specific CE-MS method was developed for the simultaneous determination of 12 antibacterial residues (four sulfonamides: sulfamethazine, sulfathiazole, sulfadiazine, and sulfachlorpyridazine; four beta-lactams: amoxicillin, ampicillin, oxacillin, and penicillin V, and four quinolones: danofloxacin, enrofloxacin, ofloxacin, and flumequine) in fish and livestock. Separation conditions, sheath liquid composition and electrospray parameters were optimized to obtain adequate CE separation and a high sensitivity. CE employed a 75 cm long fused-silica capillary (50 cm thermostated plus 25 cm at room temperature) 75 microm id and a 60 mM ammonium acetate separation buffer at pH 8 with 10% of metha…
Field Testing of a Simple Flume (SMBF) for Flow Measurement in Open Channels
2008
In this paper the stage–discharge relationship of a new flume named SMBF (Samani, Magallanex, Baiamonte, Ferro), originally proposed by Samani and Magallanez and tested by Baiamonte and Ferro, for measuring flow discharge in open channels is reviewed. The flume is obtained inserting two semicylinders in a rectangular cross section. The results of some experimental runs carried out using horizontal flumes characterized by different values of the contraction ratio (ranging from 0.17 to 0.81) are used for determining the two coefficients of the power stage–discharge equation. The stage–discharge equation is tested using flow measurements carried out in the period between December 2004 and Marc…