Search results for "Fonctionnalité"
showing 4 items of 4 documents
Complexes de métaux de transition avec des ligands carbènes N-hétérocycliques : synthèses et réactivité
2015
The purpose of this work is the synthesis of complexes containing imine-functionalized protic NHC ligands in order to further develop synthetic methodologies giving access to pNHC, C-bound ‘anionic’ imidazolide, and homo- and heterodinuclear complexes. In the case of imidazoles without functional group, deprotonation with n-butyl lithium afforded (1-aryl-1H-imidazol-2-yl)lithium in good yield. Reaction of (1-aryl-1H-imidazol-2-yl)lithium with [Ir(cod)(μ-Cl)]2 or [Rh(cod)(μ-Cl)]2 yielded a doubly C2,N3-bridged dinuclear complex. In the case of imine-functionalized imidazole, the Ir(I) N-bound imidazole complex can tautomerize to Ir(I) imine-functionalized pNHC complex chloride abstraction at…
Développement territorial et développement agricole durable
2012
L'objectif de la communication est de montrer comment au travers d'une approche pluri-disciplinaire, l'ancrage territorial de l'agriculture est une clé de compréhension de la durabilité de l'agriculture de territoires mixtes, périurbains ou ruraux-touristiques. La dimension socio-spatiale qu'introduit cet angle d'analyse conduit à rapprocher géographie et agroéconomie au sein d'une démarche qui vise à modéliser la complexité et la multi-dimensionnalité du développement agricole. Cette approche est appliquée à un territoire dominé à la fois par l'agriculture et le développement touristique, situé en Corse (Balagne). L'agriculture, entre pression foncière et valorisation touristique du patrim…
Analyse multi-échelles des compromis entre services écosystémiques fournis par la flore adventice
2021
Weeds contribute to the provision of various ecosystem services, negative when linked to their harmfulness (disservices) and positive due to the provision of trophic resources (floral resources, seeds) to pollinators and pest natural enemies (services). In this PhD thesis, we analysed how crop management strategies (coherent crop sequences and associated farming practices) implemented by farmers within a small agricultural landscape modulate the weed contribution to (dis)services provision. We also assessed the relative contribution of field cores and field edges (narrow area between the 1st row of the crop and the boundary) to these services. At the annual scale, we show that crop type hig…
Study of the interactions and physicochemical properties of pea and egg white protein mixtures : from the colloidal to the gelled state.
2022
In recent years, due to the growth of world population, people's consumption of animal protein has increased, leading to the increase of greenhouse gas emissions and land occupation. Therefore, it is necessary to partially replace animal protein with vegetable protein to increase the proportion of vegetable protein in daily consumption and developing mixed food systems seems to be one adequate solution. Pea proteins as a source of plant proteins have good nutritional properties but with limited functional properties while egg white (EW) has good functional properties such as gelling and foaming. Thereby, the physicochemical interactions from mixtures of both types of protein needs to be und…